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Silicon oxide coated nano zero-valent iron particles and preparation method and application thereof

A nano-zero-valent iron, silicon oxide technology, applied in chemical instruments and methods, catalyst activation/preparation, metal/metal oxide/metal hydroxide catalysts, etc. The problem of uneven particle distribution, etc., to achieve the effects of excellent physical and chemical properties, excellent anti-oxidation performance, and excellent dispersibility

Active Publication Date: 2020-12-08
CHINA CONSTR THIRD BUREAU GREEN IND INVESTMENT CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

After nZVI reacts with pollutants, it will generate many iron oxide precipitates and adhere to the surface, and the continuous reduction activity is difficult to guarantee.
(4) Low recycling efficiency
However, there are still problems such as uneven particle distribution, easy agglomeration, poor dispersion, and low reactivity in the liquid phase preparation of nZVI. Therefore, many improved liquid phase reduction methods have emerged, mainly by adding dispersants and carriers to avoid the above defects.
Among them, Ross used sodium alginate microcapsules for loading in "A Preparation Method for Nano-iron Particles Loaded by Sodium Alginate Microcapsules" (patent application number: 201310104440.7). Although this improved technology improves the oxidation resistance of nano-iron and stability, but its preparation process is cumbersome and time-consuming, and at the same time, the participation of macromolecular organic substances in the separation and purification process leads to certain environmental pollution problems; "(patent application number: 200910069677.X), the use of silicon micropowder loading improves the anti-agglomeration of nano-zero-valent iron particles, but in the preparation process, it is necessary to add strong hydrochloric acid to the system to pre-modify the base silicon micropowder Re-separation, the process requires both batch and multiple complex operations and the participation of strong acid to obtain the loaded nZVI, which greatly increases the preparation cost

Method used

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  • Silicon oxide coated nano zero-valent iron particles and preparation method and application thereof
  • Silicon oxide coated nano zero-valent iron particles and preparation method and application thereof
  • Silicon oxide coated nano zero-valent iron particles and preparation method and application thereof

Examples

Experimental program
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Effect test

Embodiment 1

[0032] A method for preparing silicon oxide-coated nanometer zero-valent iron particles (Si-nZVI) is provided, which specifically includes the following steps:

[0033] 1) Add 200 mL of Na with a concentration of 5 mmol / L in a 500 mL four-neck flask 2 Si 2 o 5 Solution, weigh 1.42gFeCl 3 ·6H 2 O powder was added to the above solution to dissolve, and the reaction solution was mechanically stirred for 1 h under the protection of nitrogen, and the stirring speed was controlled at 50 rpm.

[0034] 2) Weigh 0.5g NaBH 4 Dissolve in 50mL deoxygenation and deionization to get NaBH 4 solution, and NaBH under the action of a peristaltic pump 4 The solution was added dropwise into the four-necked flask at a flow rate of 5mL / min. The entire dropping process was required to be slow, and the control time was 10min. The nitrogen protection was continued, and stirring was continued at a stirring speed of 50rpm for 2h.

[0035] 3) After the reaction, through magnetic separation and sorti...

Embodiment 2

[0039] Provided is a method for preparing silicon oxide-coated nanometer zero-valent iron particles, which specifically includes the following steps:

[0040] 1) At room temperature, add 200mL of Na with a concentration of 10mmol / L to a 500mL four-neck flask 2 Si 2 o 5 solution, weigh 2.5g Fe(NO 3 ) 3 9H 2 The O powder was added into the solution for dissolution, and the reaction solution was mechanically stirred for 2 hours under the protection of nitrogen, and the stirring speed was controlled at 80 rpm.

[0041] 2) Weigh 1.0g NaBH 4 Dissolve in 50mL anaerobic water to get NaBH 4 solution, and NaBH under the action of a peristaltic pump 4 The solution was added dropwise into the four-necked flask at a flow rate of 10mL / min. The entire dropping process was required to be slow, and the control time was 5 minutes. The nitrogen protection was continued, and the stirring speed was continued at 80rpm for 2h.

[0042] 3) After the reaction, through magnetic separation and s...

Embodiment 3

[0044] Provided is a method for preparing silicon oxide-coated nanometer zero-valent iron particles, which specifically includes the following steps:

[0045] 1) At room temperature, add 200 mL of Na with a concentration of 15 mmol / L into a 500 mL four-neck flask 2 SiO 3 solution, weigh 2g FeSO 4 ·7H 2 The O powder was added into the solution for dissolution, and the reaction solution was mechanically stirred for 2 hours under the protection of nitrogen, and the stirring speed was controlled at 80 rpm.

[0046] 2) Weigh 1.0g KBH 4 Dissolved in 50mL anaerobic water to obtain KBH 4 solution, and KBH under the action of a peristaltic pump 4 The solution was added dropwise into the four-necked flask at a flow rate of 15mL / min. The whole dropping process was required to be slow, nitrogen protection continued, and stirring continued at a stirring speed of 80rpm for 2h.

[0047] 3) After the reaction, the precipitate was washed with deoxygenated deionized water and absolute eth...

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Abstract

The invention discloses silicon oxide coated nano zero-valent iron particles and a preparation method and application thereof. According to the particles, nano zero-valent iron is taken as a core, silicon oxide is taken as a coating layer, and a NaBH4 or KBH4 reducing agent is added into a mixed solution of ferric salt and inorganic silicate in an inert gas atmosphere for one-step reaction, so that the particles are prepared. The preparation method thereof comprises the following steps: adding ferric salt into an inorganic silicate solution, and stirring in an inert gas atmosphere to obtain amixed solution; dropwise adding a reducing agent NaBH4 or KBH4 solution, stirring for reaction in an inert gas atmosphere to obtain a precipitate, separating, cleaning, and drying in vacuum to obtaina product. The silicon oxide coated nano zero-valent iron is prepared through a one-step simple liquid phase reduction method, the process is simple, the raw materials are cheap, easy to obtain, non-toxic and harmless, and the obtained novel nano zero-valent iron particles are good in dispersity, small and uniform in average particle size, high in oxidation resistance and suitable for treating organic wastewater.

Description

technical field [0001] The invention belongs to the technical field of nanomaterial preparation, and in particular relates to a silicon oxide-coated nanometer zero-valent iron particle and a preparation method and application thereof. Background technique [0002] The reduction and removal of harmful pollutants in the environment by using nanometer zero-valent iron (nZVI) is a widely researched technology at home and abroad in recent years. Compared with ordinary zero-valent iron powder, nZVI, as an excellent electron donor, not only has a smaller particle diameter and a larger specific surface area, but also has the advantage of nanometer size to provide abundant reactive sites and accelerate the efficiency of pollutant treatment. At present, this technology has been applied in the removal process of nitrate nitrogen, high-priced heavy metal ions, organic halides, nitro compounds and other harmful substances in water bodies. However, in the actual process implementation pr...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01J23/745B01J37/16B82Y30/00B82Y40/00C02F1/78C02F101/30
CPCB01J23/745B01J37/16C02F1/78C02F1/725B82Y30/00B82Y40/00C02F2101/30
Inventor 毛旭辉王智成崔佳鑫虞敏达张家兴周洁颖李盈皞
Owner CHINA CONSTR THIRD BUREAU GREEN IND INVESTMENT CO LTD
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