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Loading structure for adsorbing heavy metal pollutants and preparation method and application thereof

A load structure, heavy metal technology, applied in the direction of water pollutants, alkali metal compounds, metal processing equipment, etc., can solve the problems of reducing adsorption efficiency, limiting adsorption efficiency, low adsorption selectivity, etc., to achieve fast and simple manufacturing process, avoid secondary Secondary pollution, high adsorption selectivity effect

Inactive Publication Date: 2019-04-12
RES CENT FOR ECO ENVIRONMENTAL SCI THE CHINESE ACAD OF SCI
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, there are still many problems to be solved in the application of nanomaterials in water treatment. Some nanomaterials are difficult to operate as adsorbents, difficult to recover from water, low adsorption selectivity, poor regeneration effect, high-purity nanomaterials The price is high, and it is easy to agglomerate during use to reduce the adsorption efficiency. There are different degrees of residue after use, and it is easy to migrate in the environment, but it becomes a potential source of pollution for the secondary release of heavy metals, etc.
[0004] In order to solve the above problems, modifying nanomaterials and developing different carriers for loading nanomaterials are the main research trends at present, but modified nanomaterials are often expensive and complex to synthesize, and the loading process of nanocomposites is usually Immerse the carrier material into a solution containing nanomaterials, and some only rely on the physical adsorption of the carrier material itself for loading, the degree of bonding between materials is not high, the loading stability is poor, and it is not easy to obtain stable and large quantities of finished products, and those Composite materials loaded by chemical adsorption often fall off due to the influence of environmental conditions in practical applications, which limits the adsorption efficiency

Method used

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  • Loading structure for adsorbing heavy metal pollutants and preparation method and application thereof
  • Loading structure for adsorbing heavy metal pollutants and preparation method and application thereof
  • Loading structure for adsorbing heavy metal pollutants and preparation method and application thereof

Examples

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preparation example Construction

[0032] The present invention also provides a method for preparing the load structure as described above, comprising the following steps:

[0033] Step 1. Use 3D drawing software to design a load structure of specific shape and size;

[0034] Step 2, uniformly doping heavy metal adsorption nanomaterials into 3D printing materials;

[0035] Step 3, printing the 3D printing nanocomposite material obtained in step 2 into the loading structure designed in step 1 by 3D printing technology;

[0036] Step 4, repeatedly cleaning the loading structure printed in step 3 to remove the 3D printing material remaining on the surface, and drying it.

[0037] Wherein, in step 1, the load structure includes a grid, a filter membrane, a filter ball or a pipe-type structure; in step 2, in some embodiments, the heavy metal adsorption nanomaterial can be mixed into the 3D printing material by stirring , in other embodiments, other suitable doping methods can be selected according to actual needs;...

Embodiment 1

[0042] Preparation of grid structure loaded with heavy metal adsorption nanomaterials:

[0043] Such as figure 1As shown, in this embodiment, a grid for adsorbing trivalent arsenic ions in water is manufactured by using the method of the present invention. In this embodiment, firstly, a grid with a face-centered cubic structure is designed by using three-dimensional drawing software. This structure has a high space utilization rate, a large specific surface area, and a stable structure. The grid thickness is 0.3mm, the length, width, and height of a single grid are 2.5mm, and the three-dimensional dimensions of the entire grid are 1.53cm, 1.53cm, and 1.375cm. Then, in order to adsorb and remove trivalent arsenic ions in water, we selected nano-zero-valent iron with a particle size of 50nm as the heavy metal adsorption nanomaterial, and doped nano-zero-valent iron powder with a particle size of 50nm at a mass fraction of 2% into the 3D printing light. In the cured resin, us...

Embodiment 2

[0053] Preparation of grid structure loaded with heavy metal adsorption nanomaterials:

[0054] Such as Figure 4 As shown, in this embodiment, a grid for adsorbing trivalent arsenic ions in water with the same size and shape as that in Embodiment 1 is fabricated by using the method of the present invention. The grid is also firstly designed using 3D drawing software. The thickness of the grid is 0.3mm, and the length, width and height of each grid are 2.5mm. The three-dimensional dimensions of the entire grid are 1.53cm, 1.53cm, and 1.375cm. But the difference is that in this example, we choose 5-10nm hydrophilic and lipophilic anatase nano-titanium dioxide as heavy metal adsorption nanomaterials, and 5-10nm hydrophilic and lipophilic anatase nano-titanium dioxide powder as 2% mass fraction is doped into the 3D printing photocurable resin, and then fully stirred evenly using a magnetic stirrer to obtain a 3D printing nanocomposite material. Afterwards, the grid is process...

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Abstract

A loading structure for adsorbing heavy metal pollutants and a preparation method and application thereof are disclosed. The loading structure is a hollow structure obtained through 3D printing by using a 3D printing nanocomposite material which is formed by mixing a heavy metal adsorbing nano material and a 3D printing material. Devices or components of a particular shape and size are specifically designed using three-dimensional drawing software, the heavy metal adsorbing nano material is uniformly doped into that 3D printing material, a 3D printing technique is used to manufacture the device or component designed by the 3D drawing software by using the synthetic 3D printing nano composite material, and then the wastewater containing the target heavy metal pollutant is absorbed by the printed device or component. The invention avoids the agglomeration of the heavy metal adsorption material, improves the adsorption selectivity and the adsorption efficiency, is simple to use, does notcause the residue of the adsorbent after use, avoids potential secondary pollution, is easy to recover and reuse, and reduces the cost.

Description

technical field [0001] The invention belongs to the technical field of heavy metal sewage treatment, and in particular relates to a load structure for heavy metal pollutant adsorption, a preparation method and application thereof. Background technique [0002] With the rapid development of the economy, a large amount of metals such as copper, arsenic, lead, mercury, cadmium, cobalt, etc. are discharged into natural water bodies along with the waste water produced by mining, smelting industry, chemical enterprises, agricultural irrigation, etc., which not only affects the aquatic environment Cause serious pollution, but also a serious threat to human health. Existing heavy metal wastewater treatment technologies include precipitation, redox, ion exchange, adsorption, reverse osmosis, electrolysis, membrane separation, and biological treatment. Among them, the adsorption method uses a high specific surface area, insoluble solid material as an adsorbent, and adsorbs heavy meta...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01J20/20B01J20/06B01J20/02B01J20/28B01J20/30B29C64/314B33Y70/00C02F1/28C02F101/10C02F101/20C02F101/22
CPCB01J20/02B01J20/06B01J20/20B01J20/205B01J20/28014B01J20/28038B29C64/314B33Y70/00C02F1/281C02F1/283C02F2101/103C02F2101/20C02F2101/203C02F2101/22
Inventor 胡立刚王丁一职亭亭赵瑞琪何滨江桂斌
Owner RES CENT FOR ECO ENVIRONMENTAL SCI THE CHINESE ACAD OF SCI
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