562results about How to "Small grain" patented technology

The invention provides a preparation method of a denitration catalyst, comprising the following steps of: (1) dissolving or dispersing a titanium source precursor and a tungsten source precursor in water to obtain a precursor solution; (2) pouring the precursor solution into a solvent thermal autoclave with stirring for hydrothermal reaction; (3) filtering, washing and drying after the hydrothermal reaction so as to obtain the titanium-tungsten powdered denitration catalyst. According to the preparation method, the hydrothermal synthesis method is adopted to introduce an active component in the mode of in situ synthesis. As the active component is characterized by small crystal grain, low oxidizability and large specific surface, the component can maintain a monolayer dispersion state in a large range. By the titanium-tungsten powder hydrothermal synthesis technology provided by the invention, nationalization of key raw materials of the denitration catalyst can be realized, thus substantially reducing the manufacturing cost of present denitration catalysts.

The invention belongs to the field of petrochemical industry, and relates to a method for preparing propene by catalytic cracking, which is characterized by comprising the following steps: firstly synthesizing molecular sieve ZSM-5 crystal nuclei, and preparing a silicon source, seed crystals, templating agent and deionized water into a colloidal liquid; preparing an aluminum source, inorganic acid or alkali and deionized water into a solution; while stirring, adding the solution into the colloidal liquid to prepare a uniform gel; carrying out hydrothermal crystallization on the gel, and stopping crystallization before the crystallization induction period finishes; and preparing the molecular sieve ZSM-5 crystal nuclei into a catalytic cracking catalyst which is used for preparing propylene and isobutylene by cracking olefins. The molecular sieve ZSM-5 crystal nuclei catalyst only has a weak acid center; the crystal grains are very tiny and do not need any modification treatment, and hydrogen transfer aromatization and other side reactions can be obviously inhibited without any negative pressure or diluent gas condition, thereby enhancing the selectivity of the target product, simplifying the catalytic cracking technique and lowering the catalyst cost.

The invention relates to stirringless, internal circulating and double coordinating electrolyzing oxide treatment technology for organic waste water which is difficult to be degradated, particularly for the waste water containing phenol. Internal circulating plate frame electrolytic tank is used, Ti group PbO2 electrode is used as positive pole, stainless steel is negative pole, waste water containing phenol is used as electrolyte to discharge and generate strong oxide group-hydroxyl free radical on positive pole, negative pole get electron to form H2O2, negative and positive poles are coordinated action to realize deep oxide decomposing to phenol pollutant, and then to achieve the goal of treating waste water containing phenol.

The invention discloses an oxide powder and a preparation method thereof as well as a catalyst and a carrier thereof. The powder comprises powder of hollow microballoon structure which is formed by converged nanocrystalline oxide, and the wall of the hollow microballoon is provided with a porous structure. The preparation method is the method for preparing the powder. Aqueous solution system slurry suitable for spray drying is prepared by a precipitation method, the target powder is obtained through roasting after spray drying, and the catalyst and the carrier thereof comprise the oxide powder. Compared with the prior art, the powder has the porous hollow microballoon structure, thus having high specific surface area and being beneficial to dispersing substances when being used as the catalyst or the carrier thereof; and the processes are simple, easy to operate and suitable for industrialized production.

The invention relates to a magnetic separation type composite adsorbing material which is prepared from nano Fe3O4 and active carbon fiber. The ferriferous oxide nano composition fiber material is synthesized by using conventional organic solvent as the reaction medium under the control of a simple low temperature solvent thermal system. The magnetic separation type composite adsorbing material can be used as a magnetic separation type adsorbing material for adsorbing organic or inorganic pollutants to purify waste water.

The invention provides an annealing-free low-carbon steel coil rod and a production method thereof. The annealing-free low-carbon steel coil rod comprises the following chemical components: 0.04-0.10% of C, 0.01-0.10% of Si, 0.20-0.35% of Mn, at most 0.015% of P, at most 0.010% of S, at most 0.0060% of N, 0.0030-0.0060% of total oxygen, 0.0020-0.0080% of total aluminum, at most 0.1% of inevitable impurity and the balance of iron. The manufacturing method comprises the steps of converter smelting, LF (ladle furnace) refining, continuous casting and rolling, wherein incomplete deoxidation occurs at the tapping side of a converter, the aluminum content of molten steel is reduced by using the high oxygen activity of the molten steel, the carbonization of the molten steel in the refining process is inhibited, bloom protection casting is performed, the temperature for double module input is controlled at 900-920 DEG C, the loop laying temperature is 870-900 DEG C, the speed of a roller way is 0.2-0.4 m/s, and a blower is closed. Thus, the vacuum treatment procedure is omitted, the technical process is shortened, the production cost is lowered, and the requirement of users for canceling the annealing technique in the drawing process is satisfied. For the annealing-free low-carbon steel coil rod produced according to the components and the production method provided by the invention, the grain size is controlled at 20-30 um, the tensile strength is no more than 350 MPa, and the reduction of area is no less than 75%.

A carrier of hydrocatalyst for the hydrocracking of heavy oil, hydromodifying of poor diesel oil, etc is prepared from amorphour silicon aluminium, modified beta-molecular sieve and aluminium oxide. Its preparing process is also disclosed. Said catalyst has high catalytic activity.

The invention relates to a preparation method of a p-n type nano CuO/alpha-Fe2O3 composite semiconductor material, and the material is applied to the field of gas sensors. Pure alpha-Fe2O3 is prepared by using a chemical precipitation method; and the nano CuO/alpha-Fe2O3 composite semiconductor material is further prepared by using a deposition-precipitation method. The CuO/alpha-Fe2O3 composite semiconductor gas sensitive material provided by the invention is simple in preparation technique, low in equipment requirement and low in cost; according to the prepared gas sensitive material, along with the increase of the CuO content, Cu atoms gradually enter alpha-Fe2O3 crystal phases, and the particle sizes of special grains range from 10nm to 20nm. By utilizing the prepared material, effective detection on hydrogen sulfide at room temperature is realized, and the material can rapidly respond to carbon monoxide at both 50 DEG C and 100 DEG C, so that the material has large application prospects.

The invention discloses nano indium tin oxide powder, which comprises an indium compound and a tin compound, wherein a mass ratio of indium oxide to tin oxide is 9:1; and the nano indium tin oxide powder is in an irregular elliptical spherical shape. The ITO nano powder obtained by a method for preparing the ITO nano powder is uniform in grain diameters and high in dispersibility, and the grain diameters are about 60 nanometers.

The invention relates to a composite carrier catalyst used for glycol and synthesized from hydrogenation of alkyl oxalate, and a preparation method thereof. The chemical formula of the composite carrier catalyst is CuO/ROx-Moy. Wherein, CuO accounts for 5-60 mass percent, ROx accounts for 10-90 mass percent, and Moy accounts for 0.1-60 mass percent, x as 1/2 of the highest valency of R, y is 1/2 of the highest valency of M, R is one of Si, Al, Zr and Ti, and M is one of Si, Al, Cr, Zr, Ti, B, Zn, Mo, Ce, Bi, La. Compared with the prior art, in the invention a composite carrier is employed in the catalyst used for glycol and synthesized from hydrogenation of alkyl oxalate. The carrier can effectively disperse the active component copper so as to make the sintering of copper grains hard andextend the service life of the catalyst. Meanwhile, the composite carrier can effectively adjust the surface acidity and basicity, reduce the generation of by-products, and improve the selectivity ofglycol. The total conversion rate of oxalate can reach over 99.9%, while the selectivity of glycol is above 95%. Thus, the catalyst of the invention can be used in the industrial production of glycol.

The invention relates to a die-casting heat resistant magnesium alloy containing Ca and heavy rare earth element Gd and a preparation method thereof, pertaining to the metal material technical field. The components and weight percentage thereof of the alloy are: 3.0 to 8.0 percent of Al, 0.1 to 3.0 percent of Ca, 0.1 to 3.0 percent of Gd, 0 to 0.5 percent of Mn, lower than 0.02 percent of impurity elements and the rest is Mg. The preparation method of the alloy comprises the following steps: the materials are weighed, and industrial pure Mg is heated under the protection of the mixed gas of N2 and 0.2 percent of SF6; after Mg is wholly melted, industrial pure Al, industrial pure Ca and Al-Mn interalloy are added at the temperature of 650 to 680 DEG C, Mg-Gd interalloy is added at the temperature of 660 to 680 DEG C, the temperature is increased to 740 to 760 DEG C, and when the Mg liquid is cooled to 670 to 690 DEG C, the mixture carries out die casting. The preparation method of the invention has the advantages of low cost and high production efficiency, obviously increases the tensile strength, the yield strength, the elongation percentage and the creep resistance of the alloy at room temperature, and has excellent die-casting performance.

The invention discloses a method for synthesizing a small grain SAPO-18/SAPO-34 eutectic molecular sieve. The method is mainly characterized in that a single-template agent or a double-template agent is adopted, a crystal growth inhibitor is added in the synthetic process, and the synthesis parameters are adjusted to carry out crystallization under high-speed stirring. The specific method comprises the following steps: forming a mixed solution A through an aluminum source and water; forming a mixed solution B through a phosphorus source and water; uniformly mixing the solution B with the solution A in a stirring state; sequentially adding the template agent and a silicon source in the stirring state; adding the crystal growth inhibitor, performing hydrothermal crystallization under high-temperature stirring, separating, washing and drying to obtain the molecular sieve. The obtained molecular sieve is characterized by using a powder X-ray diffractometer, and a ratio of AEI/CHA in the eutectic molecular sieve is calculated to be about 50/50-70/30 through DIFFaX. The obtained molecular sieve is small in grain and large in specific surface area and has high activity, selectivity and stability in an olefin preparation reaction through a catalyst methanol.

The invention relates to a method for preparing a copper oxide hydrogenation catalyst loaded on a silica gel-mordenite composite carrier. The method is characterized by comprising the following steps of: (1) activating natural mordenite; (2) dropwise adding a silica gel solution for adjusting a pH value to 2-3 into a mixed solution of copper salt, cerium salt and urea, wherein the copper salt, the cerium salt and the silica sol are CuO, CeO2 and SiO2 respectively based on weight, the molar ratio of CuO to SiO2 is 0.1-0.3, the molar ratio of CeO2 to SiO2 is 0.02-0.05, and the mass ratio of the urea to the copper salt is 0.16-0.21; continuously stirring in a water bath of 70-80 DEG C; adding the activated mordenite when a system is in a semi-gel state, wherein the mass ratio of the copper salt to the activated mordenite is 0.7-2; and continuously stirring to complete gelation, stopping stirring, and aging at room temperature to obtain gel; and (3) selecting the gel, washing until the pH value is 6.5-7.5, drying and roasting at the temperature of 450-600 DEG C to obtain the catalyst. The method has the advantages of high specific surface area, uniform distribution of copper oxide grains serving as a catalytic active component, small crystal grains and high activity.

The present invention discloses a spherical cerium-zirconium base compound oxide and its preparation method. Said invention provides its structure general formula. Said invention adopts urea as precipitant, and utilizes the ammonia gas released by said urea when which is undergone the process of hydrothermal decomposition treatment at 125-135deg.C to make cerium, zirconium and nitrate produce uniform coprecipitation, so that it can make the obtained solid solution sample have the advantages of small grain size, large specific surface area, high oxygen-storing capacity and good thermal stability. Said compound oxide can be extensively used in various catalysts.

The invention discloses a structural steel S420ML medium and heavy plate comprising chemical components of, by weight: 0.12 to 0.15% of C, 0.25 to 0.40% of Si, 1.45 to 1.55% of Mn, no more than 0.017% of P, no more than 0.003% of S, 0.015 to 0.035% of Als, 0.030 to 0.040% of Nb, 0.010 to 0.020% of Ti, 0.010 to 0.020% of Ni, and balance of Fe and residual elements. The carbon equivalent is represented by that: [Ceq=C+Mn/6+(Cr+Mo+V)/5+(Ni+Cu)/15]<=0.41. The production method of the plate comprises processes of KR hot metal pretreating, converter smelting, argon-blowing treating, LF refining, VD refining, continuous casting, heating, controlled rolling and controlled cooling, and stack cooling. During the processes, a TMCP rolling technology and a steel plate stacking and sustained-cooling technology are adopted. With the method provided by the invention, components in S420ML can be ensured; contents of harmful elements such as P and S can be strictly controlled; a heating system in the steel rolling process is strictly controlled; during a rolling process, a finishing temperature, a self-tempering temperature and a cooling speed are strictly controlled; and methods such as a steel plate stacking and sustained-cooling technology are adopted. Therefore, performance indexes of a 20-50mm hot-rolled weldable fine-grain structural steel S420ML medium and heavy plate can reach required standards.

The invention belongs to the field of preparation of molecular sieves and particularly relates to a rapid synthesis method for small-crystal-grain molecular sieves and an application of the small-crystal-grain molecular sieves. The rapid synthesis of the small-crystal-grain molecular sieves is achieved through the procedures of firstly, preparing a precursor mixture, then, preparing gel and finally carrying out direct crystallization. The method is applied to the synthesis of the following molecular sieves, but not limited to: ZSM-5, ZSM-11, ZSM-22, ZSM-23, ZSM-35, SAPO-34, SAPO-11, SAPO-18, SSZ-13 and EU-1. Molecular sieve products synthesized by the method have the characteristics of small crystal grain, large specific surface area, high crystallinity and high yield. According to the method, the crystallization time can be shortened greatly, the production efficiency is increased, and the manufacturing cost of the molecular sieves is reduced.

The invention provides a novel method for producing propylene and ethylene through catalytic cracking of olefins, which comprises the steps of: taking C4-C12 olefins as raw materials; and performing acatalytic cracking reaction of the olefins on the raw materials through a catalyst bed to generate the propylene and the ethylene under the conditions that the reaction temperature is between 450 and650 DEG C, the reaction pressure is between 0 and 0.3MPa, the weight space velocity of the olefins is between 1 and 14 h<-1>, and the weight ratio of water to the olefins is 0.1-10, wherein a catalyst comprises a ZSM-5 molecular sieve, an adhesive and a phosphorus element supported on the catalyst, the silicon-aluminum molar ratio SiO2/Al2O3 of the ZSM-5 molecular sieve is 10-300, and the grain diameter of crystal grains of the ZSM-5 molecular sieve is between 10 and 800nm. The method has longer reaction operation time while maintaining the high yield of the propylene and the ethylene, and can be used for industrialized production.

The invention discloses a method for preparing nanoscale boron modified HZSM-5 by seed crystal directing. The method comprises the steps as follows: (1) mixing an aluminum source, a silicon source, an alkali source, a boron source, ZSM-5 molecular sieve seed crystals and water, adjusting the pH of an obtained mixture to 10-12 and mixing the mixture uniformly to form gel; (2) crystallizing the gel in a reactor, and performing solid-liquid separation, washing and drying on a crystallized product to obtain a dried crystallized product; (3) adding the dried crystallized product in an ammonium salt solution for ion exchange to obtain an ammonia type ZSM-5 molecular sieve; (4) roasting the ammonia type ZSM-5 molecular sieve to obtain HZSM-5. The invention further discloses a molecular sieve prepared by the method and application of the molecular sieve in a reaction of methanol to propylene. The boron modified HZSM-5 requires no roasting of a template agent and is environment-friendly, the propylene yield and the service life are greatly increased, the selectivity of propylene reaches 44.0wt% or higher, and the service life reaches 500 h or longer.

The invention discloses an ultra-fine grained HPB300 hot-rolling optical disc stripe reinforcing steel bar and a preparation method thereof. The ultra-fine grained HPB300 hot-rolling optical disc stripe reinforcing steel bar comprises the following components in percentage by weight: 0.15-0.18% of C, 0.10-0.16% of Si, 0.16-0.28% of Mn, 0.080-0.120% of Cr, 0.0010-0.0020% of B, less than 0.030% of S, less than 0.045% of P and the balance of Fe. The reinforcing steel bar is prepared from molten iron, steel scrap and pig iron through steps of molten steel smelting, molten steel pouring and billet controlled rolling and controlled cooling. According to the reinforcing steel bar, a small amount of ferromanganese, ferroboron and high carbon ferro-chrome alloy into the steel-making step, so that the alloying cost is remarkably lowered. By adopting low-temperature controlled rolling before spinning and a stelmor roller aerial fog cooling process after spinning, the reinforcing steel bar has the advantages of low cost, good toughness, excellent high- and low-temperature performance, low stress time-validity and the like.

The invention relates to a prepration method of a SO4<2->/ZrO2-MxOy solid superacid catalyst and the application thereof. The preparation method adopts the coprecipitation method for the preparation, thereby obtaining a precursor of a binary mixed hydroxide containing Zr and M (M is equal to Al or Fe), the precursor is carried out the hydrothermal treatment, dilute sulfuric acid is used for soaking, and the solid superacid catalyst with the larger specific surface area is obtained after the high-temperature calcination. The catalyst can obtain good effect, high conversion rate of Alpha-pinene and high selectivity of target products of camphene and limonene by being applied in the Alpha-pinene isomerization reaction.