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A method for resource utilization and energy utilization of garbage leachate

A leachate and energy-based technology, applied in chemical instruments and methods, contaminated groundwater/leachate treatment, oxidized water/sewage treatment, etc., can solve the problems of catalyst poisoning, poor industrial practicability, and high-concentration pollutant degradation ability Low-level problems, to achieve the effect of easy implementation and simple methods

Active Publication Date: 2021-12-10
长沙紫宸科技开发有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0007] 3) Biochemical treatment method: The process of removing the main pollutants in the leachate by biochemical treatment is currently researched more on ammonia stripping + UASB + SBR, and on this basis, ozone oxidation, coagulation and other processes are added, which are more typical It adopts coagulation + ammonia stripping + pH correction + anaerobic filter + SBR + ozone disinfection, but the process based on biochemical method has a poor treatment effect on leachate, and the degradation ability of microorganisms to high-concentration pollutants in leachate is very low , and the ammonia blown out brings secondary pollution;
[0008] 4) Chemical oxidation treatment method: such as using Feton reagent oxidation + ammonia stripping + coagulation precipitation + anaerobic + SBR + ClO 2 Oxidation + activated carbon adsorption process to treat leachate, this process actually mainly relies on chemical oxidants and activated carbon adsorption to remove pollutants, the operating cost is high, and there is actually secondary pollution;
[0009] 5) CTB process treatment method: that is, the method of "coagulation + low-temperature multi-effect evaporation + ammonia stripping + biochemical treatment" can be used to treat the garbage leachate to the national secondary emission standard, but it consumes a lot of energy and produces secondary pollutants. secondary pollution;
[0010] 6) Other methods: There are also catalytic oxidation methods, electro-oxidation methods, photo-oxidation methods, wet oxidation methods, etc. These methods have poor industrial practicability either because the catalyst is easily poisoned or because the power consumption is too large.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0045] The leachate is the concentrated liquid treated by a membrane method in a waste incineration power plant, which is brown, has a peculiar smell, and has a pH value of 8.3; commercially available hydrogen peroxide (concentration 6%) is used as the oxidant; phytic acid is used as the heavy metal ion precipitation and curing agent Select lithium chloride, cerium chloride, lanthanum chloride, titanyl sulfate, vanadium dichloride, strontium nitrate to be 5:4:3:2:1:1.8 by mass ratio as the functional catalytic element compound; according to the following steps Implement resource and energy utilization of leachate:

[0046] (1) Limited oxidative organic acidification: put the leachate in a reaction tank with a stirrer, adjust the pH value to 7, stir, add hydrogen peroxide equivalent to 7.2% of the concentrated liquid mass, and the oxidation reaction temperature is 20°C, the oxidation reaction The time is 1.5h, oxidize the medium and high molecular weight organic compounds in th...

Embodiment 2

[0052] The leachate is the leachate from the leachate pool of a waste incineration power plant that was pretreated to remove slag. It is brownish yellow, has a peculiar smell, and has a pH value of 5.5; commercially available chlorine dioxide is used as the oxidant; phytic acid is used as the precipitation and curing agent for heavy metal ions Select lithium nitrate, cerium nitrate, scandium nitrate, titanyl sulfate, ammonium metavanadate, strontium nitrate to be 5:5:2:2:1:1 by mass ratio as the functional catalytic element compound; implement leaching as follows Recycling and energy utilization of concentrate:

[0053] (1) Limited oxidation organic acidification: put the leachate in a reaction tank with a stirrer, adjust the pH value to 7, stir, add chlorine dioxide equivalent to 3.8% of the leachate mass, and the oxidation reaction temperature is 30°C. The reaction time is 1.0h, and the medium and high molecular weight organic compounds in the leachate are oxidized into orga...

Embodiment 3

[0057] The leachate was selected from a waste incineration power plant leach concentrate, brown black, with a peculiar smell, and a pH value of 6.5; self-made potassium ferrate was used as the oxidant; phytic acid was used as the heavy metal ion precipitation and curing agent; lithium nitrate, high Cerium chlorate, samarium nitrate, titanyl sulfate, vanadium dichloride, and cesium chloride are used as functional catalytic element compounds in a mass ratio of 4:4:2:2:1:0.2; commercially available potassium nitrate is used as a combustion aid; The resource and energy utilization of the leached concentrate is implemented as follows:

[0058](1) Limited oxidation organic acidification: put the leachate in a reaction tank with a stirrer, adjust the pH value to 7, stir, add potassium ferrate equivalent to 1.4% of the leachate mass, and the oxidation reaction temperature is 40°C. The oxidation reaction time is 0.6h, and the medium and high molecular weight organic compounds in the le...

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Abstract

A method for recycling waste leachate into energy, comprising the following steps: (1) placing the leachate in a reaction tank with a stirrer, adjusting the pH value to 6-7, stirring, adding an oxidant, generating an oxidation reaction, and then , adding a heavy metal ion precipitation curing agent, a curing reaction occurs, and the precipitate is filtered off to obtain a mixture of organic acid and organic acid salt; (2) adding a functional catalyst element compound to the mixture obtained in step (1), stirring, and reacting, The organic acid salt catalytic oxidation accelerator is obtained; (3) the organic acid salt catalytic oxidation accelerator obtained in step (2) is used for the clean combustion of domestic waste, or for the clean combustion of dewatered sludge in a waste incineration power plant; or for Clean combustion of domestic waste mixed with sludge in waste incineration power plants; or for clean combustion of coal. The method of the invention is simple and easy to implement, can effectively solve the problems that the leachate and its concentrate are difficult to degrade, and realize the utilization of resources and energy.

Description

technical field [0001] The invention relates to a sewage treatment technology, in particular to a method for utilizing garbage leachate as a resource and energy. Background technique [0002] my country's urban domestic waste has a lot of kitchen waste, high moisture content, and low calorific value. When disposing of urban domestic waste in waste incineration power plants, fresh waste must be stored in the waste storage pit for 3 to 7 days for fermentation and maturation, that is, let the living The organic matter in the garbage is decomposed, fermented, liquefied and leached to the bottom of the storage pit to achieve the purpose of leaching out water and increasing the calorific value, so as to ensure the normal operation of the subsequent incinerator. In the "Standards for Pollution Control of Domestic Garbage Incineration" (GB18485-2001), the water leached out in this process is called "leachate", which is characterized by high pollutant concentration, large changes in w...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C02F9/04C10L9/12F23J7/00C02F101/20C02F101/30C02F103/06
CPCC02F9/00C10L9/12F23J7/00C02F1/66C02F1/72C02F1/52C02F1/00C02F1/542C02F2101/20C02F2103/06C02F2101/30
Inventor 尹小林
Owner 长沙紫宸科技开发有限公司
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