Aging-resistant EVA film adhesive for solar cell package and method for preparing same
A solar cell and anti-aging technology, which is applied in the direction of chemical instruments and methods, applications, circuits, etc., can solve the problems of insufficient adhesion, poor weather resistance of the film, and influence on light transmittance, etc., to achieve weather aging resistance Good performance, high production efficiency, and good light transmittance
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Embodiment 1
[0024] In terms of parts by mass, 0.25 parts of tackifier γ-aminopropyltriethoxysilane and 1.25 parts of 2,5-dimethyl-2,5-bis(tert-butylperoxy)hexane were used as Add the joint curing agent to 100 parts of EVA pellets (ethylene-vinyl acetate copolymer) with a VA content of 33% and mix evenly; then add 0.2 parts of β-(4-hydroxy-3,5 di-tert-butylphenyl) N-octadecanyl propionate is used as an antioxidant, 0.1 part of UV light stabilizer bis(2,2,6,6-tetramethyl-4-piperidinyl) sebacate is added to the above mixture, and mixed well . Pour the mixture into an extruder for blending and extrusion, the temperature is controlled at 80°C, and the extruded product is cast, cooled, drawn, and coiled to obtain an EVA film B-1 with a thickness of 0.5mm. The cross-linked EVA film was subjected to thermo-oxidative aging test and ultraviolet light aging test. The condition of the former is 100℃, 720h; the condition of the latter is UVB 313 ultraviolet lamp, the radiation energy is 0.63W / m 2 / ...
Embodiment 2
[0026] Add 0.40 parts of tackifier γ-aminopropyltriethoxysilane and 1.50 parts of crosslinking curing agent 2,5-dimethyl-2,5-bis(tert-butylperoxy)hexane to 100 parts VA content is mixed uniformly in the EVA pellet of 33%; Then 0.2 part of antioxidant tris (2,4-di-tert-butylphenyl) phosphite, 0.10 part of ultraviolet light stabilizer bis(2,2,6 , 6-tetramethyl-4-piperidinyl) sebacate and 0.05 parts of bis(1-octyloxy-2,2,6,6-tetramethyl-4-piperidinyl) sebacate were added above mixture, and mix well. Pour the mixture into an extruder for blending and extrusion, the temperature is controlled at 85°C, and the extruded product is cast, cooled, drawn, and coiled to obtain an EVA film B-2 with a thickness of 0.5mm. The cross-linked EVA film was subjected to thermo-oxidative aging test and UV aging test. The condition of the former was 100°C, 720h; the condition of the latter was UVB 313 ultraviolet lamp, and the radiation energy was 0.63W / m 2 / nm; exposure conditions, first irradiate...
Embodiment 3
[0028] Add 0.25 parts of tackifier γ-aminopropyltriethoxysilane and 1.00 parts of crosslinking curing agent 2,5-dimethyl-2,5-bis(tert-butylperoxy)hexane to 100 parts VA content is mixed uniformly in the EVA pellet of 33%; Then 0.2 part of antioxidant tris (2,4-di-tert-butylphenyl) phosphite, 0.2 part of ultraviolet absorber 2-hydroxyl-4-normal Octyloxybenzophenone and 0.1 part of UV light stabilizer bis(2,2,6,6-tetramethyl-4-piperidinyl) sebacate were added to the above mixture and mixed evenly. Pour the mixture into an extruder for blending and extrusion, the temperature is controlled at 83°C, and the extruded product is cast, cooled, drawn, and coiled to obtain an EVA film B-3 with a thickness of 0.5mm. The cross-linked EVA film was subjected to thermo-oxidative aging test and ultraviolet light aging test. The condition of the former is 100℃, 720h; the condition of the latter is UVB 313 ultraviolet lamp, the radiation energy is 0.63W / m 2 / nm; exposure conditions, first irr...
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