Nanocrystalline ink with fluorescence characteristics and preparation method and patterning application thereof
A technology with fluorescent characteristics and nanocrystals, which is applied in the field of nanocrystal inks and its preparation, can solve problems such as poor processing quality, simple device structure, and low efficiency, and achieve the effect of changing
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Embodiment 1
[0128] The present embodiment provides a kind of nanocrystalline ink, specifically as follows:
[0129] The nanocrystalline material of the present embodiment selects CsPbBr 3 Nanocrystal, the XRD pattern of this nanocrystal is as figure 1 As shown, the SEM image of its crystal morphology is shown in figure 2 As shown, the PL diagram of the fluorescence emission characteristics of its crystal is shown in image 3 shown.
[0130]
[0131]
[0132] The present embodiment further provides the preparation method of above-mentioned nanocrystalline ink, as follows:
[0133] According to (n-hexane + n-tetradecane): sodium thiosulfate: CsPbBr 3 The mass ratio of nanocrystals=1:0.0002:0.015 to prepare a mixed solution and ultrasonically stir for 1h to obtain CsPbI with uniform composition3 Nanocrystalline dispersion A1;
[0134] Then prepare a mixed solution according to (n-hexane + n-tetradecane): polyethylene glycol mass ratio = 1:0.03, and stir for 6 hours under heating ...
Embodiment 2
[0141] The present embodiment provides a kind of nanocrystalline ink, specifically as follows:
[0142] The nanocrystalline material in the present embodiment selects CsPbBr 3 @CsPbI 3 Nanocrystals with a core-shell structure. CsPbBr used in this example 3 @CsPbI 3 The XRD patterns of core-shell nanocrystals are as follows: Figure 4 As shown, the SEM image of its crystal morphology is shown in Figure 5 As shown, the PL diagram of the fluorescence emission characteristics of its crystal is shown in Image 6 shown.
[0143]
[0144] The present embodiment further provides the preparation method of above-mentioned nanocrystalline ink, as follows:
[0145] According to toluene: (sodium dodecylbenzenesulfonate + carboxymethyl cellulose): CsPbBr 3 @CsPbI 3 The mass ratio of nanocrystals = 1:0.001:0.01 to prepare a mixed solution and ultrasonically stir for 0.5h to obtain CsPbBr with uniform composition 3 @CsPbI 3 Nanocrystalline dispersion A2;
[0146] Then prepare ...
Embodiment 3
[0152] The present embodiment provides a kind of nanocrystalline ink, specifically as follows:
[0153] The nanocrystalline material in the present embodiment selects CsPbI 3 / rGO nanocomposite heterocrystals. CsPbI used in this example 3 The XRD patterns of / rGO nanocomposite heterocrystals are as follows Figure 7 As shown, the SEM image of its crystal morphology is shown in Figure 8 As shown, the PL diagram of the fluorescence emission characteristics of its crystal is shown in Figure 9 shown.
[0154] nanocrystalline material CaPbI 3 / rGO nanocomposite heterogeneous crystal
1.96g, Dispersant Sodium dodecyl sulfate 0.02g, binder polyvinyl acetate 16.67g, heat curing agent Alcohol-soluble resin 1000g, solvent 1,2-dichloroethane (20v / v%) + p-xylene (80v / v%) 181.35g。
[0155] The present embodiment further provides the preparation method of above-mentioned nanocrystalline ink, as follows:
[0156] According to (1,2-d...
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Abstract
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