Resource and energy utilization method of garbage leachate
A leachate and energy-based technology, which is applied in chemical instruments and methods, polluted groundwater/leachate treatment, oxidized water/sewage treatment, etc., can solve the problems of easy catalyst poisoning, poor industrial practicability, and poor leachate treatment effect, etc. problem, to achieve the effect of easy implementation and simple method
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Embodiment 1
[0045] The leachate is the concentrated liquid treated by a membrane method in a waste incineration power plant, which is brown, has a peculiar smell, and has a pH value of 8.3; commercially available hydrogen peroxide (concentration 6%) is used as the oxidant; phytic acid is used as the heavy metal ion precipitation and curing agent Select lithium chloride, cerium chloride, lanthanum chloride, titanyl sulfate, vanadium dichloride, strontium nitrate to be 5:4:3:2:1:1.8 by mass ratio as the functional catalytic element compound; according to the following steps Implement resource and energy utilization of leachate:
[0046] (1) Limited oxidative organic acidification: put the leachate in a reaction tank with a stirrer, adjust the pH value to 7, stir, add hydrogen peroxide equivalent to 7.2% of the concentrated liquid mass, and the oxidation reaction temperature is 20°C, the oxidation reaction The time is 1.5h, oxidize the medium and high molecular weight organic compounds in th...
Embodiment 2
[0052] The leachate is the leachate from the leachate pool of a waste incineration power plant that was pretreated to remove slag. It is brownish yellow, has a peculiar smell, and has a pH value of 5.5; commercially available chlorine dioxide is used as the oxidant; phytic acid is used as the precipitation and curing agent for heavy metal ions Select lithium nitrate, cerium nitrate, scandium nitrate, titanyl sulfate, ammonium metavanadate, strontium nitrate to be 5:5:2:2:1:1 by mass ratio as the functional catalytic element compound; implement leaching as follows Resource and energy utilization of concentrate:
[0053] (1) Limited oxidation organic acidification: put the leachate in a reaction tank with a stirrer, adjust the pH value to 7, stir, add chlorine dioxide equivalent to 3.8% of the leachate mass, and the oxidation reaction temperature is 30°C. The reaction time is 1.0h, and the medium and high molecular weight organic compounds in the leachate are oxidized into organ...
Embodiment 3
[0057] The leachate was selected from a waste incineration power plant leach concentrate, brown black, with a peculiar smell, and a pH value of 6.5; self-made potassium ferrate was used as the oxidant; phytic acid was used as the heavy metal ion precipitation and curing agent; lithium nitrate, high Cerium chlorate, samarium nitrate, titanyl sulfate, vanadium dichloride, and cesium chloride are used as functional catalytic element compounds in a mass ratio of 4:4:2:2:1:0.2; commercially available potassium nitrate is used as a combustion aid; The resource and energy utilization of the leached concentrate is implemented as follows:
[0058](1) Limited oxidation organic acidification: put the leachate in a reaction tank with a stirrer, adjust the pH value to 7, stir, add potassium ferrate equivalent to 1.4% of the leachate mass, and the oxidation reaction temperature is 40°C. The oxidation reaction time is 0.6h, and the medium and high molecular weight organic compounds in the le...
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