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An easy-adhesive nylon film and its preparation method, a nylon-based composite film and its preparation method

A nylon film and bonding technology, applied in the field of packaging materials, can solve problems such as insufficient bonding and achieve good bonding strength

Active Publication Date: 2022-06-21
HUNAN UNIV OF TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] However, the above physical and chemical treatments have technical defects of insufficient bonding.

Method used

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  • An easy-adhesive nylon film and its preparation method, a nylon-based composite film and its preparation method

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preparation example Construction

[0053] The present invention also provides the preparation method of the easy-adhesive nylon film described in the above technical solution, comprising the following steps:

[0054] Mix nylon resin, slip agent, opening agent, easy-bonding functional material and antistatic agent, melt and extrude through an extruder to obtain the melt raw materials of the first surface layer and the second surface layer;

[0055] Melting and extruding the nylon resin through an extruder to obtain the melt raw material of the core layer;

[0056] Co-extruding the melt raw material of the first skin layer and the second skin layer and the melt raw material of the core layer and casting to the surface of the chill roll, and after plasma treatment, a nylon base material layer is obtained;

[0057] Mixing the modified water-based hydroxy acrylic resin, nano-silica grafted hyperbranched polymer, ethylene maleic anhydride copolymer, solvent, cross-linking agent and slip agent to carry out cross-linki...

Embodiment 1

[0081] The mass percentages are: 94.2% nylon 6 resin, 0.2% oleic acid amide, 0.5% magnesium carbonate (particle size is 0.005-1.2 μm), 5% ethylene acrylic acid copolymer and 0.1% trihydroxyethyl methyl quaternary ammonium The methyl sulfate is mixed, melted and extruded by an extruder, and the melt raw material of the first surface layer is obtained;

[0082] The mass percentages are: 88.2% nylon 11 resin, 0.5% erucamide, 0.8% sodium silicate (particle size is 0.008-1.3 μm), 10% ionized ethylene methacrylic acid copolymer and 0.5% graphene are mixed , melted and extruded by an extruder to obtain the melt raw material of the second surface layer;

[0083] Melting and extruding the nylon 6 resin through an extruder to obtain the melt raw material of the core layer;

[0084] After the melt raw materials of the first surface layer and the second surface layer and the melt raw material of the core layer are casted to the surface of a chill roll with a temperature of 30° C. through...

Embodiment 2

[0090] The difference between this embodiment and Embodiment 1 is:

[0091] The mass percentages are: 87.5% nylon 6 / 12 resin, 1% ethylene bis-stearic acid amide, 0.5% talc (particle size is 0.01-1.5 μm), 10% ionized ethylene methacrylic acid copolymer Mixed with 1% stearamidopropyl dimethyl-β-hydroxyethylammonium dihydrogen phosphate, melted and extruded by an extruder to obtain the melt raw material of the first surface layer;

[0092] The mass percentages are: 87.5% nylon 610 resin, 1% silicone oil, 0.5% diatomaceous earth (particle size is 0.005-1.8 μm), 10% ethylene-methyl acrylate copolymer and 1% polyol fatty acid ester Mixing, melting and extruding through an extruder to obtain the melt raw material of the second surface layer;

[0093] Melting and extruding nylon 6 / 66 resin through an extruder to obtain the melt raw material of the core layer;

[0094] The mass parts are 50 parts of organosiloxane modified hydroxy acrylic resin, 20 parts of nano-silica grafted hyperb...

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Abstract

The invention provides an easy-adhesive nylon film and a preparation method thereof, a nylon-based composite film and a preparation method thereof, and belongs to the technical field of packaging materials. The easy-adhesive nylon film provided by the invention includes a nylon base material layer and an easy-adhesion layer provided on at least one side of the nylon base material layer; the nylon base material layer is composed of three layers of co-extruded biaxially stretched nylon film , from top to bottom are the first surface layer, the core layer and the second surface layer; the first surface layer and the second surface layer independently include nylon resin, slip agent, opening agent, easy-bonding functional material and antistatic agent; The core layer includes nylon resin; the easy-adhesive layer is prepared by cross-linking reaction of raw materials including the following components: modified water-based hydroxyl acrylic resin, nano-silica grafted hyperbranched polymer, ethylene maleic anhydride Copolymers, solvents, cross-linkers and slip agents. The easy-adhesive nylon film provided by the invention has excellent adhesiveness and is not prone to adhesion.

Description

Technical field [0001] The invention belongs to the technical field of packaging materials, and in particular relates to an easy-adhesive nylon film and a preparation method thereof, and a nylon-based composite film and a preparation method thereof. Background technique [0002] Biaxially oriented nylon (BOPA) film has the advantages of high strength, good toughness, good transparency, wide operating temperature range, excellent barrier properties, and good puncture resistance, and is widely used in food packaging, daily chemical packaging, and pharmaceutical blister packaging. , electronic product packaging and other technical fields. However, in practical applications, BOPA films need to be combined with other film materials. Therefore, it is usually necessary to perform secondary processing on the surface of the BOPA film, such as physical treatment such as dot halo treatment, plasma treatment, or chemical treatment using chemical reagents such as acids and alkalis to im...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B32B27/06B32B27/34B32B37/15B32B38/16B32B37/12B32B27/32C08L33/00C08L67/00C08L23/08C08L83/04C08L77/02C08L77/06C08L71/00C08L51/00C08L53/00C08K13/02C08K5/20C08K3/26C08K3/34C08K3/04C08K3/36C08K7/26C08J5/18B29C48/08B29C55/12B29L7/00
CPCB32B27/08B32B27/34B32B37/15B32B38/164B32B37/12B32B27/32C08J5/18B29C48/08B29C55/12C08J2333/00C08J2467/00C08J2423/08C08J2483/04C08J2471/00C08J2451/00C08J2453/00C08K2201/011C08K3/36C08K13/02C08K5/20C08K2003/267C08K3/34C08K3/042C08J2377/02C08J2377/06C08K7/26
Inventor 刘跃军林新土范淑红石璞崔玲娜刘小超
Owner HUNAN UNIV OF TECH