Antirust master batch and preparation process thereof

A preparation process and masterbatch technology, which is applied in the field of antirust masterbatch and its preparation technology, can solve the problems of opacity, lack of other properties, and complicated manufacturing methods of vapor phase antirust paper, achieve good shape recovery ability, and ensure system strength and mechanical properties, the effect of promoting release

Pending Publication Date: 2020-10-27
CHANGZHOU TIANWANG PLASTIC IND CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] During transportation and storage, metal and metal products are often susceptible to corrosion from the atmosphere and other environments, causing surface corrosion, affecting the performance and appearance of metal and metal products, and even causing failure and scrapping of metal and metal products. and the damage of metal products, we use anti-rust packaging to protect metal and metal products, including gas-phase anti-rust packaging, which uses gas-phase corrosion inhibitors to continuously and slowly gasify at room temperature and volatilize corrosion-inhibiting gas to absorb On the bare metal surface, a stable protective film with a thickness of one to two molecules is formed, which can effectively prevent the corrosion of metal by ambient atmospheres such as oxygen and moisture. Due to the continuous volatilization of the gas phase corrosion inhibitor, it can achieve long-term, stable and excellent corrosion resistance. Anti-rust effect, the traditional anti-rust packaging materials are gas phase anti-rust paper and gas phase anti-rust film. The combination of polymer materials and vapor phase antirust masterbatch, including vapor phase antirust bag and vapor phase antirust stretch film, etc. Antirust masterbatch is the basic functional masterbatch for manufacturing vapor phase antirust film, and its main component is vapor phase corrosion inhibition agent and resin, but the existing anti-rust masterbatches generally do not have other properties except the gas phase anti-rust function. Basic Functional Raw Materials

Method used

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  • Antirust master batch and preparation process thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0035] Dissolve sodium bicarbonate in pure water, add sodium dodecylbenzenesulfonate and mix evenly to obtain solution A; take 1.10 parts of acrylic acid and add sodium hydroxide aqueous solution, add 0.55 parts of acrylamide and mix to prepare mixture B; take 1.3 1 part of polycaprolactone diol, 1.2 parts of dimethylformamide, 0.1 part of n-hexadecane were mixed and stirred for 20 minutes, and 0.4 part of diphenylmethane diisocyanate, 0.05 part of isophorone diisocyanate, 0.3 part of isooctyl acrylate were added , 0.1 part of 2-aminoethanol and continue to stir for 300 minutes to prepare mixture C; slowly add mixture C to solution A, and stir at a stirring rate of 600 rpm for 2 minutes, place it at 0°C, and sonicate for 5 minutes. In a nitrogen atmosphere, sequentially add N,N'-methylenebisacrylamide, potassium persulfate, and sorbitan oleate, mix well, and raise the temperature to 60°C, keep warm for 7h, add mixture B, and keep warm for 1h, Prepare modified polyurethane;

...

Embodiment 2

[0039]Dissolve sodium bicarbonate in pure water, add sodium dodecylbenzenesulfonate and mix evenly to obtain solution A; take 1.87 parts of acrylic acid and add sodium hydroxide aqueous solution, add 0.6 parts of acrylamide and mix to prepare mixture B; take 2 1 part of polycaprolactone diol, 1.8 parts of dimethylformamide, and 0.15 parts of n-hexadecane were mixed and stirred for 30 minutes, and 0.6 parts of diphenylmethane diisocyanate, 0.07 parts of isophorone diisocyanate, and 0.4 parts of isooctyl acrylate were added , 0.15 parts of 2-aminoethanol continued to stir for 45 minutes to prepare mixture C; slowly added mixture C to solution A, and stirred at a stirring rate of 700 rpm for 3 minutes, placed at a temperature of 5°C, and ultrasonically treated for 6 minutes. In a nitrogen atmosphere, sequentially add N,N'-methylenebisacrylamide, potassium persulfate, and sorbitan oleate, mix well, and raise the temperature to 70°C, keep warm for 8h, add mixture B, and keep warm fo...

Embodiment 3

[0043] Dissolve sodium bicarbonate in pure water, add sodium dodecylbenzenesulfonate and mix evenly to obtain solution A; take 2.64 parts of acrylic acid and add sodium hydroxide aqueous solution, add 0.66 parts of acrylamide and mix to prepare mixture B; take 2.6 1 part of polycaprolactone diol, 2.4 parts of dimethylformamide, and 0.2 part of n-hexadecane were mixed and stirred for 40 minutes, and 0.8 part of diphenylmethane diisocyanate, 0.1 part of isophorone diisocyanate, and 0.6 part of isooctyl acrylate were added , 0.2 parts of 2-aminoethanol continued to stir for 60 minutes to prepare mixture C; slowly added mixture C to solution A, and stirred at a stirring rate of 800 rpm for 5 minutes, placed at a temperature of 10°C, and ultrasonically treated for 8 minutes. In a nitrogen atmosphere, sequentially add N,N'-methylenebisacrylamide, potassium persulfate, and sorbitan oleate, mix well, and raise the temperature to 80°C, keep warm for 9h, add mixture B, and keep warm for ...

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Abstract

The invention discloses an antirust master batch and a preparation process thereof. The antirust master batch is prepared from, by weight, 43-57 parts of carrier resin, 31-39 parts of an antirust agent and 12-18 parts of an assistant, wherein the carrier resin is prepared from, by weight, 100 parts of polypropylene, 7-20 parts of polyethylene, 2-15 parts of coumarone resin and 5-10 parts of modified polyurethane. According to the invention, through setting of the components and the proportions, processes and parameters of the components, the prepared antirust master batch has relatively high antirust performance, mechanical strength and mechanical property; the basic performance is provided for the prepared gas-phase antirust film; the tearing damage of the prepared gas-phase antirust filmis avoided; meanwhile, some raw materials do not need to be added for functional compensation, and the prepared antirust master batch further has certain viscosity and sealing performance, so that the prepared gas-phase antirust film can adsorb and get close to metal and metal products, the gaps between the gas-phase antirust film and the metal and metal products are reduced and dried, the effects of isolating air and preventing corrosion are achieved, and the gas-phase antirust master batch is suitable for wide application and popularization.

Description

technical field [0001] The invention relates to the field of metal antirust, in particular to an antirust masterbatch and a preparation process thereof. Background technique [0002] During transportation and storage, metal and metal products are often susceptible to corrosion from the atmosphere and other environments, causing surface corrosion, affecting the performance and appearance of metal and metal products, and even causing failure and scrapping of metal and metal products. and the damage of metal products, we use anti-rust packaging to protect metal and metal products, including gas-phase anti-rust packaging, which uses gas-phase corrosion inhibitors to continuously and slowly gasify at room temperature and volatilize corrosion-inhibiting gas to absorb On the bare metal surface, a stable protective film with a thickness of one to two molecules is formed, which can effectively prevent the corrosion of metal by ambient atmospheres such as oxygen and moisture. Due to t...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L23/12C08L23/06C08L45/02C08L51/08C08L23/20C08K13/02C08K5/3475C08K5/17C08K5/18C08K3/22C08K5/098C08K5/32C08K5/09C08K5/1545C08J3/22
CPCC08J3/226C08J2423/12C08J2423/06C08J2445/02C08J2451/08C08J2423/20C08K13/02C08K5/3475C08K5/17C08K5/18C08K2003/2227C08K5/098C08K5/32C08K5/09C08K5/1545
Inventor 吴建国史良吴建锋
Owner CHANGZHOU TIANWANG PLASTIC IND CO LTD
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