Fluoride-free environment-friendly efficient aqueous film-forming foam extinguishing agent and preparation method thereof

A foam fire extinguishing agent, fire extinguishing agent technology, applied in the direction of fire prevention equipment, etc., can solve the problems of environmental hazards, unstable foaming performance, etc., and achieve the effects of low surface tension, reduced liquid film thickness, and reduced surface tension

Inactive Publication Date: 2020-01-03
北京南瑞怡和环保科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] Therefore, the technical problem to be solved by the present invention is to overcome the technical problems that the aqueous film-forming foam fire extinguishing agent in the prior art is harmful to the environment and the foaming performance is unstable, and to provide a fluorine-free fire extinguishing agent that is both safe and environmentally friendly and has sufficient fire extinguishing efficiency. Environment-friendly and high-efficiency aqueous film-forming foam fire extinguishing agent composition and its preparation and application

Method used

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  • Fluoride-free environment-friendly efficient aqueous film-forming foam extinguishing agent and preparation method thereof
  • Fluoride-free environment-friendly efficient aqueous film-forming foam extinguishing agent and preparation method thereof
  • Fluoride-free environment-friendly efficient aqueous film-forming foam extinguishing agent and preparation method thereof

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Experimental program
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Effect test

Embodiment 1

[0036] This embodiment discloses a preparation method of a fire extinguishing agent composition, comprising the following steps:

[0037] S1: Add 753 kg of industrial soft water to the reaction kettle, and then add 5 kg of polyether-modified polysiloxane silicone surfactant 8008 and 5 kg of polyether trisiloxane silicone surfactant 8030 under mechanical stirring; Hydrogen non-ionic surfactant alkyl glycoside APG 10kg, hydrocarbon zwitterionic surfactant cocamidopropyl betaine CAB 30kg, hydrocarbon anionic surfactant fatty alcohol polyoxyethylene ether sodium sulfate AES 20kg, urea 100kg, fully dissolved to form a homogeneous solution;

[0038] S2: Thickener xanthan gum 1kg, anti-burning agent polyethylene glycol 5kg, hydroxyethyl cellulose 5kg, modified starch 5kg and carboxymethyl cellulose 5kg, preservative sodium benzoate 5kg, chelating agent ethylenediamine Disodium tetraacetate 1kg and other components are mixed with co-solvent ethylene glycol 50kg, slowly poured into th...

Embodiment 2

[0041] This embodiment discloses a preparation method of a fire extinguishing agent composition, comprising the following steps:

[0042]S1: Add 285kg of industrial soft water to the reaction kettle, and then add polyether modified polysiloxane type silicone surfactant 8008 10kg, silicone surfactant 2235 10kg, silicone surfactant 521110kg, Silicone surfactant 0193 10kg; polyether trisiloxane silicone surfactant 8030 5kg, silicone surfactant 2232 5kg; hydrocarbon nonionic surfactant alkyl glycoside APG 100kg, hydrocarbon zwitterion Type surfactant cocamidopropyl betaine CAB 200kg, hydrocarbon anionic surfactant fatty alcohol polyoxyethylene ether sodium sulfate AES 50kg, sodium α-olefin sulfonate AOS 50kg, sodium lauryl sulfate K12 50kg; urea 50kg, fully dissolved to form a homogeneous solution;

[0043] S2: 10 kg of anti-scalding agent polyethylene glycol, 10 kg of hydroxyethyl cellulose, 10 kg of modified starch, 10 kg of carboxymethyl cellulose, 15 kg of preservative sodium...

Embodiment 3

[0046] This embodiment discloses a preparation method of a fire extinguishing agent composition, comprising the following steps:

[0047] S1: Add 398kg of industrial soft water to the reaction kettle, and then add 20kg of silicone surfactant 2235, 20kg of silicone surfactant 5211 under mechanical stirring; 80kg of hydrocarbon non-ionic surfactant APG, hydrocarbon amphoteric Ionic surfactant cocamidopropyl betaine CAB150kg, hydrocarbon anionic surfactant fatty alcohol polyoxyethylene ether sodium sulfate AES 120kg; urea 80kg, fully dissolved to form a homogeneous solution;

[0048] S2: Mix anti-scalding agent polyethylene glycol 8kg, hydroxyethyl cellulose 8kg, modified starch 8kg and carboxymethyl cellulose 8kg, preservative sodium benzoate 12kg, chelating agent edetate disodium 8kg and other ingredients with 80kg of co-solvent ethylene glycol was mixed, slowly poured into the homogeneous solution in step S1 under stirring conditions, and stirred for 2 hours to obtain a clear ...

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Abstract

The invention relates to the technical field of fire extinguishing agents, in particular to a fire extinguishing agent composition, and a preparation method and application thereof. The fire extinguishing agent composition comprises an organic silicon surfactant, a hydrocarbon surfactant, an organic cosolvent, a foam additive and the like. The foam extinguishing agent has main advantages of not containing a fluorocarbon surfactant, and a polyether modified polysiloxane type organic silicon surfactant and/or a polyether trisiloxane organic silicon surfactant are/is used; on the basis of environmental protection, a compound of an anionic hydrocarbon surfactant, a nonionic hydrocarbon surfactant and an amphoteric hydrocarbon surfactant is adopted for compounding, so that better foam performance and fire extinguishing performance can be achieved; through joint adjustment and dosage matching of multiple components, low surface tension, good foaming performance and foam stabilizing performance and efficient fire extinguishing performance are achieved, and the defect that foaming performance and foam stabilizing performance of an organosilicon surfactant is relatively poor is overcome. .The fire extinguishing agent composition can achieve spreading boundary on an oil surface, can be degraded easily, is environmentally friendly, and is often applied to extinguishing oil fire.

Description

technical field [0001] The invention relates to the technical field of fire extinguishing agents, in particular to a fluorine-free, environment-friendly and high-efficiency aqueous film-forming foam fire extinguishing agent composition and its preparation and application. Background technique [0002] Foam fire extinguishing agent is a commonly used fire extinguishing agent for fire control. The main component of traditional aqueous film-forming foam fire extinguishing agent is fluorocarbon surfactant, which can significantly reduce the surface tension, so that the fire extinguishing agent can use the "liquid phase injection" method to extinguish large-scale fire extinguishing agents. Oil product storage tank fires can also be used in combination with dry powder fire extinguishing agents. The fire extinguishing speed is one-third faster than that of protein foam fire extinguishing agents, but it is difficult to degrade in the environment after use; among them, fluorine-contai...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): A62D1/02A62D1/04
CPCA62D1/0042A62D1/0071
Inventor 郭王勇鞠振福靳昕吴刘锁张建成李鹏颜庆祥徐泽强李晓锐朱琳
Owner 北京南瑞怡和环保科技有限公司
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