Cation type aqueous full fluorine polyurethane textile finishing agent and preparing method thereof
A cationic polyurethane technology, applied in textiles, papermaking, fiber treatment, etc., can solve the problems of poor product stability, poor fabric washability, poor fiber bonding, etc., achieve good stability, good washability, reduce pollution and damage effect
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Embodiment 1
[0032] Embodiment 1, a kind of cationic water-based perfluoropolyurethane textile finishing agent is prepared by the following method, and the preparation method comprises the following steps in turn:
[0033] Step 1: Preparation of polyurethane prepolymer: put 90g of hexamethylene diisocyanate (HDI), 33g of polypropylene glycol (molecular weight 2000, dried) and 5g of triethanolamine into the reactor in turn, and after passing through nitrogen to remove oxygen, stir , add 10 g of acetone solvent, and react at a constant temperature of 60° C. for 2 hours to form a polyurethane prepolymer.
[0034] Step 2: Preparation of perfluoroalkyl-terminated polyurethane: heat up the polyurethane prepolymer to 70°C, add 150g of perfluoroalkyl ethyl butanol for capping reaction, and add 0.4g of dibutyltin dilaurate catalyst, and react for 3 hours , forming a perfluoroalkyl-terminated polyurethane.
[0035]Step 3: Cool down to 50°C, add 4.5g dimethyl carbonate to ionize, and the reaction ti...
Embodiment 2
[0036] Embodiment 2, a kind of cationic water-based perfluoropolyurethane textile finishing agent is prepared by the following method, and the preparation method comprises the following steps in turn:
[0037] Step 1: Prepare polyurethane prepolymer: 120g isophorone diisocyanate (IPDI), 40g polytetrahydrofuran ether glycol (molecular weight 2000, dried) and 8gN-isopropyldiethanolamine are dropped into reactor successively, pass After entering nitrogen to remove oxygen, stir, add 10 g of butanone solvent, and react for 3 hours at a constant temperature of 65° C. to form a polyurethane prepolymer.
[0038] Step 2: Preparation of perfluoroalkyl-terminated polyurethane: heat up the polyurethane prepolymer to 75°C, add 170g of perfluoroalkyl ethyl hexanol for capping reaction, and add 0.4g of stannous octoate catalyst, react for 2.5 hours to form Perfluoroalkyl terminated polyurethane.
[0039] Step 3: Cool down to 45°C, add 6.5g dimethyl succinate to ionize, and the reaction time...
Embodiment 3
[0040] Embodiment 3, a kind of cationic water-based perfluoropolyurethane textile finishing agent is prepared by the following method, and the preparation method comprises the following steps in turn:
[0041] Step 1: Prepare polyurethane prepolymer: put 133g diphenylmethane diisocyanate (MDI), 65g polycaprolactone (molecular weight 4000, dried) and 6g N-methyldiethanolamine into the reactor successively, and feed nitrogen After deoxygenation, stir, add 15 g of tetrahydrofuran solvent, and react at a constant temperature of 70° C. for 5 hours to form a polyurethane prepolymer.
[0042] Step 2: Preparation of perfluoroalkyl-terminated polyurethane: heat up the polyurethane prepolymer to 75° C., add 216 g of perfluoroalkyl ethyl octanol for capping reaction, and add 0.5 g of zinc naphthenate catalyst, and react for 3.5 hours. Forms perfluoroalkyl-terminated polyurethanes.
[0043] Step 3: Cool down to 55°C, add 6.5g dimethyl malonate to ionize, and the reaction time is 1.5 hour...
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