MXene-based water-based nano electric heating composite coating and preparation method thereof
An electrothermal composite, water-based technology, applied in the field of nanocomposite coatings and their preparation, can solve the problems of limiting electrothermal coatings, low filler content and low electrical conductivity, and achieves good flexibility, strong coating adhesion, and excellent electrothermal properties. performance effect
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Embodiment 1
[0025] Embodiment 1: it is 20% emulsion that waterborne polyurethane is diluted with water into mass fraction; Ti 3 C 2 T x MXene was prepared as an aqueous dispersion with a mass fraction of 2%; waterborne polyurethane and Ti 3 C 2 T x The mass ratio of MXene was set to 8:2; the aqueous polyurethane emulsion was stirred at a speed of 3000rpm, and then the Ti 3 C 2 T x Add the MXene dispersion to the water-based polyurethane emulsion, and keep stirring for 5 hours to make the water-based polyurethane fully adsorb on the Ti 3 C 2 T x On the MXene nanosheet; add 0.5% (accounting for resin mass fraction) of butanone and 1% (accounting for resin mass fraction) of diethylene glycol monobutyl ether to the above-mentioned composite dispersion liquid, and continue stirring for 0.5h to obtain a composite conductive coating; Spray an appropriate amount of conductive composite paint on the surface of the aluminum alloy, and dry it at room temperature for 24 hours.
Embodiment 2
[0026] Embodiment 2: Water-based polyurethane and water-based polyacrylate are respectively diluted with water into an emulsion with a mass fraction of 30%; the two water-based emulsions are mixed uniformly with a mass ratio of 9:1; Ti 3 C 2 T x MXene was prepared as an aqueous dispersion with a mass fraction of 5%; the water-based resin ester and Ti 3 C 2 T x The mass ratio of MXene was set to 7:3; the waterborne polyurethane / waterborne polyacrylate mixed emulsion was stirred at a speed of 3500rpm, and then the Ti 3 C 2 T x Add the MXene dispersion to the water-based polyurethane / water-based polyacrylate mixed emulsion, and keep stirring for 3 hours to make the water-based polyurethane / water-based polyacrylate fully adsorb on the Ti 3 C 2 T x On the MXene nanosheet; Add 0.5% (accounting for resin massfraction) of ethyl acetate, 0.5% (accounting for resin massfraction) of NMP and 0.5% (accounting for resin massfraction) of diethylene glycol monobutylene in the abov...
Embodiment 3
[0027] Embodiment 3: Water-based polyurethane, water-based polyacrylate and water-based epoxy resin are respectively diluted with water into emulsions with a mass fraction of 30%, 30% and 10%; the three water-based emulsions are mixed uniformly with a mass ratio of 5:3:2 ; put Ti 3 C 2 T x MXene and Ti 3 CNT xMXene was formulated into aqueous dispersions with mass fractions of 3% and 2%, respectively; the two MXenes were mixed uniformly at a mass ratio of 9:1; the mass ratio of water-based resin ester to MXene was set at 9:1; stirring at a speed of 5000rpm Water-based mixed emulsion, then the MXene mixed dispersion is added to the water-based mixed emulsion, and the stirring is continued for 2h so that the water-based resin is fully adsorbed on the MXene nanosheets; 0.5% (accounting for resin mass fraction) ethyl acetate is added to the above-mentioned composite dispersion and 1% (accounting for resin mass fraction) of DMF, and continue to stir for 0.5h to obtain a compos...
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