Looking for breakthrough ideas for innovation challenges? Try Patsnap Eureka!

Underwater epoxy resin curing agent and preparation method thereof

A technology of epoxy resin curing and amine curing agent, which is applied in the field of polymer material synthesis and preparation, can solve the problems of poor curing performance and environmental protection of curing agent in water, and improve weather resistance, environmental protection and weather resistance. Excellent, simple preparation process

Active Publication Date: 2021-09-28
CNBM ZHONGYAN TECH
View PDF7 Cites 0 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] The preparation process has easy-to-obtain raw materials, simple method, and easy operation, and effectively solves the problems of ordinary epoxy resin curing agents that are difficult to cure in water, poor curing performance of water curing agents, and poor environmental protection. application is very important

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Underwater epoxy resin curing agent and preparation method thereof
  • Underwater epoxy resin curing agent and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0025] Diethylene triamine, neopentyl glycol diglycidyl ether, highly brominated DGEBA with a relative molecular weight of 1400, tris(dimethylaminomethyl)phenol, dibutyl phthalate, methyl hydrogen silicone oil according to The mass ratio is 60:15:15:5:3:2 for weighing. First, mix and stir neopentyl glycol diglycidyl ether and highly brominated DGEBA with a relative molecular weight of 1400, then add diethylenetriamine curing agent, and stir for 3 hours at 50°C; when the temperature is cooled to room temperature, add The weighed tris(dimethylaminomethyl)phenol, dibutyl phthalate and methyl hydrogen-containing silicone oil can be continuously mixed and stirred.

Embodiment 2

[0027] Triethylenetetramine, hexanediol diglycidyl ether, hyperbrominated DGEBA with a relative molecular weight of 1400, hyperbrominated DGEBA with a relative molecular weight of 2000, tris(dimethylaminomethyl)phenol, dioctyl phthalate and methyl hydrogen-containing silicone oil are weighed according to the mass ratio of 60:20:5:5:6:2:2. First, mix and stir hexanediol diglycidyl ether and highly brominated DGEBA with a relative molecular weight of 1400, then add triethylenetetramine curing agent, stir and react at 65°C for 2 hours; wait for the temperature to cool to room temperature, add and weigh Good tris(dimethylaminomethyl)phenol, dioctyl phthalate and methyl hydrogen-containing silicone oil continue to mix and stir.

Embodiment 3

[0029] Triethylenetetramine, hexanediol diglycidyl ether, high brominated DGEBA with a relative molecular weight of 1600, dimethylaminomethylphenol, dioctyl phthalate and methyl hydrogen-containing silicone oil are in a mass ratio of 70: 30:10:5:2:3 Weighing. First, mix and stir hexanediol diglycidyl ether and highly brominated DGEBA with a relative molecular weight of 1600, then add triethylenetetramine curing agent, stir and react at 45°C for 4 hours; wait for the temperature to cool to room temperature, add and weigh Good dimethylaminomethylphenol, dioctyl phthalate and methyl hydrogen silicone oil can be mixed and stirred.

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

PropertyMeasurementUnit
amine valueaaaaaaaaaa
viscosityaaaaaaaaaa
compressive strengthaaaaaaaaaa
Login to View More

Abstract

The invention relates to an underwater epoxy resin curing agent which is prepared from the following components: an amine curing agent, bifunctional glycidyl ether, highly brominated DGEBA, an active accelerant, a plasticizer and a water repellent agent. Ring-opening reaction is conducted on high-activity hydrogen atoms in an amine curing agent and epoxy groups in bifunctional glycidyl ether and highly brominated DGEBA to form a novel curing agent structure; and meanwhile, based on the accelerant, high reaction activity of the system is provided, the plasticizer improves the viscosity of the system and the mechanical property of the curing material, and the water repellent agent improves the underwater adhesion of the system, so that the problems of long curing time in water, poor adhesion and poor mechanical property of the current curing agent are effectively solved, and the weather resistance and environmental protection property of the curing agent are improved.

Description

technical field [0001] The invention relates to the field of polymer material synthesis and preparation, and furthermore, relates to an underwater epoxy resin curing agent and a preparation method thereof. Background technique [0002] Epoxy resin materials are generally composed of resin and curing agent. Because of their excellent bonding properties and outstanding mechanical properties, they have been widely used in structural repair and reinforcement projects. At present, most of the research on epoxy resin focuses on the modification of the curing agent, but most of the curing agent is still used in a dry environment, which is difficult to meet the engineering application requirements of the underwater environment; and the concrete structure that has been underwater for a long time is easy to It is damaged by water medium erosion and other factors, and the working environment is harsh. After the disease occurs, it needs to be repaired in time, otherwise it will seriousl...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
Patent Type & Authority Applications(China)
IPC IPC(8): C08G59/50C08G59/22C08G59/30
CPCC08G59/5006C08G59/5033C08G59/226C08G59/308
Inventor 裴须强朱玉雪宋作宝尹润平李婷力乙鹏张帅隗天骄
Owner CNBM ZHONGYAN TECH
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Patsnap Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Patsnap Eureka Blog
Learn More
PatSnap group products

Browse by: Latest US Patents, China's latest patents, Technical Efficacy Thesaurus, Application Domain, Technology Topic, Popular Technical Reports.

© 2024 PatSnap. All rights reserved.Legal|Privacy policy|Modern Slavery Act Transparency Statement|Sitemap|About US| Contact US: help@patsnap.com