UV curable water-based polyurethane adhesive

A water-based polyurethane and adhesive technology, applied in the direction of polyurea/polyurethane adhesives, adhesives, adhesive types, etc., can solve the problems of high polymer reflection loss, low ultraviolet absorption rate, etc. High junction strength and good solvent resistance

Inactive Publication Date: 2019-05-24
浙江久大纺织科技有限公司
View PDF7 Cites 7 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] However, the absorption rate of ultraviolet rays is low. Since the wavelength of ultraviolet rays is smaller t

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • UV curable water-based polyurethane adhesive

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0026] A UV photocurable water-based polyurethane adhesive, characterized in that the preparation raw materials are measured in parts by weight, including: 5.5 parts of polypropylene oxide ether diol (PPG2000), 5.5 parts of polyoxypropylene diol (PPG), isofor 7.5 parts of ketone diisocyanate (IPDI), 1.2 parts of dibutyltin dilaurate (DBTDL), 3.5 parts of 2,2-dimethylolpropionic acid (DMPA), 3.5 parts of hydroxyethyl acrylate (HEA), p-methoxy 0.1 parts of phenol, 3.5 parts of 2,2-dimethyltrimethylene cyclocarbonate (PDTC), 3 parts of triethylamine (TEA), 3 parts of KH560 silane coupling agent, 4.5 parts of nano-magnesium hydroxide, anhydrous 17.5 parts of ethanol, 3 parts of TPO-L photoinitiator, 3 parts of glycerol dimethacrylate (TMPDA), 3 parts of hexanediol diacrylate, 3 parts of terpene rosin resin and 29.7 parts of deionized water.

[0027] The UV photocurable water-based polyurethane adhesive is characterized in that the preparation steps are as follows:

[0028] (1) Pr...

Embodiment 2

[0038] A UV photocurable water-based polyurethane adhesive, including: 1 part of polypropylene oxide ether diol (PPG2000), 1 part of polyoxypropylene diol (PPG), 5 parts of isophorone diisocyanate (IPDI), dilauric acid 2 parts of dibutyltin (DBTDL), 5 parts of 2,2-dimethylolpropionic acid (DMPA), 5 parts of hydroxyethyl acrylate (HEA), 0.1 part of p-methoxyphenol, 2, 2-dimethyl 2 parts of trimethylene cyclocarbonate (PDTC), 3 parts of triethylamine (TEA), 5 parts of KH560 silane coupling agent, 2 parts of nano-magnesium hydroxide, 20 parts of absolute ethanol, 2 parts of TPO-L photoinitiator , 2 parts of glycerol dimethacrylate (TMPDA), 2 parts of hexanediol diacrylate, 2 parts of terpene rosin resin and 40.9 parts of deionized water.

[0039] The UV photocurable water-based polyurethane adhesive is characterized in that the preparation steps are as follows:

[0040] (1) Preparation of organic nano-magnesium hydroxide. Add KH550 silane coupling agent and absolute ethanol int...

Embodiment 3

[0050] A UV photocurable water-based polyurethane adhesive, including: 4 parts of polypropylene oxide ether diol (PPG2000), 4 parts of polyoxypropylene diol (PPG), 5 parts of isophorone diisocyanate (IPDI), dilauric acid 1 part of dibutyltin (DBTDL), 3 parts of 2,2-dimethylolpropionic acid (DMPA), 3 parts of hydroxyethyl acrylate (HEA), 0.1 part of p-methoxyphenol, 2,2-dimethyl Trimethylene cyclocarbonate (PDTC) 3 parts, triethylamine (TEA) 3 parts, KH570 silane coupling agent 3 parts, nano magnesium hydroxide 4 parts, absolute ethanol 15 parts, TPO-L photoinitiator 2 parts , 2 parts of glycerol dimethacrylate (TMPDA), 2 parts of hexanediol diacrylate, 2 parts of terpene rosin resin and 43.9 parts of deionized water.

[0051] The UV photocurable water-based polyurethane adhesive is characterized in that the preparation steps are as follows:

[0052] (1) Preparation of organic nano-magnesium hydroxide. Add KH570 silane coupling agent and absolute ethanol into the beaker, the ...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

PUM

No PUM Login to view more

Abstract

The invention discloses a UV curable water-based polyurethane adhesive, which is prepared from, by weight, 1-10 parts of polyoxypropylene glycol, 1-10 parts of polypropylene oxide glycol, 5-10 parts of isophorone diisocyanate, 0.5-2 parts of dibutyltin dilaurate, 2-5 parts of 2,2-bis(hydroxymethyl)propionic acid, 2-5 parts of 2-hydroxyethyl acrylate, 0.01-0.2 part of 4-methoxyphenol, 2-5 parts ofpoly(2,2-dimethyltrimethylene carbonate), 1-5 parts of triethylamine, 1-5 parts of KH560, 2-7 parts of nano-magnesium hydroxide, 15-20 parts of absolute ethyl alcohol, 1-5 parts of TPO-L photoinitiator, 1-5 parts of glycerolatedimethacrylate, 1-5 parts of hexanediyl bisacrylate, 1-5 parts of Terpene resin and 20-50 parts of deionized water. The invention further discloses a preparation method of the UV curable water-based polyurethane adhesive. The adhesive, applied to the field of textile, can bring excellent flame retardance and mechanical performance to textile products, and has the advantages of short curing time, good solvent resistance, high bonding strength and being green and environmentally friendly.

Description

technical field [0001] The invention belongs to the field of preparation of textile engineering adhesives, in particular to a UV photocurable water-based polyurethane adhesive. Background technique [0002] Polyurethane (PU) adhesive refers to the adhesive containing carbamate group (-NHCOO-) or isocyanate group (-NCO) in the molecular chain, which can be divided into two categories: polyisocyanate and polyurethane. Since the polyurethane adhesive contains these two groups and shows high activity and polarity, it is applied to many substrates, such as foam, plastic, wood, leather, fabric, paper, ceramics and other porous materials, as well as metal, glass, etc. , rubber, plastic and other materials with smooth surface, it has excellent adhesion to them. However, at present, polyurethane adhesives are still mainly solvent-based. Due to the shortcomings of organic solvents such as flammability, explosion, volatility, and strong odor, they are likely to cause environmental po...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

Application Information

Patent Timeline
no application Login to view more
IPC IPC(8): C09J175/14C09J193/04C09J11/04C08G18/75C08G18/67C08G18/66C08G18/48C08G18/34
Inventor 姜林强蔡国明
Owner 浙江久大纺织科技有限公司
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Try Eureka
PatSnap group products

Browse by: Latest US Patents, China's latest patents, Technical Efficacy Thesaurus, Application Domain, Technology Topic.

© 2024 PatSnap. All rights reserved.Legal|Privacy policy|Modern Slavery Act Transparency Statement|Sitemap