Medical super-tough puncture-resistant high-barrier composite film and preparation method thereof
A composite film and puncture-resistant technology, which is applied to chemical instruments and methods, applications, flat products, etc., can solve the problems of puncture resistance, high barrier, low crystallinity, easy delamination, etc., and achieve controllable thickness, low cost, and easy Forming effect
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[0031] As introduced in the background technology, there is a certain difference in the adhesion between the layers of the current non-PVC multi-layer co-extrusion film, and the separation between the layers is easy to occur during the film preparation process, so it is difficult to control The preparation of this kind of multi-layer co-extrusion film and obtain the problem of the product of high film yield. Therefore, the present invention proposes a kind of preparation method of medical puncture resistance, high barrier composite film, described method comprises:
[0032] S1. Select spherical silica or calcium carbonate powder with a particle size ranging from 0.1 to 2.0 μm, and use organic wax for organic treatment for 1 to 3 hours;
[0033]S2. Combine step S1. Silica powder after organic treatment with terephthalic acid (PTA), 1,6-naphthalene dicarboxylic acid, isophthalic acid (IPA), and ethylene glycol in a weight ratio of 0.1 to 1 : 10 ~ 50: 5 ~ 15: 10 ~ 30: 30 ~ 65 ra...
Embodiment 1
[0065] Spherical silica powders with particle sizes ranging from 0.1 to 1.0 μm were respectively selected, and organically treated with hard partially saponified montan wax for 1.5 hours;
[0066] The organically treated silica powder and terephthalic acid (PTA), 1,6-naphthalene dicarboxylic acid, isophthalic acid (IPA), and ethylene glycol are in a weight ratio of 0.5:30:10.6:15: Mix at a ratio of 44, add 200ppm ethylene glycol antimony as a catalyst, and 300ppm tributyl phosphate as a stabilizer to carry out esterification reaction. The esterification temperature is 240-265°C, and the esterification time is 3h. After that, under a vacuum of 20Pa, The polycondensation reaction was carried out at 278-300°C for 3.5h to obtain a low-crystallinity copolyester with an intrinsic viscosity of 0.68dl / g and a melting point of 220°C; the outer layer of the film;
[0067] The organically treated silica powder was mixed with terephthalic acid (PTA), isophthalic acid (IPA), 2-methyl-1,3-...
Embodiment 2
[0073] Spherical silica powders with a particle size ranging from 0.5 to 1.0 μm were respectively selected, and organically treated with ultra-low molecular weight polyethylene wax for 2.5 hours;
[0074] The organically treated silica powder and terephthalic acid (PTA), 1,6-naphthalene dicarboxylic acid, isophthalic acid (IPA), and ethylene glycol are in a weight ratio of 0.5:26:9.5:19: Mix at a ratio of 45, add 250ppm antimony trioxide as a catalyst, and 350ppm trimethyl phosphate as a stabilizer for esterification reaction. The esterification temperature is 250-255°C, and the esterification time is 3.2h. , 278-290°C for 3.2h of polycondensation reaction to obtain a low-crystallinity copolyester with an intrinsic viscosity of 0.69dl / g and a melting point of 210°C; the low-crystallinity copolyester is extruded as the The outer layer of the composite film;
[0075] The organically treated silica powder was mixed with terephthalic acid (PTA), isophthalic acid (IPA), 2-methyl-1...
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