Heat-shrinkable polyester-based film roll

A film roll, heat shrinking technology, applied in thin material processing, winding strip, application, etc., can solve the problems of low heat resistance, bad conditions, hydrogen chloride gas generation, etc., and achieve less core wrinkles and less trouble. Effect

Pending Publication Date: 2020-09-11
TOYOBO CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Among such heat-shrinkable films, polyvinyl chloride-based films have problems such as low heat resistance, hydrogen chloride gas generation during incineration, and dioxins.
In addition, the problem of polystyrene-based film is that it has poor solvent resistance, needs to use special composition ink during printing, and must be incinerated at high temperature, which will be accompanied by foul smell and a large amount of black smoke when incinerated.
[0003] However, heat-shrinkable labels are mostly discarded as garbage in the end, and thinner walls are required from the viewpoint of environmental protection.
As the thickness becomes thinner, the stiffness decreases, and the handling becomes more difficult, so there is a problem in the film roll after slitting the film
Heat-shrinkable films are difficult to handle compared to other general-purpose films, but according to research by the present inventors, defects are particularly likely to occur in heat-shrinkable polyester films with a film thickness of 30 μm or less
Trouble in printing and processing film rolls due to defects
In particular, if wrinkles are generated in the core portion of the film roll, it will cause trouble at this position during printing and processing, and there is a problem of loss.

Method used

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  • Heat-shrinkable polyester-based film roll
  • Heat-shrinkable polyester-based film roll
  • Heat-shrinkable polyester-based film roll

Examples

Experimental program
Comparison scheme
Effect test

Embodiment

[0082] Next, the present invention will be specifically described using examples and comparative examples, but the present invention is not limited to the forms of the examples, and can be appropriately changed within a range not departing from the gist of the present invention.

[0083] The evaluation methods used in the present invention are as follows. In addition, unless otherwise stated, 1 m of film was removed from the surface layer of a film roll, and the film or film roll of the surface layer part after this removal was evaluated.

[0084] [Thermal shrinkage rate in the main shrinkage direction]

[0085] Cut the film into a square of 10cm×10cm, in hot water at a temperature of 90°C±0.5°C, treat it for 10 seconds under no load to shrink it, then measure the transverse direction (main shrinkage direction) of the film. For the size, the heat shrinkage rate was obtained from the following formula (1).

[0086] Thermal shrinkage rate = ((length before shrinkage - length a...

Synthetic example 1

[0109] Synthesis example 1 (synthesis of polyester)

[0110] In the esterification reactor, 57036 parts by mass of terephthalic acid (TPA), ethylene glycol (EG) of 33244 parts by mass, neopentyl glycol (NPG) of 15733 parts by mass, 23.2 parts by mass of polycondensation catalyst Antimony trioxide, 5.0 parts by mass of sodium acetate (alkali metal compound) and 46.1 parts by mass of trimethyl phosphate (phosphorus compound), adjust the pressure to 0.25MPa, and stir at 220-240°C for 120 minutes to perform esterification reaction. Return the pressure of the reactor to normal pressure, add 3.0 parts by mass of cobalt acetate tetrahydrate and 124.1 parts by mass of magnesium acetate tetrahydrate, stir at 240°C for 10 minutes, depressurize to 1.33hPa in 75 minutes, and raise the temperature to 280°C. Stirring was continued at 280° C. (about 70 minutes) until the melt viscosity became 4500 Poise, and then discharged into water in a strand form. The discharge was cut with a wire cu...

Synthetic example 2

[0112] Small pieces A and C having the compositions shown in Table 1 were obtained by the same method as in Synthesis Example 1. In the table, NPG is an abbreviation of neopentyl glycol, BD is an abbreviation of butanediol, and CHDM is an abbreviation of cyclohexanedimethanol. It should be noted that, in the small piece A, SiO was added as a lubricant at a ratio of 4500 ppm relative to the polyester. 2 (Fuji Silysia Ltd., Sylysia 266). The intrinsic viscosity is as follows: small pieces A, C, E are 0.73dl / g, small piece D is 0.92dl / g.

[0113] [Table 1]

[0114]

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Abstract

The issue is to provide a heat-shrinkable polyester-based film roll that exhibits good winding properties, and in particular, good resistance to winding core wrinkling and end face displacement. The heat-shrinkable polyester-based film roll is characterized by being prepared by winding a heat-shrinkable polyester-based film on a paper tube, the film having a shrinkage rate in a primary film shrinkage direction of 40% or more following treatment in hot water at 90 DEG C for 10 seconds. The heat-shrinkable polyester-based film roll satisfies requirements (1) to (6): (1) the film winding length is 2000-20,000 m; (2) the film width is 400-2500 mm; (3) the film thickness is 5-30 [mu]m; (4) the thickness irregularity at a surface layer part of the film roll in the film width direction is 12% orless; (5) the paper tube has an internal diameter of 3 inches, the difference in clearance of the paper tube in the width direction is 0.5 mm or less after the film is removed from the film roll, andthe flat pressure resistance of the paper tube is 1700 N / 100 mm or more after the film is removed; (6) the average winding hardness of a surface layer part of the film roll in the width direction is 500-850.

Description

technical field [0001] The present invention relates to a film roll obtained by winding a heat-shrinkable polyester film. In more detail, it is related with the heat-shrinkable polyester film roll which improves the wrinkle of the winding core part of a film roll, and has little loss at the time of printing and processing. Background technique [0002] In recent years, stretched films (so-called heat-shrinkable films) made of polyvinyl chloride-based resins, polystyrene-based resins, polyester-based resins, etc. Indicated label packaging, bottle cap sealing, integrated packaging, etc. Among such heat-shrinkable films, the polyvinyl chloride-based film has problems such as low heat resistance, generation of hydrogen chloride gas during incineration, and a cause of dioxin. In addition, polystyrene-based films have problems in that they have poor solvent resistance, require the use of inks with a special composition during printing, and must be incinerated at high temperature...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B29C55/08B29C61/06B65H18/28B65H75/00
CPCB29C55/08B29C61/06B29C48/0018B29C48/08B29C61/02B29C61/065B29K2067/00B29L2007/008B29C2948/92704B29C48/914B29C48/305B29C55/04B65H18/28B65H75/00B65H2701/1842
Inventor 春田雅幸多保田规
Owner TOYOBO CO LTD
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