A kind of SBR styrene-butadiene latex for modified emulsified asphalt and preparation method thereof
A technology of styrene-butadiene latex and emulsified asphalt, which is applied in the direction of building components, building insulation materials, buildings, etc., can solve the problems of affecting performance, uneven dispersion, low physical and mechanical properties, etc., and achieve improved anti-aging ability and bonding performance Improved, easy effect of latex raw materials
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Embodiment 1
[0035] 1) Vulcanization graft modification of general-purpose synthetic styrene-butadiene rubber emulsion
[0036] 1.1 Add 2791 grams of 1500-type styrene-butadiene rubber emulsion with a solid content of 21.5% into the reactor, start stirring, and the rotation speed is 150r / min;
[0037]1.2 Add 80 grams of disproportionated potassium abietate soap with a concentration of 25%, 2 grams of benzoyl peroxide, 20 grams of diphenylmethane diisocyanate (MDI), isopropyl dioleic acid acyloxy (diisooctyl phosphate Oxygen) titanate 15 grams, 1% sodium metabisulfite aqueous solution 30 grams;
[0038] 1.3 After the addition, stir for 45 minutes at 30°C and a stirring speed of 150r / min to fully disperse the material evenly. Raise the temperature to 70°C, and react at 70°C for 3.5 hours to obtain the cross-linked grafted styrene-butadiene rubber emulsion;
[0039] 1.4 Slowly add 15 grams of 5% polyvinyl methyl ether aqueous solution of latex agglomeration agent, and stir for 15 minutes to...
Embodiment 2
[0047] 1) Vulcanization graft modification of general-purpose synthetic styrene-butadiene rubber emulsion
[0048] 1.1 Add 2927 grams of 1502-type styrene-butadiene rubber emulsion with a solid content of 20.5% into the reaction kettle, start stirring, and the rotation speed is 240r / min;
[0049] 1.2 Add 60 grams of fatty acid potassium soap with 20% concentration, 4.8 grams of dicumyl hydroperoxide, 11 grams of toluene diisocyanate (TDI), 41 grams of isopropyl trioleate acyloxy titanate, 1% concentration of 20 grams of sodium bisulfite aqueous solution;
[0050] 1.3 After the addition, stir for 50 minutes at 27°C and a stirring speed of 240r / min to fully disperse the material evenly. Raise the temperature to 66°C and react at 70°C for 4 hours to obtain the cross-linked grafted styrene-butadiene rubber emulsion;
[0051] 1.4 Slowly add 26 grams of 4% hydroxyethyl cellulose aqueous solution of latex agglomeration agent, and stir for 12 minutes to fully agglomerate the latex; ...
Embodiment 3
[0059] 1) Vulcanization graft modification of general-purpose synthetic styrene-butadiene rubber emulsion
[0060] 1.1 Add 2715 grams of 1502-type styrene-butadiene rubber emulsion with a solid content of 22.1% into the reaction kettle, start stirring, and the rotation speed is 150r / min;
[0061] 1.2 Add 100 grams of disproportionated potassium abietate soap with a concentration of 25%, 1.5 grams of dicumyl peroxide, 14 grams of triallyl isocyanurate (TAIC), isopropyl dioleic acid acyloxy (di 18 grams of isooctyl phosphate acyloxy) titanate, 30 grams of 1% sodium metabisulfite aqueous solution;
[0062] 1.3 After the addition, stir for 40 minutes at 32°C and a stirring speed of 180r / min to fully disperse the material evenly. Raise the temperature to 73°C and react at 73°C for 3 hours to obtain the cross-linked grafted styrene-butadiene rubber emulsion;
[0063] 1.4 Slowly add 15 grams of latex agglomeration agent 4% polyvinyl alcohol (model 1788) aqueous solution, and stir f...
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