Novel composite carbon source used for denitrification, and preparation method and applications thereof
A compound carbon source and denitrification technology, applied in chemical instruments and methods, anaerobic digestion treatment, water pollutants, etc., can solve the problem that straw pyrolysis residue cannot be utilized as a resource, so as to reduce the amount of organic matter and improve Efficiency, the effect of reducing difficulty
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Embodiment 1
[0038]A company uses crop straws to prepare high-quality fuel oil, adopts a combined process of rapid pyrolysis + hydrogenation catalysis, and the process wastewater produced is mainly pyrolysis liquid residue. The main components of the pyrolysis liquid residue are: 82% water, 6.0% methanol , 5% acetic acid, 1.5% ethanol, 0.2% butanol, 0.25% acetone, 3% esters, 1% inorganic salts.
[0039] figure 1 It is a flow chart of the preparation process of the novel composite carbon source of the present invention, and the specific steps of the preparation method are as follows:
[0040] 1) Perform microfiltration treatment on 100L of crop straw pyrolysis residue, and control the water production rate of the microfiltration membrane at 85%; the water produced by the microfiltration membrane enters the electrodialysis treatment system;
[0041] 2) The water produced by the microfiltration membrane enters the electrodialysis treatment system, 2% sodium sulfate is used as the polar liqui...
Embodiment 2
[0046] The agricultural stalks used in this project are cassava stalks and corn stalks. In the process of preparing high-quality bio-oil, pyrolysis liquid residue process wastewater is produced. The main components of the pyrolysis liquid are: 92% water, 4% methanol, 6% acetic acid, 1.8% ethanol, 0.5% butanol, 0.05%-0.6% acetone, 0.65% esters, 1.1% inorganic salts.
[0047] The preparation method of the novel composite carbon source for denitrification of the present invention comprises the following steps:
[0048] 1) Perform microfiltration treatment on 50L of crop straw pyrolysis residue, control the water production rate of the microfiltration membrane at 95%, and the water produced by the microfiltration membrane enters the electrodialysis treatment system;
[0049] 2) The water produced by the microfiltration membrane enters the electrodialysis treatment system, 2% sodium sulfate is used as the polar liquid chamber, and the volume ratio of the solution volume of the fres...
Embodiment 3
[0053] The agricultural stalks used in this project are corn stalks, wheat stalks, and soybean stalks. High-quality bio-oil is prepared by a combined process of rapid pyrolysis + hydrogenation catalysis. The main components of the pyrolysis liquid residue produced during the production process are: 88% water, 4.5% methanol, 3% acetic acid, 2.5% ethanol, 0.35% butanol, 0.25% acetone, 0.35% esters, 1.1% inorganic salts.
[0054] The preparation method of the novel composite carbon source for denitrification of the present invention comprises the following steps:
[0055] 1) Microfiltration treatment is performed on 10L of crop straw pyrolysis residue, and the water production rate of the microfiltration membrane is controlled at 90%; the water produced by the microfiltration membrane enters the electrodialysis treatment system;
[0056] 2) The water produced by the microfiltration membrane enters the electrodialysis treatment system. 2% sodium sulfate is used as the polar liquid...
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