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One-dimensional silver cluster coordination polymer and preparation method and application thereof

A technology of coordination polymers and silver clusters, which is applied in chemical instruments and methods, semiconductor/solid-state device manufacturing, electrical components, etc., can solve the problems of long time consumption and poor stability of silver-sulfur clusters, and achieve no inertness Gas protection, simple and easy reaction operation, and high reaction yield

Active Publication Date: 2020-02-28
HUAQIAO UNIVERSITY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

These synthetic methods have the problems of long time-consuming and poor stability of the obtained silver-sulfur clusters

Method used

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  • One-dimensional silver cluster coordination polymer and preparation method and application thereof
  • One-dimensional silver cluster coordination polymer and preparation method and application thereof
  • One-dimensional silver cluster coordination polymer and preparation method and application thereof

Examples

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Embodiment 1

[0033] A preparation method of a one-dimensional silver cluster coordination polymer, comprising the following steps:

[0034] Step 1. Dissolve 70 mg of silver nitrate in 4 mL of water at room temperature to obtain a silver salt solution;

[0035] Step 2. Dissolve 180 mg of 4,4'-dithiobipyridine in 4 mL of N,N'-dimethylformamide solvent at room temperature to obtain a ligand solution;

[0036] Step 3, adding the silver salt solution obtained in step 1 to the ligand solution obtained in step 2 to form a mixed solution;

[0037] Step 4, put the mixed solution obtained in step 3 into a quartz reaction bottle, seal it and carry out microwave heating reaction, the reaction temperature is 45 ° C, and the reaction time is 20 min;

[0038] Step 5. After the reaction is completed, the reaction system is cooled to room temperature, and the solution obtained from the reaction is sequentially filtered, rotary evaporated, and vacuum-dried at 45°C and a vacuum degree of 133Pa to obtain a r...

Embodiment 2

[0040] A preparation method of a one-dimensional silver cluster coordination polymer, comprising the following steps:

[0041] Step 1. Dissolve 270 mg of silver trifluoroacetate in 8 mL of water at room temperature to obtain a silver salt solution;

[0042] Step 2. Dissolve 540 mg of 4,4'-dithiobipyridine in 8 mL of N,N'-dimethylformamide solvent at room temperature to obtain a ligand solution;

[0043] Step 3, adding the silver salt solution obtained in step 1 to the ligand solution obtained in step 2 to form a mixed solution;

[0044] Step 4, put the mixed solution obtained in step 3 into a quartz reaction bottle, seal it and carry out microwave heating reaction, the reaction temperature is 60 ° C, and the reaction time is 10 min;

[0045] Step 5. After the reaction is completed, the reaction system is cooled to room temperature, and the solution obtained from the reaction is sequentially filtered, rotary evaporated, and vacuum-dried at 45°C and a vacuum degree of 133Pa to ...

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Abstract

The invention discloses a one-dimensional silver cluster coordination polymer. The molecular formula of the one-dimensional silver cluster coordination polymer is [Ag(CS<0.5>N<0.25>H<1.25>)<4>]<n>, wherein n is a positive integer, and CS<0.5>N<0.25>H<1.25> is a 4-pyridine protonated thiol ligand. The invention also discloses a preparation method of the one-dimensional silver cluster coordination polymer. The one-dimensional silver cluster coordination polymer is prepared through in-situ synthesis of a soluble silver salt and 4,4'-dithiopyridine ligand under microwave reaction conditions, has the advantages of usage of easily-available raw materials, simple and feasible reaction operation, no need for inert gas shielding, high reaction yield, capability of realizing batch production and thelike, and is expected to be applied to luminescent materials in luminescent devices.

Description

technical field [0001] The invention relates to the technical field of organic coordination compounds, in particular to a one-dimensional silver cluster coordination polymer and its preparation method and application. Background technique [0002] In recent years, metal clusters / polymers have attracted extensive attention from scientists due to their novel structures and potential applications in the fields of catalysis, biomarkers, biosensing and luminescence. Among the metal clusters, the multifunctional silver clusters with unique structure and excellent performance are the research hotspots in the fields of chemistry and biology. On the other hand, the classification of OLED light-emitting materials can be divided into fluorescent light-emitting materials and phosphorescent light-emitting materials according to the light-emitting method. Among them, phosphorescent materials usually need to use the spin-orbit coupling of heavy metal atoms to make the recombination rate o...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08G83/00C09K11/06H01L51/50H01L51/54
CPCC08G83/008C09K11/06C09K2211/188H10K85/111H10K85/30H10K50/11
Inventor 骆耿耿钟丽娜林金清
Owner HUAQIAO UNIVERSITY
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