Ultrahigh-temperature high-strength tough cement paste system

An ultra-high temperature, high-strength technology, applied in the field of oil and gas exploration and development, can solve the problems of inability to meet the needs of ultra-high temperature and ultra-deep well cementing operations in complex formations, the decline of ultra-high temperature cement stone strength, and insufficient ultra-high temperature strength, so as to improve rheology. And pumpability, good application performance, good temperature resistance

Active Publication Date: 2021-02-09
BC P INC CHINA NAT PETROLEUM CORP +3
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

Invention patent "An oil well cement slurry system for preventing high-temperature strength decline and its preparation method" (CN110484223A) uses a graphene emulsion as a strength enhancer, and micron-sized shaped silica and 8-12% xanthan gum as a suspension stabilizer. The construction performance of the cement slurry is good at 180°C, the strength is 35MPa, and it will not decline within 14 days, but the cost of materials used in this method is high, and it is not suitable for cementing construction under ultra-high temperature conditions above 200°C
Invention patent "A cementing cement for ultra-high temperature deep wells and its preparation method and application" (CN 110563428 A) uses silicon powder as the first anti-strength decay agent, and t

Method used

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  • Ultrahigh-temperature high-strength tough cement paste system
  • Ultrahigh-temperature high-strength tough cement paste system
  • Ultrahigh-temperature high-strength tough cement paste system

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0030] Formula: 100 parts of high sulfate-resistant G-grade oil well cement, 40 parts of 600-mesh acid-washed quartz sand, 10 parts of anti-high temperature strength decline material (100-mesh wollastonite and 100-mesh coke gemstone in a mass ratio of 1:1) , 3 parts of ultra-high temperature toughening agent halloysite nanotubes, 1 part of polycarboxylic acid dispersant, 3 parts of ultra-high temperature stabilizer (mass ratio of bentonite, magnesium aluminum silicate, and wenlun glue is 1:2:1), 2 parts of fluid loss reducer (patent application number 201910693705.9), 1.2 parts of retarder (patent number CN 104403056 B), 0.1 part of tributyl phosphate (defoamer), 55 parts of clear water.

[0031] The cement slurry preparation process is as follows: take 100 parts of oil well cement, 40 parts of 600-mesh acid-washed quartz sand, 10 parts of high-temperature strength decay resistance material, 3 parts of ultra-high temperature toughening agent halloysite nanotubes, 1 part of poly...

Embodiment 2

[0033]Formula: 100 parts of high sulfate-resistant G-grade oil well cement, 40 parts of 600-mesh acid-washed quartz sand, anti-high temperature strength decline material (100-mesh wollastonite and 200-mesh bauxite in a mass ratio of 1:1) 15 3 parts, 3 parts of ultra-high temperature toughening agent halloysite nanotubes, 1 part of polycarboxylic acid dispersant, 3 parts of ultra-high temperature stabilizer (the mass ratio of bentonite, magnesium aluminum silicate, and wenlun gum is 1:2:1) , 2 parts of water loss reducer (patent application number 201910693705.9), 1.2 parts of retarder (patent number CN 104403056 B), 0.1 part of tributyl phosphate (defoamer), 55 parts of water.

[0034] The cement slurry preparation process is as in Example 1.

Embodiment 3

[0036] Formula: 100 parts of high sulfate-resistant G-grade oil well cement, 40 parts of 600-mesh acid-washed quartz sand, anti-high temperature strength decline material (200-mesh kyanite and 200-mesh bauxite compounded at a mass ratio of 1:1) 15 3 parts, 3 parts of ultra-high temperature toughening agent halloysite nanotubes, 1 part of polycarboxylic acid dispersant, 3 parts of ultra-high temperature stabilizer (the mass ratio of bentonite, magnesium aluminum silicate, and wenlun gum is 1:2:1) , 2 parts of water loss reducer (patent application number 201910693705.9), 1.2 parts of retarder (patent number CN 104403056 B), 0.1 part of tributyl phosphate (defoamer), 55 parts of water.

[0037] The cement slurry preparation process is as in Example 1.

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Abstract

The invention relates to an ultrahigh-temperature high-strength tough cement paste system which is composed of the following components in parts by weight: 100 parts of high-sulfate-resistance G-gradeoil well cement, 35-45 parts of acid-pickled quartz sand, 10-20 parts of an ultrahigh-temperature strength anti-recession material, 2-5 parts of an ultrahigh-temperature toughening material, 0.5-2 part of a dispersing agent, 2-4 parts of an ultrahigh-temperature stabilizer, 0.5-4 part of a fluid loss agent, 0.2-2 part of a retarder, 0.1-1 part of a defoaming agent and 40-80 parts of clear water.The acid-pickled quartz sand is refined quartz sand subjected to acid treatment, the ultra-high-temperature strength anti-recession material is a mixture of two or more of wollastonite, kyanite, calcined flint clay and aluminite, the ultra-high-temperature toughening material is a halloysite nanotube, the dispersing agent is a polycarboxylic acid dispersing agent for oil well cement, and the ultra-high-temperature stabilizer is a mixture of bentonite, magnesium aluminum silicate and welan gum. The strength of set cement does not decline under the ultra-high temperature condition, the toughnessis good, and the well cementation quality of unconventional oil and gas wells and high-temperature deep wells is effectively improved.

Description

technical field [0001] The invention relates to an ultra-high-temperature high-strength toughness cement slurry system in the field of petroleum and natural gas exploration and development, which is suitable for ultra-high-temperature deep well cementing operations with a bottom-hole circulation temperature (BHCT) above 210°C and a bottom-hole static temperature (BHST) above 240°C. Background technique [0002] With the rapid development of my country's economy and society, the demand for oil and gas resources continues to grow. In order to ensure national energy security and reduce oil and gas dependence on foreign countries, it is necessary to increase exploration and development efforts. Deep and ultra-deep oil and gas have great potential and are important replacement resources. Basins such as Tarim, Junggar, Sichuan, and Qaidam have successively proven oil and gas reservoirs deeper than 8,000 m. With the deepening of oil and gas exploration and development, the number o...

Claims

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Application Information

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IPC IPC(8): C04B28/02
CPCC04B28/02C04B2201/50C04B2111/00724C04B14/06C04B14/043C04B14/10C04B14/005C04B14/104C04B14/04C04B24/38C04B24/003C04B2103/408C04B2103/0068C04B2103/22
Inventor 刘慧婷靳建洲于永金张华刘子帅张弛徐明刘硕琼李明夏修建纪宏飞郭雪利
Owner BC P INC CHINA NAT PETROLEUM CORP
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