Light diffusion agent mother material used for light diffusion film, preparation method and application thereof
A light-diffusing agent and light-diffusing technology, applied in application, optics, household appliances, etc., can solve the problems of inability to obtain light-diffusing performance light-diffusion film, poor operational flexibility, and low utilization rate of production equipment.
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Embodiment 1
[0053] The light-diffusing agent is directly mixed with the polyester chip as the raw material for the light-diffusing layer of the light-diffusing polyester film.
[0054] The ratio of the light diffusion layer of the film is: 78wt% of PET chips (intrinsic viscosity: 0.65dL / g), and 22wt% of polystyrene cross-linked microspheres (average particle diameter: 8.0μm). The raw material of the film substrate layer is also PET with an intrinsic viscosity of 0.65 dL / g. The polystyrene cross-linked microspheres and PET resin slices are fully mixed in a high-speed disperser according to the above ratio, and sent to the raw material bin 1 as a light diffusion layer. The substrate layer PET resin chips are sent into the raw material bin 2. The mixed material in the raw material bin 1 is sent to the twin-screw extruder for melt extrusion, and the polyester resin in the raw material bin 2 is sent to the single-screw extruder for melt extrusion. The temperature settings of each zone of the...
Embodiment 2
[0060] The light diffusing agent is firstly prepared into a light diffusing agent masterbatch, and then the light diffusing agent masterbatch is mixed with polyester chips as the raw material of the light diffusing layer of the film.
[0061] The formula of the light diffusing agent masterbatch is: 100 parts by weight of powdery PET (intrinsic viscosity: 0.56 dL / g), and 80 parts by weight of polystyrene crosslinked microspheres (average particle diameter: 8.0 μm). Dry the powdered PET at 120°C for 10 hours and mix it with polystyrene cross-linked microspheres in a high-speed disperser, then put the pre-dispersed mixture into a twin-screw extruder to melt and extrude, and the extrudate is cooled and granulated to obtain Light diffusing agent masterbatch (masterbatch-1).
[0062] The ratio of the light-diffusing layer of the polyester film is: 50 parts by weight of PET chips (intrinsic viscosity: 0.65 dL / g), and 50 parts by weight of the light-diffusing agent masterbatch (master...
Embodiment 3
[0064] Add 132.8 parts by weight of terephthalic acid, 33.2 parts by weight of isophthalic acid, 93 parts by weight of ethylene glycol and 52 parts by weight of neopentyl glycol into the reactor, start heating and stirring, and add 0.035 parts by weight of antimony trioxide As a catalyst, at 240°C, 3.5kg / cm 2 The esterification reaction under pressure was carried out for 1 hour. Return the reactor to normal pressure, add 0.024 parts by weight of trimethyl phosphate and 0.01 parts by weight of sodium acetate, and then carry out polycondensation reaction at 250°C under reduced pressure (0.5-10mmHg) for 3 hours to obtain a number-average molecular weight of 20500, A copolymerized polyester resin with a softening point of 73°C.
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