Tuberculosis serum marker screening method and application
A technology for serum markers and screening methods, which can be used in measurement devices, instruments, scientific instruments, etc., can solve the problems of non-specificity, protein omission, non-specific binding, etc., and achieve high specificity, high protein biological activity, and accuracy. high sex effect
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preparation example 1
[0045] Preparation Example 1 Constructing a Biomimetic Affinity Ligand Library
[0046] The biomimetic affinity ligand synthesis process is similar to the content of our previously published patent: "Antibody Affinity Purification Material and Its Application, 2014.11.19, China, CN104148018A".
[0047] The biomimetic affinity small molecule structures constructed this time for the specific adsorption of human serum antibodies include but are not limited to the following 19 types: L-theanine; aminopyrine; 3-aminophenol; 4-amino-1 naphthol hydrochloride ;4-2aminoethylbenzenesulfonamide;1-aminoanthraquinone;hexylamine;2,6-diaminoanthraquinone;2,6-diaminopyridine;2-phenylacetamide;adenine;hydroxysuccinyl imine; 2,4,6-triaminopyrimidine; diphenylamine; dodecylamine; diethylamine hydrochloride; dibenzylamine; dodecylamine; N-acetyl-L-methionine.
[0048] Take the bionic affinity medium A5-87 (5:4-2aminoethylbenzenesulfonamide, 87:ethylenediamine) to separate and purify the mixed se...
preparation example 2
[0050] Preparation example 2 sample pretreatment:
[0051] Experimental group: From 20 tuberculosis patient serum samples, take 100 μL per person, and obtain a total of 2 mL serum samples, centrifuge and mix at 2000 rpm, discard the precipitate, and dilute the serum 8 times with 0.005-0.5 mol of PBS buffer as it is;
[0052] Control group: take 20 healthy human serum samples, and the processing method is the same as that of the above-mentioned experimental group.
[0053] Equilibration of the bionic affinity chromatography column: wash the bionic affinity separation matrix gravity column with 10mL 0.1M acetic acid, 10mL double distilled water, 10mL 0.1M NaOH, and 10mL double distilled water in sequence, and finally wash the bionic affinity separation matrix gravity column with 10mL PBS (10mM, pH 7.4) Equilibrate all columns separately.
[0054] Biomimetic affinity chromatography of serum samples after pretreatment: take 5 mL diluted serum sample solutions of the experimental...
Embodiment 1
[0059] Such as figure 2 The process flow of the present invention is shown. The prepared Mycobacterium tuberculosis culture filtrate or cytoplasmic protein of Mycobacterium tuberculosis cells were subjected to chromatography with the bionic affinity chromatography column of the experimental group and the bionic affinity chromatography column of the control group respectively. Among them, the bionic affinity chromatography column in the experimental group and the bionic affinity chromatography column in the control group were chromatographically made of A5-87 material.
[0060] Liquid Chromatography-Mass Spectrometry Analysis of Eluted Components:
[0061] Collect all the eluted control groups and experimental histone components adsorbed on the bionic affinity chromatographic column A5-87 by the bionic-immunoaffinity method; and wash all the eluted components with 25mM NH 4 HCO 3 Replace buffer system. Then all samples were hydrolyzed with Trypsin, and the hydrolyzed polyp...
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