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Method for preparing high-performance reverse osmosis membrane based on construction of multiple network structure

A technology of network structure and reverse osmosis membrane, which is applied in the direction of semipermeable membrane separation, chemical instruments and methods, membrane technology, etc., can solve the problems of less reverse osmosis membrane, membrane surface pollution, oxidation, etc., and achieve good reproducibility and improvement Effect of water flux, good retention

Inactive Publication Date: 2019-10-08
浙江特分环境技术有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Compared with other reverse osmosis membranes, polyamide reverse osmosis composite membranes have obvious advantages, but they still face three problems: the mutually restrictive relationship between flux and salt ion rejection, membrane surface contamination and chlorine oxidation, etc.
[0004] The self-aggregation-composite technology of dopamine (DOPA) biomimetic adhesion has become a research hotspot in the surface modification of materials today, but there are few studies on the use of this technology to construct network structures and further prepare reverse osmosis membranes.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0024] 0.5% DOPA and 0.5% PVA aqueous solution were prepared and coated on the polysulfone bottom membrane in advance. After drying in the shade, prepare an aqueous solution of m-phenylenediamine with a mass fraction of 2%, add triethylamine hydrochloride with a mass fraction of 2%, and triethylamine with a mass fraction of 0.5%, mix evenly, and evenly coat the diaphragm. After drying in the shade, configure 0.2% trimesoyl chloride (TMC) oil phase solution, evenly coat the diaphragm, and heat-treat in an oven at 120°C for 5 minutes. The high-flux seawater membrane based on the new buffer system prepared by this method was tested at a test pressure of 1.05 MPa, a concentrated water flow rate of 1.0 L / min, an ambient temperature of 25 °C, and a pH value of 6.5-7.5 in concentrated water. The water is a sodium chloride aqueous solution, and under the experimental conditions of a concentration of 1000ppm, the measured water flux is 65LMH, and the desalination rate is 99.7%.

Embodiment 2

[0026] 0.7% DOPA and 0.5% PVA aqueous solutions were prepared and coated on the polysulfone bottom membrane in advance. After drying in the shade, prepare an aqueous solution of m-phenylenediamine with a mass fraction of 2%, add triethylamine hydrochloride with a mass fraction of 2%, and triethylamine with a mass fraction of 0.5%, mix evenly, and evenly coat the diaphragm. After drying in the shade, configure 0.2% trimesoyl chloride (TMC) oil phase solution, evenly coat the diaphragm, and heat-treat in an oven at 120°C for 5 minutes. The high-flux seawater membrane based on the new buffer system prepared by this method was tested at a test pressure of 1.05 MPa, a concentrated water flow rate of 1.0 L / min, an ambient temperature of 25 °C, and a pH value of 6.5-7.5 in concentrated water. The water is a sodium chloride aqueous solution, and under the experimental conditions of a concentration of 1000ppm, the measured water flux is 69LMH, and the desalination rate is 99.7%.

Embodiment 3

[0028] 0.5% DOPA and 0.8% PVA aqueous solution were prepared and coated on the polysulfone bottom membrane in advance. After drying in the shade, prepare an aqueous solution of m-phenylenediamine with a mass fraction of 2%, add triethylamine hydrochloride with a mass fraction of 2%, and triethylamine with a mass fraction of 0.5%, mix evenly, and evenly coat the diaphragm. After drying in the shade, configure 0.2% trimesoyl chloride (TMC) oil phase solution, evenly coat the diaphragm, and heat-treat in an oven at 120°C for 5 minutes. The high-flux seawater membrane based on the new buffer system prepared by this method was tested at a test pressure of 1.05 MPa, a concentrated water flow rate of 1.0 L / min, an ambient temperature of 25 °C, and a pH value of 6.5-7.5 in concentrated water. The water is a sodium chloride aqueous solution, and under the experimental conditions of a concentration of 1000ppm, the measured water flux is 66LMH, and the desalination rate is 99.7%.

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Abstract

The invention is intended to provide a method for preparing a high-performance reverse osmosis membrane based on construction of multiple network structure. Before aqueous application, a mixed solution of dopamine and water-soluble macromolecules is applied to a base membrane, so that a three-dimensional network is constructed on the base membrane. The preparation process of the high-performance reverse osmosis membrane has the need for firstly applying the aqueous solution with dopamine and one or more types of water-soluble macromolecules to a polysulfone base membrane so that dopamine is self-polymerized to form a membrane; the water-soluble macromolecules are doped in the polydopamine membrane to form a three-dimensional network structure; the aqueous solution with a polyamine is applied then; an oil solution with poly-acyl chloride dissolved in IsoparL (isoparaffin solvent) is applied; the reverse osmosis membrane is prepared by interfacial polymerization. The ingredients of a coating solution herein and their types are optimally selected, the post-treatment temperature is regulated, and therefore, the high-performance reverse osmosis membrane is prepared.

Description

technical field [0001] The invention belongs to the technical field of reverse osmosis composite membranes, and in particular relates to a high-performance reverse osmosis membrane preparation method based on the construction of multiple network structures. [0002] technical background [0003] The core of reverse osmosis technology is high-performance reverse osmosis composite membrane. As the basis and core of separation membrane technology, functional membrane materials have always been the focus of membrane technology development in developed countries such as the United States and Japan, especially the research on high-performance reverse osmosis composite membranes. It is even more important. Now the general reverse osmosis membrane is a polyamide membrane obtained by interfacial polymerization. Due to its excellent separation performance, polyamide reverse osmosis composite membrane has become the mainstream application membrane for seawater desalination by reverse o...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01D71/68B01D71/06B01D69/12B01D67/00
CPCB01D67/0006B01D69/125B01D71/06B01D71/68
Inventor 刘炜
Owner 浙江特分环境技术有限公司
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