A method for resource utilization and energy utilization of garbage leachate
A leachate and energy-based technology, applied in chemical instruments and methods, contaminated groundwater/leachate treatment, oxidized water/sewage treatment, etc., can solve the problems of catalyst poisoning, poor industrial practicability, and high-concentration pollutant degradation ability Low-level problems, to achieve the effect of easy implementation and simple methods
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Embodiment 1
[0045] The leachate is the concentrated liquid treated by a membrane method in a waste incineration power plant, which is brown, has a peculiar smell, and has a pH value of 8.3; commercially available hydrogen peroxide (concentration 6%) is used as the oxidant; phytic acid is used as the heavy metal ion precipitation and curing agent Select lithium chloride, cerium chloride, lanthanum chloride, titanyl sulfate, vanadium dichloride, strontium nitrate to be 5:4:3:2:1:1.8 by mass ratio as the functional catalytic element compound; according to the following steps Implement resource and energy utilization of leachate:
[0046] (1) Limited oxidative organic acidification: put the leachate in a reaction tank with a stirrer, adjust the pH value to 7, stir, add hydrogen peroxide equivalent to 7.2% of the concentrated liquid mass, and the oxidation reaction temperature is 20°C, the oxidation reaction The time is 1.5h, oxidize the medium and high molecular weight organic compounds in th...
Embodiment 2
[0052] The leachate is the leachate from the leachate pool of a waste incineration power plant that was pretreated to remove slag. It is brownish yellow, has a peculiar smell, and has a pH value of 5.5; commercially available chlorine dioxide is used as the oxidant; phytic acid is used as the precipitation and curing agent for heavy metal ions Select lithium nitrate, cerium nitrate, scandium nitrate, titanyl sulfate, ammonium metavanadate, strontium nitrate to be 5:5:2:2:1:1 by mass ratio as the functional catalytic element compound; implement leaching as follows Recycling and energy utilization of concentrate:
[0053] (1) Limited oxidation organic acidification: put the leachate in a reaction tank with a stirrer, adjust the pH value to 7, stir, add chlorine dioxide equivalent to 3.8% of the leachate mass, and the oxidation reaction temperature is 30°C. The reaction time is 1.0h, and the medium and high molecular weight organic compounds in the leachate are oxidized into orga...
Embodiment 3
[0057] The leachate was selected from a waste incineration power plant leach concentrate, brown black, with a peculiar smell, and a pH value of 6.5; self-made potassium ferrate was used as the oxidant; phytic acid was used as the heavy metal ion precipitation and curing agent; lithium nitrate, high Cerium chlorate, samarium nitrate, titanyl sulfate, vanadium dichloride, and cesium chloride are used as functional catalytic element compounds in a mass ratio of 4:4:2:2:1:0.2; commercially available potassium nitrate is used as a combustion aid; The resource and energy utilization of the leached concentrate is implemented as follows:
[0058](1) Limited oxidation organic acidification: put the leachate in a reaction tank with a stirrer, adjust the pH value to 7, stir, add potassium ferrate equivalent to 1.4% of the leachate mass, and the oxidation reaction temperature is 40°C. The oxidation reaction time is 0.6h, and the medium and high molecular weight organic compounds in the le...
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