Antibacterial flame-retardant fibers and preparation method of fabric of antibacterial flame-retardant fibers

A technology of flame retardant fibers and flame retardant fabrics, applied in the field of preparation of antibacterial and flame retardant fibers, can solve the problems of uneven mixing of flame retardants and antibacterial agents, low moisture regain of polyester fibers, secondary personal injury, etc., and achieve antibacterial resistance. Long-lasting and stable combustion performance, excellent mechanical properties, and the effect of alleviating resource shortages

Active Publication Date: 2020-04-17
SHAANXI YUANFENG TEXTILE TECH RES
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Polyester-based fibers will produce molten droplets when used, causing secondary damage to the human body. At the same time, polyester fibers have low moisture regain and poor fabric comfort; Chinese patent "Preparation method of antibacterial and flame-retardant protein viscose fiber", publication : CN102304783A, in the process of preparing antibacterial flame-retardant fiber, just flame retardant slurry, protein glue and chitosan solution are mixed evenly with viscose spinning solution, what adopt is the mixing of physical method, easily cause flame retardant Inhomogeneous mixing with antibacterial agents, resulting in unstable antibacterial and flame retardant functions of fibers, and defects such as not being resistant to washing; the flame retardant fabric developed by antibacterial and flame retardant acrylic fibers has a "smoldering" phenomenon, resulting in a decrease in the flame retardant performance of the fabric

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
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  • Antibacterial flame-retardant fibers and preparation method of fabric of antibacterial flame-retardant fibers
  • Antibacterial flame-retardant fibers and preparation method of fabric of antibacterial flame-retardant fibers
  • Antibacterial flame-retardant fibers and preparation method of fabric of antibacterial flame-retardant fibers

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preparation example Construction

[0042] The preparation method of a kind of antibacterial flame-retardant fiber that the present invention relates to specifically implements according to the following steps:

[0043] Step 1, collecting the pure white cotton waste textiles, and then washing and drying the collected white pure cotton waste textiles and crushing them;

[0044] Step 2, bleaching the crushed natural white pure cotton waste textiles with hydrogen peroxide, the mass fraction of hydrogen peroxide is 8-12%, the treatment temperature is controlled at 60-90°C, bleaching for 50-80 minutes, and then drying to obtain cellulose raw material;

[0045] Step 3, treating the cellulose raw material obtained in step 2 with 10-20% sodium hydroxide or 45% sodium carbonate solution for 1-3 hours, and drying at a temperature of 80-90° C. to obtain alkali cellulose;

[0046]Step 4, mixing the alkali cellulose prepared in step 3 with the hydroxyl-containing phosphorus flame retardant, and then adding a crosslinking ag...

Embodiment 1

[0061] A method for preparing antibacterial and flame-retardant fibers, specifically implemented according to the following steps:

[0062] Step 1, collecting the pure white cotton waste textiles, and then washing and drying the collected white pure cotton waste textiles and crushing them;

[0063] Step 2, the pulverized material is subjected to oxygen bleaching with hydrogen peroxide, the mass fraction of hydrogen peroxide is 12%, the treatment temperature is controlled at 60° C., bleached for 80 minutes, and dried to obtain cellulose raw material;

[0064] Step 3, treating the cellulose raw material with 10% sodium hydroxide solution for 3 hours, drying at 80°C to obtain alkali cellulose;

[0065] Step 4, mixing alkali cellulose with a certain mass fraction of a hydroxyl-containing phosphorus-based flame retardant, using urea as a crosslinking agent, causing the flame retardant to undergo hydroxylamination crosslinking reaction with the alkali cellulose, and preparing flame-...

Embodiment 2

[0078] A method for preparing antibacterial and flame-retardant fibers, specifically implemented according to the following steps:

[0079] Step 1, collecting the pure white cotton waste textiles, and then washing and drying the collected white pure cotton waste textiles and crushing them;

[0080] Step 2, the pulverized material is subjected to oxygen bleaching with hydrogen peroxide, the mass fraction of hydrogen peroxide is 10%, the treatment temperature is controlled at 70° C., bleached for 60 minutes, and dried to obtain cellulose raw material;

[0081] Step 3, treating the bleached product in step 1 with 20% sodium hydroxide solution for 4 hours, drying at 85°C to obtain alkali cellulose;

[0082] Step 4, mixing the alkali cellulose with a certain mass fraction of a hydroxyl-containing phosphorus flame retardant, using urea as a crosslinking agent, causing the flame retardant to undergo a hydroxylaminated crosslinking reaction with the alkali cellulose to prepare the fla...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
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Abstract

The invention discloses a preparation method of antibacterial flame-retardant fibers. The preparation method specifically comprises the steps that a collected raw white pure cotton waste fabric is crushed after washed and dried, then oxygen bleaching is carried out by using oxygen peroxide, drying is carried out, and then a sodium hydroxide or sodium carbonate solution is used to carry out processing and drying to obtain alkali cellulose; and the alkali cellulose / a hydroxy-containing phosphorus flame retardant and a cross-linking agent are mixed to enable the obtained mixture to subjected toan oxyamination crosslinking reaction to prepare flame-retardant cellulose, the flame-retardant cellulose is mixed with a nano antibacterial sol to prepare a cellulose solution, then spinning is carried out to obtain primary fibers, and the primary fibers are processed to obtain the antibacterial flame-retardant fibers. The invention further discloses a method for preparing an antibacterial flame-retardant fabric. According to the preparation method of the antibacterial flame-retardant fibers, the waste raw white pure cotton fabric is used to prepare the antibacterial flame-retardant fibers, resources are fully used, environmental pollution is reduced, the antibacterial flame-retardant fabric prepared by using the fibers is long-lasting and stable in antibacterial and flame retardant properties and washable, and after 50 times of washing, the antibacterial flame-retardant performance still meets the standard requirements.

Description

technical field [0001] The invention belongs to the technical field of preparation methods of functional textiles, and relates to a preparation method of an antibacterial and flame-retardant fiber. The invention also discloses a method for preparing an antibacterial and flame-retardant fabric by using the self-made fiber. Background technique [0002] In recent years, with the development of society and economy, the country's emphasis on safety, the introduction of military-civilian integration development strategy, the rapid development of textile technology, and the continuous improvement of corporate safety awareness, especially due to the damage caused by textile ignition or combustion to personal property Incalculable losses, many foreign countries have passed strict laws and regulations, requiring special industries such as fire protection, electric power, petrochemical, and metallurgy to use flame-retardant fabrics. During the use of flame-retardant fabrics, as the hu...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): D01F2/24D01F1/07D01F1/10D02G3/04D02G3/44D03D15/00D03D15/12D03D15/225D03D15/283D03D15/50D03D15/513
CPCD01F2/24D01F1/103D01F1/07D02G3/045D02G3/449D02G3/443D10B2201/22D10B2331/04D10B2321/101D10B2331/021D10B2401/13D03D15/47D03D15/513
Inventor 侯琳樊争科赵雷徐炎炎孙凯飞
Owner SHAANXI YUANFENG TEXTILE TECH RES
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