Method for enhancing fluorescence intensity of copper nano-cluster

A fluorescence intensity, copper nanotechnology, applied in the field of metal nanocluster materials, can solve the problems of limited fluorescence intensity enhancement, unfavorable environmental protection, etc., and achieve the effect of expanding the fluorescence emission range, avoiding pollution and damage, and enhancing fluorescence intensity.

Active Publication Date: 2020-01-24
ANHUI UNIVERSITY
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Problems solved by technology

Most of the above-mentioned fluorescent materials use gold nanoclusters as raw materials, and the degree of enhancement of fluorescence intensity is limited. In addition, solvents such as methanol are used in the synthesis process, which is not conducive to environmental protection requirements; according to the material display, gold nanoclusters are orange, There are limitations during use

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  • Method for enhancing fluorescence intensity of copper nano-cluster
  • Method for enhancing fluorescence intensity of copper nano-cluster
  • Method for enhancing fluorescence intensity of copper nano-cluster

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Embodiment 1

[0028] 1. Materials

[0029] The methods used in this example are conventional methods known to those skilled in the art unless otherwise specified, and the reagents and other materials used are all commercially available products unless otherwise specified.

[0030] 2. Method

[0031] 2.1 Synthesis of copper nanocluster powder

[0032] Take the copper salt and the complexing agent containing carboxyl group in ultrapure water, adjust the pH to 4, add a poor solvent and a reducing agent, mix evenly, and centrifugally dry the resulting precipitate to obtain copper nano-cluster powder.

[0033] It should be noted that the copper salt is copper sulfate, copper nitrate, copper chloride, copper acetate or cuprous cyanide, and the carboxyl-containing complexing agent is glutathione, cysteine, thioglycolic acid, Mercaptopropionic acid, p-mercaptobenzoic acid, glycine or protein, the poor solvent is ethanol, isopropanol or propanol, and the reducing agent is hydrazine hydrate, sodium...

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Abstract

The invention relates to a method for enhancing the fluorescence intensity of a copper nano-cluster. The method comprises: synthesizing copper nano-cluster powder, and then generating a composite material of the copper nano-cluster and a prussian blue analogue in situ from the copper nano-cluster powder, a transition metal salt solution and a transition metal cyanide. According to the invention, the copper nano-cluster and the prussian blue analogue are mutually combined to form the composite material of the copper nano-cluster and the prussian blue analogue, so that the the fluorescence intensity of the copper nanocluster is enhanced due to the confinement effect of the prussian blue analogue, and in the composite material, the copper nano-cluster is still kept in a dispersed state.

Description

technical field [0001] The invention belongs to the technical field of metal nano-cluster materials, and in particular relates to a method for enhancing the fluorescence intensity of copper nano-clusters. Background technique [0002] Fluorescent metal nanoclusters have attracted much attention as a new type of fluorescent nanomaterials. Metal nanoclusters refer to molecular-level aggregates composed of several to hundreds of metal atoms under the protection of certain molecular layers. Due to their unique physical, electrical, and optical properties, metal nanoclusters have shown promising applications in fields such as single-molecule optoelectronics, catalysis, bioimaging, and sensors. At present, most studies mainly focus on gold, silver and their alloy nanoclusters. As we all know, copper is more abundant and cheap in the earth's crust than gold and silver, so it is widely used in human's daily life. However, relatively little research has been done on copper nanoclu...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C07F1/08C09K11/06C09K11/60B82Y20/00B82Y30/00B82Y40/00G01N21/64
CPCC07F1/005C09K11/06C09K11/60B82Y20/00B82Y30/00B82Y40/00G01N21/6428C09K2211/188
Inventor 杜袁鑫史宏宇
Owner ANHUI UNIVERSITY
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