Method for preparing bi-(sulfonyl fluoride) imine and (fluorinated alkyl sulfonyl fluorine sulfonyl) imine alkali metal salt

A technology of alkali metal salt and sulfonamide, applied in the field of fluorine chemical synthesis, can solve the problems of difficult purification of the product, pollute the environment, complicated operation, etc., and achieve the effects of avoiding product agglomeration, high yield and purity, and easy operation.
CN101747242BActive Publication Date: 2013-06-19武汉市瑞华新能源科技有限公司

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
武汉市瑞华新能源科技有限公司
Publication Date
2013-06-19

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Abstract

The invention discloses a method for preparing bi-(sulfonyl fluoride) imine and (fluorinated alkyl sulfonyl fluorine sulfonyl) imine alkali metal salt. The method comprises the following steps of: reacting sulfamide and thionyl chloride and chlorosulfonic acid to prepare bi-(sulfonyl chlorine) imine and (fluorinated alkyl sulfonyl chlorine sulfonyl) imine, reacting with antimony trifluoride and potassium carbonate (rubidium or caesium) to obtain corresponding high-purity bi-(sulfonyl fluoride) imine potassium (rubidium or caesium) salt or (fluorinated alkyl sulfonyl fluorine sulfonyl) imine potassium (rubidium or caesium) salt, performing double decomposition exchange reaction using the potassium (rubidium or caesium) salt with the lithium perchlorate (or sodium) or lithium tetrafluoroborate (or sodium) in the aprotic polar solvent to obtain corresponding lithium (or sodium) salt with high purity. The method in the invention has the characteristics of simple operating steps, easy separation and extraction of output, high purity and yield, no environmental pollution, and the like, and is suitable for mass industrial production.
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Description

technical field

[0001] The invention belongs to the chemical synthesis of fluorine, and relates to a preparation method of an alkali metal salt of a fluorine-containing imine, in particular to a bis(fluorosulfonyl)imide (H[N(SO 2 f) 2 ]) and (perfluoroalkylsulfonylfluorosulfonyl)imine (H[R f SO 2 NSO 2 F], R f =C m f 2m+1 , m=1-8) alkali metal salt (M[N(SO 2 f) 2 ], M[R f SO 2 NSO 2 F)]; Preparation of M = Li, Na, K, Rb, Cs). Background technique

[0002] Bis(fluorosulfonyl)imide (H[N(SO 2 f) 2 ], hereinafter referred to as H[FSI]) and (perfluoroalkylsulfonylfluorosulfonyl)imine (H[R f SO 2 NSO 2 F)], R f =C m f 2m+1 , m=1-8; hereinafter referred to as H[R f FSI]) alkali metal salts, especially lithium salts, are important fluorine-containing organic ion compounds, which are used in high-performance non-aqueous electrolyte materials for clean energy devices such as secondary lithium batteries, supercapacitors, and aluminum electrolytic capacitors, as well...

Claims

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