Unlock instant, AI-driven research and patent intelligence for your innovation.

Preparation method of porous carbon cathode material and primary lithium battery using porous carbon cathode material

A cathode material and porous carbon technology, which is applied in the electrodes of primary batteries, electrode manufacturing, battery electrodes, etc., can solve the problems of poor consistency of battery products, difficult to control the amount of alcohol volatilization, and unsuitable for large-scale production. Agglomerated and clumped, non-hazardous, easy-to-control effects

Inactive Publication Date: 2010-08-11
EVE ENERGY CO LTD
View PDF1 Cites 18 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Since alcohol is a volatile and flammable liquid, it is difficult to control the volatilization of alcohol during the mixing process, and the risk in the production process is high, and this process is not suitable for large-scale production, and the labor intensity of workers is high. The consistency of the obtained battery product is not good

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Preparation method of porous carbon cathode material and primary lithium battery using porous carbon cathode material
  • Preparation method of porous carbon cathode material and primary lithium battery using porous carbon cathode material
  • Preparation method of porous carbon cathode material and primary lithium battery using porous carbon cathode material

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0024] For comparison, use the existing method to prepare a kind of porous carbon cathode material for lithium primary battery, select the water emulsion of acetylene black, 60% polytetrafluoroethylene and alcohol, according to acetylene black: polytetrafluoroethylene: alcohol mass ratio 100:10 : 300 mixed in a blender, then extruded into a carbon bag, dried at 90°C for 10 hours to remove alcohol, then treated at 250-260°C for 20 minutes, and finally heated at 180±5°C, Vacuum drying for 15±2h under the condition of vacuum degree ≤-0.1MPa to obtain a thoroughly dried porous carbon cathode material A, which is used as a reference material prepared by the current technology.

[0025]The method of the invention is used to prepare a porous carbon cathode material for lithium primary batteries, which is prepared by water beating, drying and dehydration, drying for further dehydration, high-temperature foaming and vacuum drying. Among the raw materials, the carbon black is selected f...

Embodiment 2

[0028] A porous carbon cathode material for a lithium primary battery is prepared, which is prepared by ultrasonic water beating, dehydration by pressure filtration, drying for further dehydration, high-temperature foaming, and vacuum drying. Among the raw materials, the carbon black is selected from acetylene black, the binder is selected from 60% polytetrafluoroethylene water emulsion, and the functional additive is selected from copper powder. In this embodiment, the mass ratio of 300:20:3500:42 is preferably weighed to mix acetylene black, copper powder, water, and polytetrafluoroethylene emulsion, and mix and disperse at a high speed with a dynamic ultrasonic disperser, so that each component is fully mixed and evenly Afterwards, a slurry was obtained. The resulting slurry is filtered and dehydrated by a plate-and-frame filter press, crushed and granulated, dried at 150±10°C for 8 hours for further dehydration, then foamed at 280-290°C for 15 minutes, and finally Vacuum ...

Embodiment 3

[0030] A porous carbon cathode material for a lithium primary battery is prepared, which is prepared by water beating, drying and dehydration, high-temperature foaming, and vacuum drying. Among the raw materials, the carbon black is a mixture of furnace black and conductive carbon black, the binder is a mixture of polytetrafluoroethylene aqueous emulsion and polyacrylic acid resin aqueous solution, and the functional additive is copper phthalocyanine. The present embodiment preferably weighs carbon black, copper phthalocyanine, water and binding agent in a mass ratio of 100:3:3000:20, wherein carbon black is a mixture of furnace black and conductive carbon black with a mass ratio of 80:20 , the binder is a mixture of polytetrafluoroethylene aqueous emulsion and polyacrylic acid resin aqueous solution with a mass ratio of 60:40. After mixing these substances together, disperse at high speed with a high-shear dispersing emulsifier, so that each component is fully mixed and unifo...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

No PUM Login to View More

Abstract

The invention discloses a preparation method of a porous carbon cathode material and a primary lithium battery using the porous carbon cathode material. The porous carbon cathode material comprises the components such as carbon black, additives and binder. The preparation method comprises the following steps: mixing the raw materials with water, pulping, then dewatering for drying, foaming for pore-forming, and performing vacuum drying and other processes. The material is used as cathode carrier, liquid SOCl2, SO2Cl2, SO2 or other active material is used as cathode active material and metal lithium is used as anode active material to prepare the high-energy-density primary lithium battery. The preparation process of the material uses water as solvent without using ethanol, isopropanol or other flammable organic solvents, thus increasing the safety, improve the working environment, facilitating the mechanized and scale manufacture, reducing the labor intensity and significantly improving the consistency and stability of the electrical characteristics of batteries.

Description

technical field [0001] The invention relates to a cathode material of a lithium primary battery, in particular to a preparation method of a lithium battery cathode material of a liquid cathode active material and a lithium primary battery using the material. Background technique [0002] A lithium battery with metallic lithium as the anode and a liquid active material as the cathode, such as lithium / thionyl chloride (Li / SOCl 2 ) battery, lithium / sulfuryl chloride (Li / SO 2 Cl 2 ) and lithium / sulfur dioxide (Li / SO 2 ) battery, etc., is the primary battery with the highest specific energy in the battery system currently used in the world. The liquid active material in the battery needs to be stored and reacted in the porous carbon cathode, that is to say, the porous carbon cathode is not only the storage of the liquid active material The warehouse is also the place where the electrochemical reaction of the liquid active material occurs, and it also plays the role of catalysi...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
IPC IPC(8): H01M4/66H01M6/14
CPCH01M4/0471H01M6/14H01M4/08H01M4/0416H01M4/663H01M2300/002
Inventor 袁中直徐瑛刘金成祝媛
Owner EVE ENERGY CO LTD