The invention discloses an air mark inhibitor for two-acid chemical polishing of a sand blasting surface aluminum alloy and a preparation method of the air mark inhibitor, and belongs to the technical field of chemical treatment of surfaces of aluminum alloy workpieces. The air mark inhibitor is prepared from 2-3wt.% of molybdate, 5-10wt.% of a corrosion inhibitor, 10-15wt.% of a surfactant, 10-15wt.% of water and the balance phosphoric acid, wherein the corrosion inhibitor is formed by mixing a hydroxyazo sulfonic acid substance, alanine and allyl thiourea. When a polishing solution containing the inhibitor is used for polishing a sand blasting surface aluminum alloy workpiece with holes, generation of air marks can be remarkably inhibited, and brightness unevenness caused by the air marks is reduced; and meanwhile, the polishing time can be effectively shortened, so that the surface marks and material surface exposure caused by long polishing time are reduced. The inhibitor can remarkably improve the yield and the production efficiency, reduces the production cost, is suitable for two-acid chemical polishing of 3C products with holes such as notebook computer shells, i PAD shells and mobile phone shells, and is particularly suitable for continuous production of an automatic line.