Novel fluorocarbon-graphene-acrylic polymer and preparation method thereof

A technology of acrylic acid and polymer, which is applied in the direction of plant fiber, anti-corrosion coating, textile and paper making, etc. It can solve the problems of insufficient waterproof and water pressure resistance, and achieve the effects of good transparency, excellent heat dissipation and wear resistance, and strong uniformity of coating film

Inactive Publication Date: 2018-11-16
权家(厦门)新材料有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Wherein U.S. Patent No. 6126849 adopts perfluoroalkyl acrylate monomer, octadecyl acrylate monomer, vinyl chloride monomer, N-methacrylic acid amide monomer etc. to prepare an emulsion polymer under the emulsification of fluorosurfactant A water- and oil-repellent finishing agent, but it is seriously insufficient in waterproof and water pressure resistance
Among them, the Japanese patent JP-A58-42682 uses hydrophobic and oleophobic perfluoroalkyl groups and siloxanes that can impart flexibility to impart hydrophobic and oleophobic properties to substrates such as textiles, but it is insufficient in severe waterproof and water pressure resistance and other ions. sex mix

Method used

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  • Novel fluorocarbon-graphene-acrylic polymer and preparation method thereof
  • Novel fluorocarbon-graphene-acrylic polymer and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0023] Embodiment 1: the preparation of fluorocarbon graphene acrylic acid emulsion or solution

[0024] ①Preparation of fluorocarbon graphene acrylic acid emulsion: Take 15.00 g of monomer perfluoroalkyl ethyl acrylate, 3.808 g of y-(methacryloyloxy)propyltrimethoxysilane, 2 g of methyl methacrylate, and 10 g of acrylic acid Octalol ester 7g, fatty polyalcohol oxyethylene ether (3-15EO) 4g, emulsifier sodium lauryl sulfonate 1g, deionized water 60ml obtain stable pre-emulsion through high-pressure homogenizer emulsification in reaction vessel, Dissolve 0.700g of sodium persulfate in 20ml of deionized water, add 2 / 5 of the total volume of the pre-emulsion into a reactor equipped with a stirrer, thermometer, and condenser, stir and heat, raise the temperature to 40-80°C, add 2 / 5 of the total volume of the initiator, after half an hour of reaction, add the remaining pre-emulsifier and initiator dropwise, and continue the reaction for 5 hours after the addition is complete in 1 h...

Embodiment 2

[0031] Embodiment 2: the preparation of fluorocarbon graphene acrylic acid emulsion or solution

[0032]①Take 20.00g of monomer perfluoroalkyl octyl acrylate, 4g of y-(methacryloyloxy)propyltriethoxysilane, 308g of butyl acrylate, 9g of stearyl acrylate, 3g of methylol acrylamide, Emulsifier sodium dodecyl sulfonate 1g, fatty alcohol polyoxyethylene ether (OS-15) 3g, deionized water 24ml in the reaction vessel through high-pressure homogenizer emulsification to obtain a stable pre-emulsion, take sodium persulfate 0.690 Dissolve g in 8ml deionized water, add 2 / 5 of the pre-emulsion into a reactor equipped with a stirrer, a thermometer, and a condenser, stir and heat, raise the temperature to 40-80°C, add 2 / 5 of the initiator, and react for 1 hour Then add the remaining pre-emulsifier and initiator dropwise, continue the reaction for 4 hours after the dropwise addition is complete in 0.5 hours, cool down, add ammonia water to adjust the pH value to 6.0-8.0, and obtain a fluoroca...

Embodiment 3

[0037] Embodiment 3: the preparation of fluorocarbon graphene acrylic acid emulsion or solution

[0038] ①Take 25.00g of monomer perfluoroalkylnonyl acrylate, 6g of y-(methacryloyloxy)propyltriethoxysilane, 8g of acrylic acid, 6g of stearyl acrylate, 1.12g of methylol acrylamide, Branched-chain fatty alcohol polyoxyethylene ether (1312) 3g, emulsifier sodium dodecylsulfonate 1g, deionized water 50ml obtain stable pre-emulsion through high-pressure homogenizer emulsification in reaction vessel, take potassium persulfate 0.660 g was dissolved in 17ml of deionized water, and 2 / 5 of the pre-emulsion was added to a reactor equipped with a stirrer, a thermometer, and a condenser, stirred and heated, and the temperature was raised to 40-80°C, and 2 / 5 of the initiator was added, and the reaction was carried out for 40 minutes Then add the remaining pre-emulsifier and initiator dropwise, continue the reaction for 6 hours after the dropwise addition is complete in 1.5 hours, cool down, ...

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PUM

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Abstract

The invention discloses a novel fluorocarbon-graphene-acrylic polymer and a preparation method thereof. The polymer is prepared from components in parts by weight as follows: 5-30 parts of a fluorocarbon monomer, 0.01-5 parts of graphene, 0.5-5 parts of a silicon-containing monomer, 5-35 parts of an acrylate monomer, 1-4 parts of a self-crosslinking monomer, 30-80 parts of a solvent and 0.1-1 partof an initiator. The polymer further contains an emulsifier when in a form of solution or emulsion. A solution or emulsion prepared from the novel fluorocarbon-graphene-acrylic polymer has good waterproof, anti-corrosion, anti-power, oil-repellent, anti-fouling, aging-resistant and self-cleaning functions and the like, and is applicable to waterproofing, corrosion resistance, power resistance, oil repellency, fouling resistance, aging resistance and self-cleaning of polyester fibers, polyamide fibers, cotton fibers, cotton fibers / polyester fibers, cotton fibers / hemp fibers, artificial cottonfibers and (building, electronic and metal) coatings.

Description

technical field [0001] The invention relates to the field of polymer materials, in particular to a novel fluorocarbon graphene acrylic acid polymer and a preparation method thereof. Background technique [0002] Fluorocarbon graphene polymer material refers to the product after the hydrogen atoms on the main chain or side chain of ordinary polymers are replaced by fluorine atoms. Fluorocarbon graphene polymer materials have excellent properties, such as strong hydrophobicity, strong stability, including thermal stability, chemical stability, anti-oxidation stability, non-stickiness, biocompatibility and good gas permeability, These properties make fluorine-containing materials well-used in many fields, such as protective coatings and lubricants in the field of microelectronics. [0003] Fluorinated fabric finishing agent is an important textile finishing agent. After finishing with fluorine-containing fabric finishing agent, the fabric can show the characteristics that ord...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08F220/24C08F230/08C08F220/14C08F220/18C08F2/26C08F2/30C08F2/44D06M15/277D06M11/74C09D133/16C09D5/08C09D5/16C09D7/61D06M101/06D06M101/32D06M101/34
CPCC08F2/26C08F2/30C08F2/44C08F220/24C09D5/08C09D5/1668C09D5/1687C09D143/04D06M11/74D06M15/277D06M2101/06D06M2101/32D06M2101/34D06M2200/01D06M2200/11C08K3/042C08F230/08C08F220/14C08F220/1818
Inventor 李太权
Owner 权家(厦门)新材料有限公司
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