Antirust master batch and preparation process thereof
A preparation process and masterbatch technology, which is applied in the field of antirust masterbatch and its preparation technology, can solve the problems of opacity, lack of other properties, and complicated manufacturing methods of vapor phase antirust paper, achieve good shape recovery ability, and ensure system strength and mechanical properties, the effect of promoting release
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Embodiment 1
[0035] Dissolve sodium bicarbonate in pure water, add sodium dodecylbenzenesulfonate and mix evenly to obtain solution A; take 1.10 parts of acrylic acid and add sodium hydroxide aqueous solution, add 0.55 parts of acrylamide and mix to prepare mixture B; take 1.3 1 part of polycaprolactone diol, 1.2 parts of dimethylformamide, 0.1 part of n-hexadecane were mixed and stirred for 20 minutes, and 0.4 part of diphenylmethane diisocyanate, 0.05 part of isophorone diisocyanate, 0.3 part of isooctyl acrylate were added , 0.1 part of 2-aminoethanol and continue to stir for 300 minutes to prepare mixture C; slowly add mixture C to solution A, and stir at a stirring rate of 600 rpm for 2 minutes, place it at 0°C, and sonicate for 5 minutes. In a nitrogen atmosphere, sequentially add N,N'-methylenebisacrylamide, potassium persulfate, and sorbitan oleate, mix well, and raise the temperature to 60°C, keep warm for 7h, add mixture B, and keep warm for 1h, Prepare modified polyurethane;
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Embodiment 2
[0039]Dissolve sodium bicarbonate in pure water, add sodium dodecylbenzenesulfonate and mix evenly to obtain solution A; take 1.87 parts of acrylic acid and add sodium hydroxide aqueous solution, add 0.6 parts of acrylamide and mix to prepare mixture B; take 2 1 part of polycaprolactone diol, 1.8 parts of dimethylformamide, and 0.15 parts of n-hexadecane were mixed and stirred for 30 minutes, and 0.6 parts of diphenylmethane diisocyanate, 0.07 parts of isophorone diisocyanate, and 0.4 parts of isooctyl acrylate were added , 0.15 parts of 2-aminoethanol continued to stir for 45 minutes to prepare mixture C; slowly added mixture C to solution A, and stirred at a stirring rate of 700 rpm for 3 minutes, placed at a temperature of 5°C, and ultrasonically treated for 6 minutes. In a nitrogen atmosphere, sequentially add N,N'-methylenebisacrylamide, potassium persulfate, and sorbitan oleate, mix well, and raise the temperature to 70°C, keep warm for 8h, add mixture B, and keep warm fo...
Embodiment 3
[0043] Dissolve sodium bicarbonate in pure water, add sodium dodecylbenzenesulfonate and mix evenly to obtain solution A; take 2.64 parts of acrylic acid and add sodium hydroxide aqueous solution, add 0.66 parts of acrylamide and mix to prepare mixture B; take 2.6 1 part of polycaprolactone diol, 2.4 parts of dimethylformamide, and 0.2 part of n-hexadecane were mixed and stirred for 40 minutes, and 0.8 part of diphenylmethane diisocyanate, 0.1 part of isophorone diisocyanate, and 0.6 part of isooctyl acrylate were added , 0.2 parts of 2-aminoethanol continued to stir for 60 minutes to prepare mixture C; slowly added mixture C to solution A, and stirred at a stirring rate of 800 rpm for 5 minutes, placed at a temperature of 10°C, and ultrasonically treated for 8 minutes. In a nitrogen atmosphere, sequentially add N,N'-methylenebisacrylamide, potassium persulfate, and sorbitan oleate, mix well, and raise the temperature to 80°C, keep warm for 9h, add mixture B, and keep warm for ...
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