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Low-dielectric-constant hollow aluminum oxide/silicon dioxide nano composite material and application thereof

A technology of nano-composite materials and low dielectric constant, applied in the field of material chemistry, can solve the problems of differences in dielectric properties and wide application of unfavorable materials, and achieve the effects of high stability, high hardness and low dielectric constant

Active Publication Date: 2020-08-18
SHANDONG SINOCERA FUNCTIONAL MATERIAL CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, in the prior art for porous SiO 2 The research on materials mainly focuses on how to reduce the dielectric constant of silicon oxide films, but there are relatively few studies on how to effectively reduce the dielectric constant of silicon dioxide materials themselves. Moreover, porous SiO 2 The dielectric properties of materials are also greatly affected by the preparation process, which is not conducive to the wide application of materials.

Method used

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  • Low-dielectric-constant hollow aluminum oxide/silicon dioxide nano composite material and application thereof
  • Low-dielectric-constant hollow aluminum oxide/silicon dioxide nano composite material and application thereof
  • Low-dielectric-constant hollow aluminum oxide/silicon dioxide nano composite material and application thereof

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Embodiment 1

[0060] The preparation method of the low dielectric constant hollow alumina / silicon dioxide nanocomposite described in this embodiment comprises the following steps:

[0061] (1) Take calcium chloride and surfactant (hexadecyltrimethylammonium bromide) according to the mass ratio of 8:1, add water to prepare the solution as a template solution, and add 1% mass fraction of EDTA as a structure-directing agent , the calcium chloride mass concentration is controlled to be 0.9g / ml, and the template solution is added to 800r / min high-speed magnetic stirring by an ultrasonic nebulizer (the diameter of the ultrasonic atomizing sheet is 18mm, and the vibration frequency is 1.7MHz), and The ammonia solution with a mass fraction of 16% adjusts the pH of the system to 10; then continuously feeds small bubbles with a content of 40% CO 2 Gas to form nano-calcium carbonate template, and the atomized droplets can form nano-calcium carbonate template particles with a size of 5-500nm in the alk...

Embodiment 2

[0069] The preparation method of the low dielectric constant hollow alumina / silicon dioxide nanocomposite described in this embodiment comprises the following steps:

[0070] (1) Take calcium chloride and surfactant (sodium lauryl sulfate) according to the mass ratio of 5:1, add water preparation solution as template solution, and add 1% mass fraction EDTA as structure directing agent, control calcium chloride The mass concentration is 0.05g / ml, and the template solution is added to 800r / min high-speed magnetic stirring through an ultrasonic nebulizer (the diameter of the ultrasonic atomizing sheet is 18mm, and the vibration frequency is 1.7MHz), and a mass fraction of 16% is added. Ammonia solution adjusts the pH of the system to 8; then continuously feeds CO 2 Gas to form nano-calcium carbonate template, and the atomized droplets can form nano-calcium carbonate template particles with a size of 5-500nm in the alkaline reaction system;

[0071] (2) After the template particl...

Embodiment 3

[0078] The preparation method of the low dielectric constant hollow alumina / silicon dioxide nanocomposite described in this embodiment comprises the following steps:

[0079] (1) Get calcium chloride and surfactant (hexadecyltrimethylammonium chloride) according to the mass ratio of 40:1, add water preparation solution as template solution, control calcium chloride mass concentration to be 5g / ml, pass Ultrasonic atomizer (ultrasonic atomization plate diameter is 18mm, vibration frequency is 1.7MHz) to add the template solution to 800r / min high-speed magnetic stirring, and add ammonia solution with a mass fraction of 16% to adjust the pH of the system to 12; then Continuously inject small bubbles with 40% CO content 2 Gas to form nano-calcium carbonate template, and the atomized droplets can form nano-calcium carbonate template particles with a size of 5-500nm in the alkaline reaction system;

[0080] (2) After the template particles formed in step (1) are separated by high-sp...

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Abstract

The invention belongs to the technical field of material chemistry and relates to a low-dielectric-constant hollow aluminum oxide / silicon dioxide nano composite material, and further discloses a preparation method and application thereof. The low-dielectric-constant hollow aluminum oxide / silicon dioxide nano composite material is of a laminated shell structure with a closed cavity structure; aluminum oxide is directionally deposited on the outer surface of a hollow silicon dioxide shell layer; an inner shell is a silicon dioxide layer; an aluminum oxide shell body is deposited and grown on thesurface of the silicon dioxide layer; since the advantages of the aluminum oxide and silicon dioxide are effectively combined, and the advantages of low dielectric constant, low refractive index andhigh-frequency dielectric stability of the hollow silicon dioxide can be exerted at the same time; and the advantages of high strength, chemical erosion resistance, low thermal conductivity, low thermal expansion coefficient and the like of the aluminum oxide material are utilized, so that the material can meet the performance requirements in the antireflection field and the 5G millimeter wave frequency band field.

Description

technical field [0001] The invention belongs to the technical field of material chemistry, specifically relates to a low dielectric constant hollow alumina / silicon dioxide nanocomposite material, and further discloses its preparation method and application. Background technique [0002] With the vigorous and rapid development of science and technology, we have entered the IT era of rapid development. In the rapidly developing field of information technology, various electronic products, systems and equipment are constantly emerging. From the automatic control system of industrial production to various electrical equipment in home life, it contains a large number of electronic circuits. With the rapid growth of the electronic industry in the 21st century, the impact on our life and work is gradually deepening. The emergence of various sensors and electronic components plays an irreplaceable role in various fields of national defense and national economy, and has also been w...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C01B33/18C01B33/12C01F7/14C01F7/34
CPCC01B33/18C01B33/12C01F7/142C01F7/34C01P2004/04
Inventor 宋锡滨马雁冰李心勇潘光军
Owner SHANDONG SINOCERA FUNCTIONAL MATERIAL CO LTD
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