Looking for breakthrough ideas for innovation challenges? Try Patsnap Eureka!

MXene-based water-based nano electric heating composite coating and preparation method thereof

An electrothermal composite, water-based technology, applied in the field of nanocomposite coatings and their preparation, can solve the problems of limiting electrothermal coatings, low filler content and low electrical conductivity, and achieves good flexibility, strong coating adhesion, and excellent electrothermal properties. performance effect

Pending Publication Date: 2021-06-08
NORTHWESTERN POLYTECHNICAL UNIV
View PDF9 Cites 9 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the surface of these fillers lacks functional groups with affinity for water and other organic solvents, and they are difficult to disperse in water, solvents and polymer matrices to form a homogeneous system, nor can they form a strong bond with polymer molecular chains Force, so the resulting coatings have low filler levels and correspondingly low electrical conductivity
Moreover, most of the coatings based on these conductive fillers are dispersed in organic solvents, and the organic volatile gases generated during use will bring harm to the environment.
These deficiencies have limited the further development of environmentally friendly high-performance electrothermal coatings

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • MXene-based water-based nano electric heating composite coating and preparation method thereof
  • MXene-based water-based nano electric heating composite coating and preparation method thereof
  • MXene-based water-based nano electric heating composite coating and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0025] Embodiment 1: it is 20% emulsion that waterborne polyurethane is diluted with water into mass fraction; Ti 3 C 2 T x MXene was prepared as an aqueous dispersion with a mass fraction of 2%; waterborne polyurethane and Ti 3 C 2 T x The mass ratio of MXene was set to 8:2; the aqueous polyurethane emulsion was stirred at a speed of 3000rpm, and then the Ti 3 C 2 T x Add the MXene dispersion to the water-based polyurethane emulsion, and keep stirring for 5 hours to make the water-based polyurethane fully adsorb on the Ti 3 C 2 T x On the MXene nanosheet; add 0.5% (accounting for resin mass fraction) of butanone and 1% (accounting for resin mass fraction) of diethylene glycol monobutyl ether to the above-mentioned composite dispersion liquid, and continue stirring for 0.5h to obtain a composite conductive coating; Spray an appropriate amount of conductive composite paint on the surface of the aluminum alloy, and dry it at room temperature for 24 hours.

Embodiment 2

[0026] Embodiment 2: Water-based polyurethane and water-based polyacrylate are respectively diluted with water into an emulsion with a mass fraction of 30%; the two water-based emulsions are mixed uniformly with a mass ratio of 9:1; Ti 3 C 2 T x MXene was prepared as an aqueous dispersion with a mass fraction of 5%; the water-based resin ester and Ti 3 C 2 T x The mass ratio of MXene was set to 7:3; the waterborne polyurethane / waterborne polyacrylate mixed emulsion was stirred at a speed of 3500rpm, and then the Ti 3 C 2 T x Add the MXene dispersion to the water-based polyurethane / water-based polyacrylate mixed emulsion, and keep stirring for 3 hours to make the water-based polyurethane / water-based polyacrylate fully adsorb on the Ti 3 C 2 T x On the MXene nanosheet; Add 0.5% (accounting for resin massfraction) of ethyl acetate, 0.5% (accounting for resin massfraction) of NMP and 0.5% (accounting for resin massfraction) of diethylene glycol monobutylene in the abov...

Embodiment 3

[0027] Embodiment 3: Water-based polyurethane, water-based polyacrylate and water-based epoxy resin are respectively diluted with water into emulsions with a mass fraction of 30%, 30% and 10%; the three water-based emulsions are mixed uniformly with a mass ratio of 5:3:2 ; put Ti 3 C 2 T x MXene and Ti 3 CNT xMXene was formulated into aqueous dispersions with mass fractions of 3% and 2%, respectively; the two MXenes were mixed uniformly at a mass ratio of 9:1; the mass ratio of water-based resin ester to MXene was set at 9:1; stirring at a speed of 5000rpm Water-based mixed emulsion, then the MXene mixed dispersion is added to the water-based mixed emulsion, and the stirring is continued for 2h so that the water-based resin is fully adsorbed on the MXene nanosheets; 0.5% (accounting for resin mass fraction) ethyl acetate is added to the above-mentioned composite dispersion and 1% (accounting for resin mass fraction) of DMF, and continue to stir for 0.5h to obtain a compos...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

No PUM Login to View More

Abstract

The invention relates to an MXene-based water-based nano electric heating composite coating and a preparation method thereof, and the MXene-based water-based nano electric heating composite coating is prepared by the following steps: by using a water-dispersible MXene nanosheet as a conductive filler, respectively using water-based polyurethane, water-based polyacrylate or water-based epoxy resin and MXene to prepare water dispersion liquids with certain mass fractions, adding the MXene dispersion liquid into the water-based resin according to a preset mass ratio of the water-based resin to the MXene under the stirring action, and continuously conducting stirring to enable water-based resin macromolecules to be fully and uniformly adsorbed on MXene nanosheets, so as to obtain the water-based resin ester-MXene nano electric heating composite coating. The prepared coating can be constructed through spraying, dip-coating, roller coating or dispensing and other methods, has excellent electric heating performance and heating regulation performance, is high in adhesive force and good in flexibility, has the resistivity capable of being regulated as required, is low in required voltage and high in temperature rise rate, is not limited by the surface appearance of a base material in use, and is wide in application range.

Description

technical field [0001] The invention belongs to the field of electrothermal coating materials, and relates to an MXene-based water-based nanometer electrothermal composite coating and a preparation method thereof. 3 C 2 T x MXene is a nanocomposite coating of conductive filler and a preparation method thereof. Background technique [0002] Electrothermal paint is a functional conductive paint that can generate Joule heat under the action of an applied voltage. The traditional electric heating material is generally a metal wire. Although it has excellent heating performance, it will cause uneven heating due to the gaps in its layout. At the same time, it cannot be used on special-shaped and small parts, which limits its application. Electrothermal paint can form a uniform conductive film on the surface of the components used, and is not limited by the shape of the surface, thus showing broad application prospects in the field of electrothermal materials. [0003] At pres...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
Patent Type & Authority Applications(China)
IPC IPC(8): C09D5/24C09D175/04C09D133/04C09D163/00
CPCC08K2201/001C08K2201/011C08L2205/03C09D5/24C09D133/04C09D163/00C09D175/04C08K7/00C08L33/04C08L63/00C08L75/04
Inventor 张秋禹刘宗旭朱苞蕾王文艳王金鑫
Owner NORTHWESTERN POLYTECHNICAL UNIV
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Patsnap Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Patsnap Eureka Blog
Learn More
PatSnap group products