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Phosphorus-free nitrogen-free dye-accelerating repairing agent and preparation method thereof

A technology of repairing agent and co-solvent, which is applied in the field of dyeing processing aids, can solve the problems of excessive copper ion content, increase the load of printing and dyeing wastewater and waste gas treatment, and cannot meet the requirements of emission standards at the same time, and achieve good value, good level dyeing and Correction rate, effect of guaranteeing stability and reliability

Inactive Publication Date: 2021-08-13
GUANGDONG ZHAN FENG FINE CHEM CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the raw materials used in such patents partially contain phosphorus (such as: isomeric decanol ether phosphate), nitrogen (such as: piperazine carboxylate, fatty amine polyoxyethylene ether, ethylenediamine bisdimethylheptyl Sodium alkyl sulfonate) elements, volatile and flammable solvents (such as: ethanol), increase the load of printing and dyeing wastewater and waste gas treatment; after the modification of benzyl benzoate, it is loaded with foamed copper, which may cause fabric damage after treatment. Upper copper ion content exceeds the standard
[0004] At present, there are many repairing agent products used in the domestic and foreign markets, and the products cannot meet ZDHC's MRSL (v2.0), Oeko-Tex Standard 100's MRSL (v2020.2), bluesign's BSSL (v10.1), REACH The requirements of the SVHC (205 items) and other regulations, as well as the discharge standards of printing and dyeing wastewater, waste gas, etc.

Method used

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  • Phosphorus-free nitrogen-free dye-accelerating repairing agent and preparation method thereof
  • Phosphorus-free nitrogen-free dye-accelerating repairing agent and preparation method thereof
  • Phosphorus-free nitrogen-free dye-accelerating repairing agent and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0036] a, under normal temperature and pressure, add semi-branched biomass phenol polyoxyethylene ether (N EO =25) 15g, polyethylene glycol oleic acid monoester (600MO) 5g, isomerism decanol polyoxyethylene polyoxypropylene ether sulfate (C 10 EO 5 PO 2 S) 3g, isomerism dodecyl alcohol polyoxyethylene polyoxypropylene ether sulfate (C 12 EO 5 PO 2 S) 1g, 1g of sodium dodecyl diphenyl ether disulfonic acid, 3g of glycerol, 3g of triethylene glycol and 9g of deionized water, heated to 85°C and stirred for 30min to form a stable and uniform solution.

[0037] b. Cool to 60°C under continuous stirring, then add 20 g of dibutyl 1,4-cyclohexanecarboxylate and 15 g of diisononyl 1,2-cyclohexanecarboxylate to the mixture obtained in step a , 2-(acetyl)-1,2,3-tributyl tricarboxylate 20g and then stirred for 50min to form a stable and uniform solution, and cooled to room temperature to obtain the non-phosphorous and nitrogen-free dye-promoting repairing agent 1 #.

Embodiment 2

[0039] a, under normal temperature and pressure, add semi-branched biomass phenol polyoxyethylene ether (N EO =25) 5g, semi-branched biomass phenol polyoxyethylene ether sodium sulfonate (N EO =25) 5g, polyethylene glycol oleic acid monoester (600MO) 5g, isomerism decanol polyoxyethylene polyoxypropylene ether sulfate (C 10 EO 5 PO 2 S) 3g, isomerism dodecyl alcohol polyoxyethylene polyoxypropylene ether sulfate (C 12 EO 5 PO 2 S) 1g, isomeric tridecanol polyoxyethylene polyoxypropylene ether sulfate (C 10 EO 5 PO 2 S) 5g, 1g of sodium dodecyl diphenyl ether disulfonic acid, 3g of glycerol, 7g of triethylene glycol and 10g of deionized water, heated to 85°C and stirred for 30min to form a stable and uniform solution.

[0040] b. Cool to 60°C under continuous stirring, then add 20 g of dibutyl 1,4-cyclohexanecarboxylate and 20 g of diisononyl 1,2-cyclohexanecarboxylate to the mixture obtained in step a , 2-(acetyl)-1,2,3-tributyl tricarboxylate 15g and then stirred for...

Embodiment 3

[0042] a, under normal temperature and pressure, add semi-branched biomass phenol polyoxyethylene ether (N EO =25) 5g, semi-branched biomass phenol polyoxyethylene ether sodium sulfonate (N EO =25) 5g, polyethylene glycol oleic acid monoester (600MO) 15g, isomerism decanol polyoxyethylene polyoxypropylene ether sulfate (C 10 EO 5 PO 2 S) 3g, isomerism dodecyl alcohol polyoxyethylene polyoxypropylene ether sulfate (C 12 EO 5 PO 2 S) 1g, isomeric tridecanol polyoxyethylene polyoxypropylene ether sulfate (C 10 EO 5 PO 2 S) 5g, 1g of sodium dodecyl diphenyl ether disulfonic acid, 3g of glycerol, 2g of triethylene glycol and 10g of deionized water, heated to 90°C and stirred for 15min to form a stable and uniform solution.

[0043] b. Cool to 60°C under continuous stirring, then add 20g of dibutyl 1,4-cyclohexanecarboxylate and 25g of diisononyl 1,2-cyclohexanecarboxylate to the mixture obtained in step a , 2-(acetyl)-1,2,3-tributyl tricarboxylate 5g and stirred for 35min ...

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Abstract

The invention discloses a phosphorus-free nitrogen-free dye-accelerating repairing agent and a preparation method thereof. The phosphorus-free nitrogen-free dye-accelerating repairing agent comprises the following components of 30-60% of ester compound, 10-30% of emulsifying dispersant, 1-13% of cosolvent and 0-10% of deionized water, wherein the ester compound comprises a compound of formula (1), a compound of formula (2) or a combination of the compound of formula (1) and the compound of formula (2), wherein the compound of formula (1) is 1, 4-cyclohexane carboxylic acid ester, and the compound of formula (2) is one or a mixture of 1, 2-cyclohexane carboxylic acid ester and 2-(acetyl)-1, 2, 3-tricarboxylic acid tributyl ester in any proportion. According to the repairing agent, 1, 4-cyclohexane carboxylic acid dibutyl ester, 1, 2-cyclohexane carboxylic acid diisononyl ester and 2-(acetyl)-1, 2, 3-tricarboxylic acid tributyl ester are adopted as the main plasticizers so as to provide the excellent migration dyeing, after-finishing and repairing performance, and the good leveling property and the good correction rate are obtained when the repairing agent is used for the dyeing and the repairing of the polyester fiber fabric.

Description

technical field [0001] The invention specifically relates to a dyeing and processing auxiliary agent for polyester textiles, in particular to a non-phosphorous and nitrogen-free dyeing accelerator and repairing agent and a preparation method thereof. Background technique [0002] Polyester fiber is widely used. It has compact structure, high crystallinity, and difficult dyeing. Commonly used disperse dyes are dyed by high temperature, high pressure or hot melt. However, accidents or mistakes occur from time to time during the dyeing process, resulting in dyeing defects such as colored flowers, color differences, and stripes in dyed fabrics. Although dyeing and finishing workers are aware of these problems, they cannot be completely predicted or avoided; after dyeing defects appear, color correcting agents are passively used to solve them. The color correction agents such as wintergreen oil and methylnaphthalene used in the early days are not only poisonous and smelly, but a...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): D06P1/651D06P1/613D06P1/62D06P1/16D06P3/54
CPCD06P1/65125D06P1/6135D06P1/6133D06P1/6138D06P1/625D06P1/65118D06P1/65131D06P1/16D06P3/54
Inventor 李中全邹其光
Owner GUANGDONG ZHAN FENG FINE CHEM CO LTD