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High-strength and wear-proof PP plastic rope

A high-strength, plastic technology, applied in the field of plastics, can solve the problems of reducing the mechanical properties and flexibility of the plastic body, and achieve the effects of increasing stress, improving wear resistance, and improving mechanical strength.

Inactive Publication Date: 2020-08-07
界首市宏利塑料股份有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

In traditional wear-resistant plastics, relevant wear-resistant additives are added to the polypropylene matrix to improve the wear resistance of plastic filaments. However, a large amount of wear-resistant additives can achieve a good wear-resistant effect. However, this large amount of additives Addition will greatly reduce the mechanical properties and flexibility of the plastic body

Method used

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  • High-strength and wear-proof PP plastic rope
  • High-strength and wear-proof PP plastic rope
  • High-strength and wear-proof PP plastic rope

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0022] The preparation method of modified polypropylene is:

[0023] S1, preparation of modifier

[0024] Add 1mol 2-acetylene naphthalene, 1.15mol bistrimethylsiloxymethylsilane, 5mmol catalyst chloroplatinic acid and 1L solvent toluene into the reaction kettle, feed nitrogen for 15min, replace the air in the reaction kettle, and stir Heat up to 80°C, keep warm and stir for 11 hours. After the reaction, remove the solvent by rotary evaporation, wash with anhydrous ether, and dry to obtain the modifier shown in formula M; the yield is 83.6%; the reaction formula is as follows :

[0025]

[0026] S2, preparation of modified polypropylene

[0027] Add 1 kg of deionized water, 2 g of emulsifier polyoxypropylene ether, 1.5 g of initiator sodium persulfate, and 65 g of propylene monomer into the reactor, transfer the reactor to a water bath, and perform prepolymerization at a temperature of 60 ° C 30min, then the reactor was moved out of the water bath, cooled to room tempera...

Embodiment 2

[0029] A high-strength wear-resistant PP plastic rope, including the following raw materials in parts by weight: 110g modified polypropylene, 6g dimethyl phthalate, 6g trimethyloxalate acetate, 20g filler, 1g plasticizer , 1.6g paraffin oil, 0.5g lubricant.

[0030] Described filler is calcium carbonate;

[0031] Described plasticizer is epoxy fatty acid methyl ester;

[0032] Described lubricant is zinc stearate.

Embodiment 3

[0034] A high-strength and wear-resistant PP plastic rope, including the following raw materials in parts by weight: 140g modified polypropylene, 8g dimethyl phthalate, 8g trimethyloxalate acetate, 15g filler, 1.2g plasticizer Agent, 2g paraffin oil, 1g lubricant.

[0035] Described filler is montmorillonite;

[0036] Described plasticizer is diethyl terephthalate;

[0037] Described lubricant is zinc oxalate.

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Abstract

The invention discloses a high-strength and wear-proof PP plastic rope. The high-strength and wear-proof PP plastic rope is prepared from raw materials by weight: 110-140 parts of modified polypropylene, 5-8 parts of dimethyl phthalate, 6-8 parts of trimethyl ethyl acetate, 15-22 parts of filler, 0.5-1.2 parts of plasticizer, 1.5-3 parts of paroline and 0.5-1 part of lubricant. The polypropylene is modified, organosilicone and rigid functional group naphthalene rings are introduced in a bound manner, specifically, firstly, propylene monomers are pre-polymerized in an emulsion polymerization manner, then a modifier is added, double bonds on the modifier and the propylene are co-polymerized and then embedded into the polypropylene, the polypropylene with the organosilicone is obtained, due to introduction of the organosilicone, on one hand, the unit density of polypropylene chain segments is improved, the mechanical strength of the polypropylene is greatly improved, the bearing stress isenhanced, then the wear-proof performance of the PP rope is improved, and due to introduction of the rigid functional group naphthalene rings, the mechanical strength of the polypropylene is furtherimproved.

Description

technical field [0001] The invention belongs to the technical field of plastics, and in particular relates to a high-strength and wear-resistant PP plastic rope. Background technique [0002] Most of the plastic ropes on the market now use polypropylene (PP) as the raw material, which has been the fastest growing major thermoplastic, especially in fiber and filament, film extrusion, injection molding processing, etc. Polypropylene's excellent flow properties and wide range of flow rates, combined with other unique polymer properties, give it excellent processability. The lower flow rate can meet the processing requirements of extruded tape, tape filament and monofilament, etc., and can also make the finished product have tensile strength and low elongation, while maintaining sufficient transverse integrity, so that the winding machine guide device The splitting and dusting conditions are kept to a minimum. Main features: non-toxic, odorless, low density, strength, stiffnes...

Claims

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Application Information

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IPC IPC(8): D07B1/02C08F210/06C08F230/08
CPCC08F210/06D07B1/025D07B2205/201C08F230/085D07B2801/10
Inventor 刘立平李影
Owner 界首市宏利塑料股份有限公司
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