A kind of polymer electrolyte and its preparation method and battery comprising the polymer electrolyte
A polymer and electrolyte technology, applied in the field of polymer electrolyte preparation, can solve the problems of low lithium ion migration number, low room temperature conductivity, polymer electrolyte mechanical properties, electrochemical stability and thermal stability not meeting ideal requirements, etc. , to achieve the effect of good electrochemical stability, improved migration number, room temperature conductivity and lithium ion migration number.
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Embodiment 1
[0025] A polymer electrolyte, the polymer electrolyte includes a polymer matrix, an organic solvent, an inorganic filler, a first solution and a second solution; the polymer matrix and the inorganic filler are dispersed in an organic solvent; the inorganic filler is a modified calcium-based montmorillonite Two mixtures of soil and modified nano-calcium carbonate;
[0026] The polymer matrix is a mixture of polyethylene oxide and polymethyl methacrylate.
[0027] The organic solvent is N,N-dimethylformamide.
[0028] The first solution is LiPF 6 of the dispersion.
[0029] The second solution is ethylene carbonate.
[0030] A kind of polymer electrolyte, its preparation method comprises the following steps:
[0031] S1. Add the above-mentioned appropriate amount of polyethylene oxide, polymethyl methacrylate, modified calcium-based montmorillonite, and modified nano-calcium carbonate to 100 parts under stirring conditions according to the mass ratio of 13:1.5:1.5:1.5 In ...
Embodiment 2
[0036]A polymer electrolyte, the polymer electrolyte includes a polymer matrix, an organic solvent, an inorganic filler, a first solution and a second solution; the polymer matrix and the inorganic filler are dispersed in an organic solvent; the inorganic filler is a modified calcium-based montmorillonite A mixture of soil and nano-nickel oxide;
[0037] The polymer matrix is a mixture of polyethylene oxide and polyvinyl chloride.
[0038] Preferably, the organic solvent is N,N-dimethylacetamide.
[0039] The first solution is LiBF 4 of the dispersion.
[0040] The second solution is ethylene carbonate.
[0041] A kind of polymer electrolyte, its preparation method comprises the following steps:
[0042] S1. Add the above-mentioned polyethylene oxide, polyvinyl chloride, modified calcium-based montmorillonite, and nano-manganese dioxide into the organic solvent with stirring at a mass ratio of 13:1.5:1.5:1.5 to form a uniform and transparent Suspension, after standing u...
Embodiment 3
[0047] A polymer electrolyte, the polymer electrolyte includes a polymer matrix, an organic solvent, an inorganic filler, a first solution and a second solution; the polymer matrix and the inorganic filler are dispersed in an organic solvent; the inorganic filler is a modified calcium-based montmorillonite Two mixtures of soil and nano-nickel oxide;
[0048] The polymer matrix is a mixture of polyethylene oxide and polyvinylidene fluoride.
[0049] The organic solvent is acetone.
[0050] The first solution is LiAsF 6 of the dispersion.
[0051] The second solution is diethyl carbonate.
[0052] A kind of polymer electrolyte, its preparation method comprises the following steps:
[0053] S1. Add the above-mentioned polyethylene oxide, polyvinylidene fluoride, modified calcium-based montmorillonite, and nano-nickel oxide to the organic solvent with stirring at a mass ratio of 13:1.5:1.5:1.5 to form a uniform and transparent Suspension, after standing under reduced pressu...
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