Additive of Co-Ni alloy electroplating solution for electroplating

An alloy electroplating solution and additive technology, applied in the field of electroplating process, can solve the problems of complex electroplating process, prone to cracks, potential corrosion, etc., and achieve the effects of inhibiting abnormal deposition, improving bonding force, and strong deep plating ability

An alloy electroplating solution and additive technology, applied in the field of electroplating process, can solve the problems of complex electroplating process, prone to cracks, potential corrosion, etc., and achieve the effects of inhibiting abnormal deposition, improving bonding force, and strong deep plating ability

CN112267134AActive Publication Date: 2021-01-26中山市康迪斯威科技有限公司

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  • Additive of Co-Ni alloy electroplating solution for electroplating
  • Additive of Co-Ni alloy electroplating solution for electroplating
  • Additive of Co-Ni alloy electroplating solution for electroplating

Examples

Experimental program
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Effect test

Embodiment 1

[0075] A surface treatment method for a crystallizer copper plate, characterized in that the copper plate is a chromium-zirconium copper alloy, and the chromium-zirconium copper alloy undergoes the following steps: (1) pretreatment; (2) alkaline electrochemical corrosion treatment; ( 3) High-temperature annealing and reduction, wherein the copper plate of the crystallizer is used as the working electrode, the inert graphite carbon rod is used as the counter electrode, and the positive and negative electrodes can be controlled to reversing the power supply during the alkaline washing electrochemical corrosion treatment process.

[0076] (1) The pretreatment is mechanical grinding-oil removal and degreasing-hot water washing-cold water washing-acid activation-alkali washing-water washing, the mechanical grinding is grinding with 2000 mesh sandpaper, and the oil removal and degreasing is: 25g / LNa 2 CO 3 , 10g / LNaOH, 50g / LNa 3 PO 4 . 12H 2 O, 7g / LNa 2 SiO 3 , temperature 70 ...

Embodiment 2

[0091]A surface treatment method for a crystallizer copper plate, characterized in that the copper plate is a chromium-zirconium copper alloy, and the chromium-zirconium copper alloy undergoes the following steps: (1) pretreatment; (2) alkaline electrochemical corrosion treatment; ( 3) High-temperature annealing and reduction, wherein the copper plate of the crystallizer is used as the working electrode, the inert graphite carbon rod is used as the counter electrode, and the positive and negative electrodes can be controlled to reversing the power supply during the alkaline washing electrochemical corrosion treatment process.

[0092] (1) The pretreatment is mechanical grinding-oil removal and degreasing-hot water washing-cold water washing-acid activation-alkali washing-water washing, the mechanical grinding is grinding with 2000 mesh sandpaper, and the oil removal and degreasing is: 25g / LNa 2 CO 3 , 10g / LNaOH, 50g / LNa 3 PO 4 . 12H 2 O, 7g / LNa 2 SiO 3 , temperature 75 ...

Embodiment 3

[0109] A surface treatment method for a crystallizer copper plate, characterized in that the copper plate is a chromium-zirconium copper alloy, and the chromium-zirconium copper alloy undergoes the following steps: (1) pretreatment; (2) alkaline electrochemical corrosion treatment; ( 3) High-temperature annealing and reduction, wherein the copper plate of the crystallizer is used as the working electrode, the inert graphite carbon rod is used as the counter electrode, and the positive and negative electrodes can be controlled to reversing the power supply during the alkaline washing electrochemical corrosion treatment process.

[0110] (1) The pretreatment is mechanical grinding-oil removal and degreasing-hot water washing-cold water washing-acid activation-alkali washing-water washing, the mechanical grinding is grinding with 2000 mesh sandpaper, and the oil removal and degreasing is: 25g / LNa 2 CO 3 , 10g / LNaOH, 50g / LNa 3 PO 4 . 12H 2 O, 7g / LNa 2 SiO 3 , temperature 80 ...

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Abstract

The invention provides an additive of a Co-Ni alloy electroplating solution for electroplating. The additive comprises chlorobenzaldehyde, 1, 3-propanedithiol, butyne alcohol ether propane sodium sulfonate and sodium diethylenetriamine pentaacetate. The additive can effectively inhibit abnormal deposition of CoNi, a coating is small in grain, the surface is smooth, internal stress is low, deep plating capacity is high, and the electroplating effect is better than that of similar electroplating solutions.

Description

technical field [0001] The invention belongs to an electroplating process, and relates to an additive composition of a Co-Ni alloy electroplating solution for a porous copper plate for a crystallizer. Background technique [0002] Continuous casting is the most important method of producing steel slabs, and the mold is compared to the "heart" of the continuous casting machine. The performance of the mold copper plate directly affects the quality of the casting slab, the production efficiency and production cost of continuous casting, crystallization As an important heat-conducting part of molten steel solidification and forming in continuous casting, the copper plate of the mold is to release the heat of the liquid steel as soon as possible to form a solidified billet shell of sufficient thickness. Therefore, for the copper plate of the mold, its primary function The functional requirement is better thermal conductivity, which is why copper is selected as the mold material. ...

Claims

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Application Information

Patent Timeline
26 Jan 2021
Publication
CN112267134A
IPC
C25D3/56; C25D5/34
CPC
C25D3/562; C25D5/34; Y02P10/20
Inventors
赵玉平