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Composite additive for sintering iron ore powder and method of manufacturing the same

A composite additive and iron ore powder technology, which is applied in the field of metallurgical iron ore powder sintering, can solve problems such as the life of the blast furnace lining and the adverse effects of technical and economic indicators, and achieve the effects of reducing solid fuel consumption, increasing utilization coefficient, and reducing emissions

Inactive Publication Date: 2009-08-19
WUHAN NEW ORIENTAL METALLURGICAL MATERIALS
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

According to the industrial tests conducted by some domestic sintering plants, these sintering additives have certain effects in increasing the strength and output of sintering ore and reducing energy consumption, but there are still some unresolved problems, such as: the chemical composition of some additives is: oxidizing agent Sodium nitrate (NaNO 3 ), potassium permanganate (KMnO 4 ), potassium nitrate (KNO 3 ), etc.; catalysts include sodium chloride (NaCl), potassium chloride (KCl), sodium carbonate (NaCO 3 ), etc.; zinc oxide (ZnO), sodium borate (NaB 4 o 7 10H 2 O), etc.; binders include bentonite, etc. Most of these chemical compositions contain K, Na, Zn, Si, Al and other elements that are harmful to blast furnace smelting, and even contain substances that will have adverse effects on the environment. The ore is brought into the blast furnace and enriched in a cycle in the furnace, which has a great adverse effect on the life of the blast furnace lining and technical and economic indicators

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0024] A composite additive for iron ore powder sintering and a preparation method thereof. With 30-40wt% of combustion aid, 17-25wt% of oxygen-enhancing agent, 7-10wt% of strengthening agent, 14-20wt% of catalyst, 5-7wt% of coarse rice husk, 8-10wt% of calcium fluoride , 2-3wt% SHN pellet binder and 6-10wt% boric anhydride are used as raw materials, and the above-mentioned raw materials are mixed and stirred evenly.

[0025] In this embodiment: the combustion aid is either fine rice bran, or rubber powder, or a mixture of fine rice bran and rubber powder, with a particle size of 0-1mm; the oxygen enhancer is either ammonium nitrate, guanidine nitrate, or ammonium nitrate Mixture with guanidine nitrate, particle size ≤ 60 mesh; strengthening agent is a mixture of graphite and cerium oxide, particle size < 100 mesh, of which: graphite is 50-70wt%, cerium oxide is 30-50wt%; catalyst is manganese dioxide and di Mixture of ferrocene, particle size <100 mesh, wherein: manganese di...

Embodiment 2

[0030] A composite additive for iron ore powder sintering and a preparation method thereof. With 40-50wt% of combustion aid, 15-20wt% of oxygen-enhancing agent, 3-7wt% of strengthening agent, 10-16wt% of catalyst, 7-10wt% of coarse rice husk, 5-8wt% of calcium fluoride , 3-5wt% SHN pellet binder and 5-8wt% boric anhydride are used as raw materials, and the above-mentioned raw materials are mixed and stirred evenly.

[0031] All the other are with embodiment 1.

[0032]The composite additive prepared in this example is used for iron concentrate sintering, and the test results are shown in Table 2.

[0033] Table 2

[0034]

Amount added (%)

in the mix

-2mm particle size

Fraction(%) V 垂

mm / min

Yield(%)

Drum index (%)

Coal Blending Amount (%)

Sinter

Iron grade (%)

0 56.6 14.43 47.79 68.62 6.2 56.10 0.3 51.32 16.14 58.62 69.99 5.8 56.72 0.4 42.39 18.95 64.62 73.11...

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PUM

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Abstract

The invention relates to a compound additive for sintering iron ore powder and a preparation method thereof, and provides the following technical scheme: the compound additive is prepared by evenly stirring the following raw materials: 30wt% to 50 wt% of combustion-supporting agent, 15wt% to 25wt% of oxygen-increasing agent, 3wt% to 10wt% of strengthener, 10wt% to 20wt% of catalytic agent, 5wt% to 10wt% of coarse rice hull, 5wt% to 10wt% of calcium fluoride, 2wt% to 5wt% of SHN pellet binder and 5wt% to 10wt% of boric anhydride. The invention has the characteristics of simple preparation process and low cost; and by applying the prepared compound additive in sintering the iron ore powder, the vertical sintering speed can be increased by more than 12%, the production yield can be increased by more than 4%, the tumbler index can be increased by more than 5%, the sintering iron grade can be improved by 1 to 1.5, the fuel consumption can be reduced by more than 10%, the emission of SO2 can further be reduced and the compound additive is free from materials causing damage on blast furnace production, such as K, Na and other elements, therefore, the invention can improve the air permeability of sintering beds, increasing the combustion speed and the reaction speed of the mineralizing process and improving the yield and the quality of the sintering ore.

Description

technical field [0001] The invention belongs to the technical field of metallurgical iron ore powder sintering. In particular, it relates to a composite additive for iron ore powder sintering and a preparation method thereof. Background technique [0002] Iron ore powder sintering is a mineralization process involving complex physical and chemical reactions, including solid phase reaction and new phase formation at low temperature, binder phase and liquid phase formation at high temperature, and Condensation, recrystallization and phase change processes formed during cooling. Therefore, there are many factors affecting sintering mineralization and consolidation, such as mineral type, ingredient combination, raw material particle size, mixture moisture, alkalinity, fuel addition amount, ignition temperature, sintering negative pressure, material layer height and cooling method, etc. [0003] With the rapid development of the iron and steel industry, resources and energy are...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C22B1/16
Inventor 蒋春华彭志坚郑银珠
Owner WUHAN NEW ORIENTAL METALLURGICAL MATERIALS
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