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Amphoteric early-strength polycarboxylate superplasticizer mother solution for C30 concrete

A technology of polycarboxylic acid and water reducing agent, which is applied in the field of building materials and concrete admixtures, can solve the problems of inability to exert water reducing effect, achieve good workability, promote hydration process, and improve the effect of limitations

Inactive Publication Date: 2019-10-08
HUBEI UNIV OF TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Normally, the cement particles will be positively charged, so the water reducer molecules should be made anionic to interact with it, and the sand with high mud content means that the clay content is high, and the clay particles are negatively charged, so the single anion Type water reducing agent can not play a good water reducing effect

Method used

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  • Amphoteric early-strength polycarboxylate superplasticizer mother solution for C30 concrete
  • Amphoteric early-strength polycarboxylate superplasticizer mother solution for C30 concrete

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0039] The polycarboxylate superplasticizer masterbatch comprises the following components in parts by weight:

[0040] 330 parts of allyl polyoxyethylene ether with a molecular weight of 4000, 22 parts of acrylic acid, 18 parts of a composition of DMC and DAC with a mass ratio of 2:1, 2 parts of 27.5% industrial grade hydrogen peroxide, 3 parts of sodium vinyl sulfonate, alkyl 2 parts of acrylate phosphate, 8 parts of 4-(acrylamide) benzoic acid, 1 part of sodium dithionite, 0.8 part of thioglycolic acid, 12 parts of industrial grade sodium hydroxide liquid caustic soda with a mass ratio of 30-32%, and the remainder is water , with a total mass of 1,000 parts, the amphoteric early-strength polycarboxylate superplasticizer mother liquor for C30 concrete with a finished product mass fraction of 40% after preparation

[0041] The specific preparation process of the amphoteric early-strength polycarboxylate superplasticizer mother liquor for C30 concrete is as follows:

[0042] ...

Embodiment 2

[0047] The polycarboxylate superplasticizer masterbatch comprises the following components in parts by weight:

[0048] 339 parts of 4000 molecular weight methallyl polyoxyethylene ether, 25 parts of acrylic acid, 11 parts of acryloyloxyethyl trimethyl ammonium chloride (DAC), 5 parts of 27.5% industrial grade hydrogen peroxide, 5.5 parts of sodium acrylsulfonate , 4 parts of methacryloyloxyethyl phosphate, 4 parts of amide small monomers, 0.4 parts of sodium dithionite, 0.4 parts of mercaptopropionic acid, 6 parts of industrial grade sodium hydroxide liquid caustic soda with a mass ratio of 30-32%, The rest is water, the total mass is 1000 parts, and the finished product mass fraction is 40% C30 amphoteric early-strength polycarboxylate superplasticizer mother liquor for concrete after preparation.

[0049] The specific preparation process of the amphoteric early-strength polycarboxylate superplasticizer mother liquor for C30 concrete is as follows:

[0050] 1. Mix 339 parts...

Embodiment 3

[0055] The polycarboxylate superplasticizer masterbatch comprises the following components in parts by weight:

[0056] 331 parts of 4000 molecular weight isopentenol polyoxyethylene ether, 23 parts of acrylic acid, 12 parts of tetrahydroxymethyl phosphonium sulfate (THPS), 3.5 parts of 27.5% industrial grade hydrogen peroxide, 6 parts of sodium styrene sulfonate, ethylene glycol methyl 4 parts of acrylate phosphate ester, 7 parts of amide small monomer, 0.9 part of sodium formaldehyde sulfoxylate, 0.8 part of mercaptopropionic acid, 11 parts of industrial grade sodium hydroxide liquid caustic soda with a mass ratio of 30-32%, and the rest is Water, the total mass is 1000 parts, and the C30 amphoteric early-strength polycarboxylate superplasticizer mother liquor for concrete with a finished product mass fraction of 40% after preparation.

[0057] The specific preparation process of the amphoteric early-strength polycarboxylate superplasticizer mother liquor for C30 concrete is...

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Abstract

The invention provides an amphoteric early-strength polycarboxylate superplasticizer mother solution for C30 concrete. The polycarboxylate superplasticizer mother solution comprises, by weight, 330-339 parts of polyether macromonomers with the molecular weight being 4000, 22-25 parts of acrylic acid, 11-18 parts of quaternary ammonium and quaternary phosphorus cation micromonomers, 2-5 parts of 27.5% industrial-grade hydrogen peroxide, 3-6 parts of unsaturated sulfonate, 2-4 parts of phosphate functional monomers, 4-8 parts of amide micromonomers, 0.4-1 part of reducing agent, 6-12 parts of caustic soda liquid, 0.4-0.8 part of chain transfer agent and the balance water, wherein the total weight of the components is 1000 parts. The mass fraction of the polycarboxylate superplasticizer mother solution is 40%, and the acid-ether ratio of the mother solution is controlled to be 3.7-4.1. Compared with relatively-low-molecular-weight polyether macromonomers such as polyether macromonomers with the molecular weight being 2400 used by existing common polycarboxylate superplasticizers, the polyether macromonomers with the molecular weight being 4000 and used by the polycarboxylate superplasticizer mother solution have cost advantages and can meet the production requirements of low cost and high effectiveness.

Description

technical field [0001] The invention relates to the technical field of building materials and concrete admixtures, in particular to a mother liquor of an amphoteric early-strength polycarboxylate superplasticizer for C30 concrete. Background technique [0002] With the continuous development of the concrete industry, the water reducing agents used to improve the workability of concrete are becoming more and more diverse. The water reducing agents currently on the market can be divided into lignin-based, naphthalene-based, and amine-based according to their chemical composition. Sulfonates, polycarboxylates, resins, etc. Compared with other types of water reducers, polycarboxylate water reducers have superior performance, so they are more widely used. [0003] Polycarboxylate superplasticizer is an anionic surfactant containing carboxyl copolymer in its molecular structure. When used, the water reducing rate can reach about 25%-40%, and it has excellent slump retention effec...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08F283/06C08F220/06C08F228/02C08F230/02C04B24/16C04B103/30
CPCC04B24/165C04B2103/302C08F283/065C08F220/06
Inventor 柯凯姚恒严明陈艳林熊焰
Owner HUBEI UNIV OF TECH
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