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Durable antibacterial composite fabric based on graphene and preparation method thereof

A composite fabric and graphene technology, applied in the field of textile fabrics, can solve problems such as inability to exert antibacterial effect, odor, and reduce fabric air permeability, so as to increase self-cleaning and anti-fouling properties, increase specific surface area, and improve bactericidal performance Effect

Active Publication Date: 2021-09-28
江苏江山红化纤有限责任公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] The raw materials of conventional fabrics are mainly cotton, hemp, silk, polyester, nylon, etc. Textile fiber fabrics with a porous structure are easy to absorb bacteria during use, and the sweat discharged from the human body and the shed sebum provide a rich environment for the reproduction of fungi. The nutrition of bacteria can cause the growth of bacteria. The growth of bacteria not only produces peculiar smell, but also easily causes cross infection and spreads diseases. It is also easy to damage fibers. With the improvement of living standards, people pay more and more attention to the comfort and functionality of textiles. Traditional fabrics Can no longer meet people's use requirements
[0003] Graphene oxide can destroy the cell membrane of bacteria, thereby causing the outflow of intracellular substances and killing bacteria, while most of the existing graphene antibacterial fabrics are prepared by directly setting a bonding coating on the fabric, and directly setting the coating on the fabric will cause The air permeability of the fabric is greatly reduced, and the washability is poor, so it cannot exert a lasting antibacterial effect

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0033] S1: Preparation of the skin-friendly layer

[0034] Cotton fibers are woven to form a skin-friendly layer;

[0035] S2: Preparation of the sweat-absorbing layer

[0036] (1) Impregnating bamboo fibers with 2wt% sodium hydroxide, repeatedly cleaning the bamboo fibers with deionized water to neutrality, and drying; adding the dried bamboo fibers to a water-soluble phenolic resin with a solid content of 33% Soak for 36 hours and dry; under nitrogen protection, keep the temperature at 150 °C for 3 hours of oxidation, then increase the temperature to 600 °C for reaction, cool to 20 °C, add hydrochloric acid, soak for 90 minutes, repeatedly wash with deionized water until neutral, and dry , to obtain modified bamboo fiber;

[0037] (2) Modified bamboo fiber weaving, sewed on the surface of the skin-friendly layer through fiber filaments to form a sweat-absorbing layer;

[0038] S3: Preparation of Antibacterial Layer

[0039] (1) Under the action of ultrasound, add 0.1 mol...

Embodiment 2

[0047] S1: Preparation of the skin-friendly layer

[0048] Cotton fibers are woven to form a skin-friendly layer;

[0049] S2: Preparation of the sweat-absorbing layer

[0050] (1) Impregnating bamboo fibers with 3wt% sodium hydroxide, repeatedly cleaning the bamboo fibers with deionized water to neutrality, and drying; adding the dried bamboo fibers to a water-soluble phenolic resin with a solid content of 36% Soak for 30 hours and dry; under nitrogen protection, keep the temperature at 200 °C for 2 hours of oxidation, then raise the temperature to 800 °C for reaction, cool to 22 °C, add hydrochloric acid, soak for 80 minutes, repeatedly wash with deionized water until neutral, and dry , to obtain modified bamboo fiber;

[0051] (2) Modified bamboo fiber weaving, sewed on the surface of the skin-friendly layer through fiber filaments to form a sweat-absorbing layer;

[0052] S3: Preparation of Antibacterial Layer

[0053] (1) Under the action of ultrasound, add 0.3mol / L a...

Embodiment 3

[0061] S1: Preparation of Modified Bamboo Fibers

[0062] S1: Preparation of the skin-friendly layer

[0063] Cotton fibers are woven to form a skin-friendly layer;

[0064] S2: Preparation of the sweat-absorbing layer

[0065] (1) Impregnating bamboo fibers with 10wt% sodium hydroxide, repeatedly cleaning the bamboo fibers with deionized water to neutrality, and drying; adding the dried bamboo fibers to a water-soluble phenolic resin with a solid content of 40% Soak for 24 hours and dry; under nitrogen protection, keep oxidized at 250 °C for 1 hour, then raise the temperature to 900 °C for reaction, cool to 25 °C, add hydrochloric acid, soak for 30 minutes, repeatedly wash with deionized water until neutral, and dry , to obtain modified bamboo fiber;

[0066] (2) Modified bamboo fiber weaving, sewed on the surface of the skin-friendly layer through fiber filaments to form a sweat-absorbing layer;

[0067] S3: Preparation of Antibacterial Layer

[0068] (1) Under the acti...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
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PUM

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Abstract

The invention discloses a lasting antibacterial composite fabric based on graphene. The lasting antibacterial composite fabric comprises a skin-friendly layer, a sweat absorption layer, an antibacterial layer and an anti-ultraviolet layer, water-soluble phenolic resin is used for carrying out modification treatment on bamboo fibers, so that the modified bamboo fibers have high specific surface area, and the adsorbability, the antibacterial property, the deodorization property and the ultraviolet resistance of the bamboo fibers are greatly improved; graphene oxide quantum dots are used as a matrix for fixing cerium oxide nano-particles, so that the cerium oxide nano-particles are uniformly distributed on the graphene oxide quantum dot nano-sheets, and the effects of slowly releasing the cerium oxide nano-particles and resisting bacteria for a long time are achieved by adding chitosan and glycerol; and nano zinc oxide and flower-like titanium dioxide are organically combined in the anti-ultraviolet layer, so that UVA and UVB in sunlight ultraviolet rays can be effectively shielded, and the self-cleaning property and the pollution resistance of the fabric are improved.

Description

technical field [0001] The invention belongs to the technical field of textile fabrics, and in particular relates to a graphene-based durable antibacterial composite fabric and a preparation method thereof. Background technique [0002] The raw materials of conventional fabrics are mainly cotton, hemp, silk, polyester, nylon, etc. The textile fiber fabrics with porous structure are easy to absorb bacteria during use, and the sweat and sebum excreted by the human body provide abundant resources for the reproduction of fungi. The nutrition of textiles will cause the growth of bacteria. The growth of bacteria not only produces odor, but also easily causes cross-infection and spreads diseases. It is also easy to damage fibers. With the improvement of living standards, people pay more and more attention to the comfort and functionality of textiles. Traditional fabrics It can no longer meet people's usage requirements. [0003] Graphene oxide can destroy the cell membrane of bact...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B32B9/02B32B9/04B32B37/00B32B37/12B32B38/08D06M11/74D06M11/45D06M13/148D06M15/03D06M11/44D06M11/46D06M13/513D06M101/06
CPCB32B5/02B32B5/26B32B37/00B32B37/12B32B38/08D06M11/74D06M11/45D06M13/148D06M15/03D06M11/44D06M11/46D06M13/513D06M16/00D06M2101/06B32B2262/062B32B2262/065B32B2260/021B32B2260/04B32B2260/046B32B2307/7145B32B2307/71B32B2307/754B32B2307/7163
Inventor 倪张根黄荣庆曹建鹏
Owner 江苏江山红化纤有限责任公司
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