Catalyst with hydrogenation catalysis, preparation method and application thereof, and heavy oil hydrogenation deasphaltene method

Abstract

The invention relates to the technical field of hydrocarbon oil hydrogenation, in particular to a catalyst with hydrogenation catalysis, a preparation method and application thereof, and a heavy oil hydrogenation deasphaltene method. The catalyst contains a carrier and a hydrogenation active component loaded on the carrier, the hydrogenation active component contains at least one VB group metal element, and the carrier will contain hydrated alumina and have at least two proton acceptor sites Compounds and compositions of boron-containing compounds are formed. The catalyst of the present invention uses hydrated alumina wet gel as a starting material to prepare a higher-strength carrier, omits the step of drying the hydrated alumina wet gel, simplifies the overall process flow, and reduces the overall operating energy consumption , avoiding the dust pollution caused by using pseudo-boehmite dry rubber powder as the raw material to prepare the carrier, and greatly improving the working environment.

Description

technical field [0001] The present invention relates to the technical field of hydrocarbon oil hydrogenation, specifically, the present invention relates to a catalyst with hydrogenation catalysis and its preparation method and application, and the present invention also relates to a heavy oil hydrogenation deasphaltene method using the catalyst . Background technique [0002] In the traditional catalyst preparation method, alumina shaped body, especially γ-alumina shaped body, is often used as the carrier of supported catalyst because of its good pore structure, suitable specific surface area and high heat resistance stability. use. This kind of alumina is usually obtained from dried hydrated alumina, such as pseudo-boehmite, which is shaped, dried, and then calcined at high temperature. [0003] Based on the above understanding, if figure 1 As shown, the prepared hydrated alumina wet gel needs to be dried to obtain pseudo-boehmite dry rubber powder, and then the pseudo-...

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Problems solved by technology

[0014] (1) Pseudo-boehmite that has not been completely dried has strong viscosity, is difficult to transfer, and easily causes secondary dust pollution;

[0015] (2) Drying starts from the surface. The drying of the wet solid product separated from the mixture obtained from the gelling reaction is incomplete drying, so there is a sandwich biscuit phenomenon, that is, the surface of part of the pseudo-boehmite is dried (that is, the dried surface is substantially free of free water), while the interior is still wet (that is, for the non-dried interior, the content of free water is basically maintained at the level before drying), since the surface is dried, Therefore, hard particles are formed. When peptizing agent and / or binder are added to this incompletely dried pseudo-boehmite and kneaded, the hard particles formed during the drying process are in the process of extrusion. It is easy to cause blockage and affect production efficiency;

[0016] (3) It is difficult to stably control the dry base of pseudo-boehmite. The instability of the dry base will cause great interference to the molding process, making the molding process very unstable, resulting in an increase in the amount of unqualified products and low production efficiency;

[0017] (4) CN103769118A adopts a conventional molding process when molding, yet because the dry basis (35%-50%) of the pseudo-boehmite it adopts is far lower than the conventional dry basis content (about 70%), that is The water content is high, and there is basically no extrusion pressure during the extrusion molding process. Therefore, the carrier obtained after the extrudate is dried and roasted has basically no mechanical strength. As long as a little external force is applied, it will be pulverized and has no possibility of industrial application. sex, which is the biggest problem facing the technology

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