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Anti-corrosion rust inhibitor for concrete and preparation method of anti-corrosion rust inhibitor

A rust inhibitor and concrete technology, applied in the field of building material additives, can solve problems such as inability to absorb sulfate ions, achieve significant rust and sulfate corrosion resistance, good sulfate corrosion resistance and rust resistance, construction operation convenient effect

Active Publication Date: 2019-08-30
福建省建筑科学研究院有限责任公司 +3
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0007] Chinese invention patent CN104478286B discloses a composite anticorrosion and rust inhibitor for concrete, which is mainly composed of polycarboxylate water reducer, sodium dodecylsulfonate, N-methylethanolamine, sodium molybdate and other components, which can improve concrete The anti-chloride ion penetration performance can significantly alleviate the damage of chloride ions to the passivation film of steel bars, and has a significant anti-corrosion effect. It can prevent sulfate ions from entering the concrete through certain physical means, but this composition ratio cannot absorb the sulfate ions entering the concrete. sulfate ion

Method used

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  • Anti-corrosion rust inhibitor for concrete and preparation method of anti-corrosion rust inhibitor
  • Anti-corrosion rust inhibitor for concrete and preparation method of anti-corrosion rust inhibitor
  • Anti-corrosion rust inhibitor for concrete and preparation method of anti-corrosion rust inhibitor

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Experimental program
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Effect test

Embodiment 1

[0027] Dissolve 104.7g of calcium nitrate tetrahydrate in 100ml of water to prepare a calcium nitrate solution, and dissolve 47.0g of sodium carbonate in 250ml of water to prepare a sodium carbonate solution;

[0028] Dissolve 22.2g of polycarboxylate water-reducing agent and 10.5g of ethylenediaminetetramethylenephosphonic acid in 231ml of water and place it in a flask, then add calcium nitrate solution and sodium carbonate solution dropwise to the flask at a constant speed, and the reaction is performed at 20 ℃, the whole dropping process is 1.5h, and the nano calcium carbonate suspension is obtained.

[0029] Dissolve 22.9 g of barium nitrate, 17.5 g of ethylene glycol, 29.2 g of vitamin C, and 15.3 g of disodium EDTA in 150 ml of water, and put the mixed aqueous solution into the above-mentioned nano-calcium carbonate suspension and stir evenly.

[0030] The polycarboxylate water reducing agent is obtained by radical copolymerization of acrylic acid and prenyl polyoxyethyl...

Embodiment 2

[0032] Dissolve 121.1g of calcium nitrate tetrahydrate in 100ml of water to prepare a calcium nitrate solution, and dissolve 49.4g of sodium carbonate in 250ml of water to prepare a sodium carbonate solution;

[0033] Dissolve 26.7g of polycarboxylate water-reducing agent and 9.0g of ethylenediaminetetramethylenephosphonic acid in 217ml of water and place it in a flask, then add calcium nitrate solution and sodium carbonate solution dropwise to the flask at the same time, and the reaction is performed at 25 ℃, the whole dropping process is 2h, and the nano calcium carbonate suspension is obtained.

[0034] 30.5g of barium nitrate, 11.5g of ethylene glycol, 25g of vitamin C, and 10g of disodium EDTA were dissolved in 150ml of water, and the mixed aqueous solution was put into the above-mentioned nano-calcium carbonate suspension and stirred evenly.

[0035] The polycarboxylate water reducing agent is obtained by radical copolymerization of acrylic acid and prenyl polyoxyethylen...

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Abstract

The invention discloses an anti-corrosion rust inhibitor for concrete and a preparation method of the anti-corrosion rust inhibitor. The raw materials of the anti-corrosion rust inhibitor comprise calcium nitrate, sodium carbonate, a polycarboxylic acid water reducing agent, ethylenediaminetetramethylene phosphonic acid, barium nitrate, ethylene glycol, vitamin C, ethylenediamine disodium tetraacetate and water. The preparation method comprises the steps: preparing a calcium nitrate solution and a sodium carbonate aqueous solution separately, dissolving the polycarboxylic acid water reducing agent and ethylenediamine tetramethylene phosphonic acid in water, placing the solution of the polycarboxylic acid water reducing agent and ethylenediamine tetramethylene phosphonic acid in a four-necked flask, then adding the calcium nitrate solution and the sodium carbonate solution to the flask at a constant rate dropwise and simultaneously, performing a reaction at 20-35 DEG C, completing thewhole dropping process within 1-3 hours, dissolving the barium nitrate, ethylene glycol, vitamin C and ethylenediamine disodium tetraacetate in water, putting the obtained solution into a nanometer calcium carbonate suspension, and performing even stirring. The concrete which is manufactured through the provided anti-corrosion rust inhibitor for concrete has good resistance to sulfate corrosion and a rust-resisting effect, good workability is achieved at a water-to-binder ratio, and construction operation is convenient.

Description

[0001] 【Technical field】 [0002] The invention belongs to the technical field of building material additives, in particular to a concrete anticorrosion and rust inhibitor and a preparation method thereof. [0003] 【Background technique】 [0004] Reinforced concrete structures can give full play to the advantages of both steel and concrete to withstand external loads, and are widely used in civil engineering structures such as medium and high-rise buildings, long-span bridges, tunnels, and subways. In these civil engineering structures, the durability of concrete is especially critical and often directly determines the lifespan of the building. Among the factors affecting the durability of concrete, one of the most important factors is chloride and sulfate corrosion. Chloride and sulfate corrosion will cause reinforced concrete structures to expand and crack, steel bars to corrode, etc., resulting in performance degradation and even failure of reinforced concrete structures, s...

Claims

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Application Information

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IPC IPC(8): C04B24/12C04B103/61
CPCC04B40/0039C04B2103/61C04B22/085C04B22/10C04B2103/302C04B24/12C04B24/026C04B24/06
Inventor 薛军鹏林亚杰陈新秀陈明建周长喜陈建科
Owner 福建省建筑科学研究院有限责任公司
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