Looking for breakthrough ideas for innovation challenges? Try Patsnap Eureka!

Nanocrystalline ink with fluorescence characteristics and preparation method and patterning application thereof

A technology with fluorescent characteristics and nanocrystals, which is applied in the field of nanocrystal inks and its preparation, can solve problems such as poor processing quality, simple device structure, and low efficiency, and achieve the effect of changing

Active Publication Date: 2019-08-06
TSINGHUA UNIV
View PDF10 Cites 8 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] However, these research and application works have only solved the problems of the synthesis technology of fluorescent nanomaterials and the application in the field of optoelectronics in a small range.
There are still many excellent properties of fluorescent nanomaterials that have not been fully utilized; the current device processing technologies, such as spin coating, electrodeposition, dipping and pulling, etc., have poor processing quality, small area, low efficiency, high cost and poor device structure. Simple problems, so it cannot meet the needs of high-quality, complex-structured device processing and diversified applications

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Nanocrystalline ink with fluorescence characteristics and preparation method and patterning application thereof
  • Nanocrystalline ink with fluorescence characteristics and preparation method and patterning application thereof
  • Nanocrystalline ink with fluorescence characteristics and preparation method and patterning application thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0128] The present embodiment provides a kind of nanocrystalline ink, specifically as follows:

[0129] The nanocrystalline material of the present embodiment selects CsPbBr 3 Nanocrystal, the XRD pattern of this nanocrystal is as figure 1 As shown, the SEM image of its crystal morphology is shown in figure 2 As shown, the PL diagram of the fluorescence emission characteristics of its crystal is shown in image 3 shown.

[0130]

[0131]

[0132] The present embodiment further provides the preparation method of above-mentioned nanocrystalline ink, as follows:

[0133] According to (n-hexane + n-tetradecane): sodium thiosulfate: CsPbBr 3 The mass ratio of nanocrystals=1:0.0002:0.015 to prepare a mixed solution and ultrasonically stir for 1h to obtain CsPbI with uniform composition3 Nanocrystalline dispersion A1;

[0134] Then prepare a mixed solution according to (n-hexane + n-tetradecane): polyethylene glycol mass ratio = 1:0.03, and stir for 6 hours under heating ...

Embodiment 2

[0141] The present embodiment provides a kind of nanocrystalline ink, specifically as follows:

[0142] The nanocrystalline material in the present embodiment selects CsPbBr 3 @CsPbI 3 Nanocrystals with a core-shell structure. CsPbBr used in this example 3 @CsPbI 3 The XRD patterns of core-shell nanocrystals are as follows: Figure 4 As shown, the SEM image of its crystal morphology is shown in Figure 5 As shown, the PL diagram of the fluorescence emission characteristics of its crystal is shown in Image 6 shown.

[0143]

[0144] The present embodiment further provides the preparation method of above-mentioned nanocrystalline ink, as follows:

[0145] According to toluene: (sodium dodecylbenzenesulfonate + carboxymethyl cellulose): CsPbBr 3 @CsPbI 3 The mass ratio of nanocrystals = 1:0.001:0.01 to prepare a mixed solution and ultrasonically stir for 0.5h to obtain CsPbBr with uniform composition 3 @CsPbI 3 Nanocrystalline dispersion A2;

[0146] Then prepare ...

Embodiment 3

[0152] The present embodiment provides a kind of nanocrystalline ink, specifically as follows:

[0153] The nanocrystalline material in the present embodiment selects CsPbI 3 / rGO nanocomposite heterocrystals. CsPbI used in this example 3 The XRD patterns of / rGO nanocomposite heterocrystals are as follows Figure 7 As shown, the SEM image of its crystal morphology is shown in Figure 8 As shown, the PL diagram of the fluorescence emission characteristics of its crystal is shown in Figure 9 shown.

[0154] nanocrystalline material CaPbI 3 / rGO nanocomposite heterogeneous crystal

1.96g, Dispersant Sodium dodecyl sulfate 0.02g, binder polyvinyl acetate 16.67g, heat curing agent Alcohol-soluble resin 1000g, solvent 1,2-dichloroethane (20v / v%) + p-xylene (80v / v%) 181.35g。

[0155] The present embodiment further provides the preparation method of above-mentioned nanocrystalline ink, as follows:

[0156] According to (1,2-d...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

PropertyMeasurementUnit
Viscosityaaaaaaaaaa
Viscosityaaaaaaaaaa
Viscosityaaaaaaaaaa
Login to View More

Abstract

The invention relates to nanocrystalline ink with fluorescence characteristics and a preparation method thereof and patterning application thereof. The nanocrystalline ink comprises a nanocrystallinematerial, a dispersant, a binder, a thermal curing agent or a light inducer. The nanocrystal material is selected from one or at least two of an ABX3 nanocrystalline, an ABX3@ABX'3 core-shell structure nanocrystalline composite and a nanocomposite with the ABX3 nanocrystalline grown in situ on the surface of a nano two-dimensional material. The nanocrystalline ink has good fluorescence characteristics, and physical and chemical properties such as ink viscosity meet the basic requirements of inkjet printing. Patterned printing can be realized by inkjet printing. Patterned devices with fluorescence characteristics can be obtained by thermal curing or ultraviolet radiation curing. The nanocrystalline ink can be used in the fields of anti-counterfeiting identification, safety monitoring, intelligent display, building photovoltaic integration, biomedical and visible light wireless communication, and realizes high-quality, large-area, fast and efficient, low-cost and complex-structure deviceprocessing and diversified application.

Description

technical field [0001] The invention relates to the technical field of application of nanomaterials, in particular to a nanocrystalline ink with fluorescent properties, a preparation method thereof, and a patterning application. Background technique [0002] Semiconductor nanocrystals have been widely used in solar cells, light-emitting diodes, photodetection, photocatalysis, lasers and other fields due to their unique photoelectric properties; especially CsPbX 3 (X is a halogen element) is a representative of inorganic perovskite nanocrystals, because of its excellent properties such as high light absorption coefficient, low defect density, long carrier diffusion distance and bipolar carrier transport, it is also favored by researchers. Widespread concern. [0003] The inventor has previously developed a series of in-situ growth CsBX on the surface of nanometer two-dimensional materials 3 (B is an element containing +2 valence state; X is a halogen element) nanocrystallin...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
IPC IPC(8): C09D11/50C09D11/30B41M5/00B41M3/14B41M3/00G09F13/22G09F3/00H01Q1/24H01Q1/38H01Q1/50
CPCB41M3/00B41M3/14B41M5/00B41M5/0041C09D11/30C09D11/50G09F3/0294G09F13/22G09F2013/225H01Q1/241H01Q1/38H01Q1/50
Inventor 林红张琦石京周养盈魏雅璇
Owner TSINGHUA UNIV
Features
  • Generate Ideas
  • Intellectual Property
  • Life Sciences
  • Materials
  • Tech Scout
Why Patsnap Eureka
  • Unparalleled Data Quality
  • Higher Quality Content
  • 60% Fewer Hallucinations
Social media
Patsnap Eureka Blog
Learn More