Method for preparing high-performance reverse osmosis membrane based on construction of multiple network structure
A technology of network structure and reverse osmosis membrane, which is applied in the direction of semipermeable membrane separation, chemical instruments and methods, membrane technology, etc., can solve the problems of less reverse osmosis membrane, membrane surface pollution, oxidation, etc., and achieve good reproducibility and improvement Effect of water flux, good retention
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Embodiment 1
[0024] 0.5% DOPA and 0.5% PVA aqueous solution were prepared and coated on the polysulfone bottom membrane in advance. After drying in the shade, prepare an aqueous solution of m-phenylenediamine with a mass fraction of 2%, add triethylamine hydrochloride with a mass fraction of 2%, and triethylamine with a mass fraction of 0.5%, mix evenly, and evenly coat the diaphragm. After drying in the shade, configure 0.2% trimesoyl chloride (TMC) oil phase solution, evenly coat the diaphragm, and heat-treat in an oven at 120°C for 5 minutes. The high-flux seawater membrane based on the new buffer system prepared by this method was tested at a test pressure of 1.05 MPa, a concentrated water flow rate of 1.0 L / min, an ambient temperature of 25 °C, and a pH value of 6.5-7.5 in concentrated water. The water is a sodium chloride aqueous solution, and under the experimental conditions of a concentration of 1000ppm, the measured water flux is 65LMH, and the desalination rate is 99.7%.
Embodiment 2
[0026] 0.7% DOPA and 0.5% PVA aqueous solutions were prepared and coated on the polysulfone bottom membrane in advance. After drying in the shade, prepare an aqueous solution of m-phenylenediamine with a mass fraction of 2%, add triethylamine hydrochloride with a mass fraction of 2%, and triethylamine with a mass fraction of 0.5%, mix evenly, and evenly coat the diaphragm. After drying in the shade, configure 0.2% trimesoyl chloride (TMC) oil phase solution, evenly coat the diaphragm, and heat-treat in an oven at 120°C for 5 minutes. The high-flux seawater membrane based on the new buffer system prepared by this method was tested at a test pressure of 1.05 MPa, a concentrated water flow rate of 1.0 L / min, an ambient temperature of 25 °C, and a pH value of 6.5-7.5 in concentrated water. The water is a sodium chloride aqueous solution, and under the experimental conditions of a concentration of 1000ppm, the measured water flux is 69LMH, and the desalination rate is 99.7%.
Embodiment 3
[0028] 0.5% DOPA and 0.8% PVA aqueous solution were prepared and coated on the polysulfone bottom membrane in advance. After drying in the shade, prepare an aqueous solution of m-phenylenediamine with a mass fraction of 2%, add triethylamine hydrochloride with a mass fraction of 2%, and triethylamine with a mass fraction of 0.5%, mix evenly, and evenly coat the diaphragm. After drying in the shade, configure 0.2% trimesoyl chloride (TMC) oil phase solution, evenly coat the diaphragm, and heat-treat in an oven at 120°C for 5 minutes. The high-flux seawater membrane based on the new buffer system prepared by this method was tested at a test pressure of 1.05 MPa, a concentrated water flow rate of 1.0 L / min, an ambient temperature of 25 °C, and a pH value of 6.5-7.5 in concentrated water. The water is a sodium chloride aqueous solution, and under the experimental conditions of a concentration of 1000ppm, the measured water flux is 66LMH, and the desalination rate is 99.7%.
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