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A kind of superhydrophilic anti-fog coating and its preparation method and application

An anti-fog coating, super-hydrophilic technology, applied in the coating, metal material coating process, liquid chemical plating, etc., can solve the problems of titanium dioxide coating application limitations, etc., achieve good application prospects, long anti-fog duration , highly controllable effect

Active Publication Date: 2022-03-22
NINGBO INST OF MATERIALS TECH & ENG CHINESE ACADEMY OF SCI
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

However, this super-hydrophilic anti-fog effect can only last for a few hours to a week or so. After losing the ultraviolet light, it returns to the hydrophobic state. Frequent use of ultraviolet light to maintain its hydrophilicity makes the application of titanium dioxide coatings restricted. Therefore, it is particularly important to develop an inorganic coating that can maintain a super-hydrophilic anti-fog effect under visible light.

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  • A kind of superhydrophilic anti-fog coating and its preparation method and application
  • A kind of superhydrophilic anti-fog coating and its preparation method and application
  • A kind of superhydrophilic anti-fog coating and its preparation method and application

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preparation example Construction

[0028] Another aspect of the embodiments of the present invention also provides a method for preparing a superhydrophilic anti-fog coating, which includes: at least using any one of the physical vapor deposition method, the sol-gel method, and the plasma-enhanced chemical vapor deposition method photocatalytically active TiO 2 Elemental doping is performed to deposit a super-hydrophilic anti-fog coating on the substrate.

[0029] Further, the doped elements include any one or a combination of metal elements and non-metal elements, and are not limited thereto.

[0030] Furthermore, the elements to be doped include any one or a combination of two or more of N, C, S, F, Fe, Cr, Ni, Cu, and are not limited thereto.

[0031] Further, the element doping includes single element doping or multi-element co-doping.

[0032] In some more specific embodiments, the method includes: placing the substrate in a vacuum chamber of a film coating equipment, and then sputtering a Ti target in a...

Embodiment 1

[0051] The N-doped TiO of this embodiment 2 A superhydrophilic anti-fog coating was prepared on a glass substrate by physical vapor deposition, and the N-doped TiO 2 The total thickness of the superhydrophilic anti-fog coating is about 100 nm.

[0052] The N-doped TiO 2 The superhydrophilic anti-fog coating can be prepared according to the following steps:

[0053] (1) Cleaning, degreasing, and surface activation treatment of the glass substrate: firstly, the glass substrate is cleaned and degreased with solvents such as ethanol and acetone, and then placed in the vacuum chamber of the reactive magnetron sputtering equipment, and the Vacuumize the vacuum chamber of the above-mentioned coating equipment, then raise the temperature in the vacuum chamber to 100°C, and pass in argon gas, turn on the ion beam, the ion beam voltage is 1300V, increase the gas ionization rate, and apply - 400V bias voltage to guide argon ions to bombard and activate the metal surface;

[0054] (2)...

Embodiment 2

[0057] The N-C co-doped TiO of the present embodiment 2 A superhydrophilic anti-fog coating was prepared on a glass substrate by physical vapor deposition, and the N-C co-doped TiO 2 The total thickness of the superhydrophilic anti-fog coating is about 150nm.

[0058] The N-C doped TiO 2 The superhydrophilic anti-fog coating can be prepared according to the following steps:

[0059] (1) Cleaning, degreasing, and surface activation treatment of the glass substrate: firstly, the glass substrate is cleaned and degreased with solvents such as ethanol and acetone, and then placed in the vacuum chamber of the reactive magnetron sputtering equipment, and the Vacuumize the vacuum chamber of the above-mentioned coating equipment, then raise the temperature in the vacuum chamber to 100°C, and pass in argon gas, turn on the ion beam, the ion beam voltage is 1300V, increase the gas ionization rate, and apply - 400V bias voltage to guide argon ions to bombard and activate the metal surf...

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Abstract

The invention discloses a super-hydrophilic anti-fog coating, a preparation method and application thereof. The coating is made of photocatalytically active TiO 2 and doping elements, wherein the doping elements include metal elements and / or non-metal elements. In the present invention, TiO with photocatalytic properties 2 Carrying out metal and / or metalloid doping reduces its forbidden band width so as to realize visible light-induced superhydrophilic anti-fog; element-doped TiO provided by the present invention 2 The super-hydrophilic anti-fog coating has the advantages of good binding force, high transparency, long-lasting anti-fog effect, and good anti-fog effect. The contact angle between the surface of the obtained coating and water is lower than 5°. The water property is still good, and the contact angle between the coating and the 10mm-diameter counter-grinding pin wrapped with a dust-free cloth is still less than 10° after 500 frictions under the friction conditions of a load of 1kg and a stroke of 5mm, and the light transmittance The content is 85-92%, and the preparation method is simple and easy, the controllability is high, the cost is low, and it can be produced in batches, and has a good application prospect in the field of anti-fog of transparent substrates.

Description

technical field [0001] The invention belongs to the field of surface anti-fog, and in particular relates to a super-hydrophilic anti-fog coating and a preparation method and application thereof. Background technique [0002] Transparent materials (such as glass, plastic) are widely used in industrial and agricultural production, daily life and military fields, such as goggles, laser protective glasses, telescopes and lenses of various camera equipment, observation windows of various machinery, sports Diving goggles, bathroom glass, chemical or biological protective masks, vehicle windshields and rearview mirrors, EOD treatment protective equipment, helmets, solar panels, observation windows for measuring instruments, glass covers, glass walls for greenhouses, etc. However, glasses will make us "see flowers in the fog" when we breathe out in winter; in cold winter, the fogging on the surface of the windshield will greatly affect our visibility and even cause accidents. The p...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C23C14/08C23C14/35C23C18/12C23C16/40C23C16/50
CPCC23C14/083C23C14/35C23C14/0036C23C14/352C23C18/1216C23C18/1254C23C16/405C23C16/50
Inventor 马付良曾志翔王刚汤磊
Owner NINGBO INST OF MATERIALS TECH & ENG CHINESE ACADEMY OF SCI