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Light diffusion agent mother material used for light diffusion film, preparation method and application thereof

A light-diffusing agent and light-diffusing technology, applied in application, optics, household appliances, etc., can solve the problems of inability to obtain light-diffusing performance light-diffusion film, poor operational flexibility, and low utilization rate of production equipment.

Active Publication Date: 2013-10-30
JIANGSU POLYTECHNIC UNIVERSITY +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, this method uses thermoplastic polystyrene resin to form a tiny dispersed phase in polyester as light diffusing agent particles. The size and shape of the dispersed phase particles are strongly dependent on extrusion conditions and stretching conditions, so it is impossible to obtain stable light diffusion. performance light diffusing film
[0005] When using a multi-layer co-extrusion method to prepare a light-diffusing film, if the light-diffusing agent and polyester are directly mixed as the raw material for the light-diffusing layer, it is difficult to ensure that the light-diffusing agent particles in the light-diffusing layer are uniformly dispersed after co-extrusion. It affects the light transmittance of the light-diffusing film; on the other hand, it is necessary to set up a large-volume raw material resin silo on the production line, and when producing different grades of light-diffusing film, it is necessary to set up multiple raw material resin silos
Therefore, the utilization rate of production equipment is low and the operation flexibility is poor

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0053] The light-diffusing agent is directly mixed with the polyester chip as the raw material for the light-diffusing layer of the light-diffusing polyester film.

[0054] The ratio of the light diffusion layer of the film is: 78wt% of PET chips (intrinsic viscosity: 0.65dL / g), and 22wt% of polystyrene cross-linked microspheres (average particle diameter: 8.0μm). The raw material of the film substrate layer is also PET with an intrinsic viscosity of 0.65 dL / g. The polystyrene cross-linked microspheres and PET resin slices are fully mixed in a high-speed disperser according to the above ratio, and sent to the raw material bin 1 as a light diffusion layer. The substrate layer PET resin chips are sent into the raw material bin 2. The mixed material in the raw material bin 1 is sent to the twin-screw extruder for melt extrusion, and the polyester resin in the raw material bin 2 is sent to the single-screw extruder for melt extrusion. The temperature settings of each zone of the...

Embodiment 2

[0060] The light diffusing agent is firstly prepared into a light diffusing agent masterbatch, and then the light diffusing agent masterbatch is mixed with polyester chips as the raw material of the light diffusing layer of the film.

[0061] The formula of the light diffusing agent masterbatch is: 100 parts by weight of powdery PET (intrinsic viscosity: 0.56 dL / g), and 80 parts by weight of polystyrene crosslinked microspheres (average particle diameter: 8.0 μm). Dry the powdered PET at 120°C for 10 hours and mix it with polystyrene cross-linked microspheres in a high-speed disperser, then put the pre-dispersed mixture into a twin-screw extruder to melt and extrude, and the extrudate is cooled and granulated to obtain Light diffusing agent masterbatch (masterbatch-1).

[0062] The ratio of the light-diffusing layer of the polyester film is: 50 parts by weight of PET chips (intrinsic viscosity: 0.65 dL / g), and 50 parts by weight of the light-diffusing agent masterbatch (master...

Embodiment 3

[0064] Add 132.8 parts by weight of terephthalic acid, 33.2 parts by weight of isophthalic acid, 93 parts by weight of ethylene glycol and 52 parts by weight of neopentyl glycol into the reactor, start heating and stirring, and add 0.035 parts by weight of antimony trioxide As a catalyst, at 240°C, 3.5kg / cm 2 The esterification reaction under pressure was carried out for 1 hour. Return the reactor to normal pressure, add 0.024 parts by weight of trimethyl phosphate and 0.01 parts by weight of sodium acetate, and then carry out polycondensation reaction at 250°C under reduced pressure (0.5-10mmHg) for 3 hours to obtain a number-average molecular weight of 20500, A copolymerized polyester resin with a softening point of 73°C.

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Abstract

The invention provides a light diffusion agent mother material used for a light diffusion film, a preparation method and application thereof. A light diffusion agent is compounded from organic polymer cross linking microspheres with different refractive indexes and grain diameters, the light diffusion agent mother material is prepared from 100 weight parts of polyester resin, 60 to 100 weight parts of compounded light diffusion agents and 1 to 7 weight parts of diffusion resin through high-speed diffusion and fused extrusion grain cutting by a double-screw extruding machine. The invention also provides a high-transparency heat-resistance light diffusion film prepared by using the light diffusion agent mother materials as additives. The light diffusion layer of the light diffusion film is formed by mixing the light diffusion agent mother materials and polyester slices according to the mixture ratio of 40 to 60 weight percent of polyester slices and 40 to 60 weight percent of the light diffusion agent mother materials. The light diffusion film prepared by the invention has high light transmission rate, high mist degree, excellent heat resistance performance and excellent dimension stability, and is particularly suitable for being used as the light diffusion film in a back light module of a large-dimension liquid crystal display.

Description

technical field [0001] The present invention relates to a light-diffusing agent masterbatch for producing light-diffusing films by a multilayer co-extrusion method and a preparation method thereof, and also relates to a light-diffusing film prepared from the masterbatch, and the light-diffusing film has a balanced light transmittance and light diffusion properties while maintaining excellent heat resistance and dimensional stability. It belongs to the technical field of functional polymer material processing. Background technique [0002] The light diffusion film is an important part of the backlight module of the liquid crystal display (LCD). Its function is to atomize the point light source or line light source emitted from the front of the light guide plate into a uniform surface through the light scattering effect of the light diffusion agent particles dispersed on the surface of the film. Light source, improve the luminance of the LCD panel and control the uniformity o...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08L67/02C08L25/06C08L33/12B29D7/01B29C47/92B29C51/04G02F1/13357B29C48/40B29C48/92
CPCB29C48/92B29C2948/92704B29C48/04B29C48/40B29C2948/92809B29C2948/92885B29C2948/92895
Inventor 朱梦冰俞强马慧敏刘勤学周波丁永红秦志风
Owner JIANGSU POLYTECHNIC UNIVERSITY
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