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Tebuconazole-algae slow-release microcapsule fungicide and preparation method thereof

A tebuconazole, sustained-release technology, applied in the field of tebuconazole-algae sustained-release microcapsule fungicide and its preparation, can solve the adverse effects of the surrounding environment, the difficulty of exerting super-efficient effects, and the increase in dosage and frequency and other problems, to achieve the effect of reducing the dosage, low cost and improving the utilization rate

Inactive Publication Date: 2011-12-21
SHANGHAI NORMAL UNIVERSITY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] At present, existing tebuconazole pesticide formulation is 43% suspension concentrate, 25% wettable powder and 80% water dispersible granule (Chinese patent CN101156578A), tebuconazole suspension seed coating (Chinese patent CN101133735A), wettable powder ( Chinese patent CN101133737A), these dosage forms are easily affected by factors such as heat, air, rain, soil, microorganisms and other chemical substances during the application process, resulting in the decomposition and loss of pesticides, making it difficult to exert super-efficient effects, and the dosage and frequency Increase year by year, cost increase
Due to the fine particles, the powder is easy to drift, and it will have adverse effects on the user and the surrounding environment during use.

Method used

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  • Tebuconazole-algae slow-release microcapsule fungicide and preparation method thereof
  • Tebuconazole-algae slow-release microcapsule fungicide and preparation method thereof
  • Tebuconazole-algae slow-release microcapsule fungicide and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0037] a. Take the pretreated Microcystis powder and dry it at 50°C for 7 hours;

[0038] b. Dissolve 1 part of tebuconazole, 0.25 part of naphthalene acetic acid and 0.75 part of indolebutyric acid in a reactor filled with 6.25 parts of ethanol, and add 5 parts of dried algal powder, and place in a constant temperature air bath shaker for 25 Shaking and soaking at ℃ for 24 hours;

[0039] c, adding 0.5 part of carboxymethyl cellulose to the material obtained in step b;

[0040] d, 0.75 parts of sodium lignosulfonate and 1 part of sodium dodecyl sulfonate are dissolved in 25 parts of twice distilled water;

[0041] e. After mixing the substance of step c with the substance of step d, first use a high-shear emulsifier to stir at a speed of 12000rpm for 15 minutes, evaporate ethanol at 40°C, solidify into capsules, filter to remove water, and mix with 1 part of zinc sulfate Mix evenly to obtain the tebuconazole-algae sustained-release microcapsule fungicide.

[0042] The prep...

Embodiment 2

[0044] a. Take the pretreated Microcystis powder and dry it at 70°C for 4 hours;

[0045] b. Dissolve 1 part of tebuconazole, 0.4 part of naphthalene acetic acid and 0.1 part of indolebutyric acid in a reactor containing 6 parts of methanol, and add 5 parts of dried algae powder, and place in a constant temperature air bath shaker Shaking and soaking at 25°C for 24 hours;

[0046] c, adding 0.6 part of hydroxyethyl cellulose to the material obtained in step b;

[0047] d, 0.6 parts of polyvinyl alcohol and 1 part of sorbitan monolaurate are dissolved in 30 parts of twice distilled water;

[0048] e. After mixing the substance of step c with the substance of step d, first stir it with a high-shear emulsifier at a speed of 10000rpm for 15 minutes, steam methanol at 50°C, solidify into a capsule, filter to remove water, and mix with 1.4 parts of rare earth nitrate Mix evenly to obtain the tebuconazole-algae sustained-release microcapsule fungicide.

Embodiment 3

[0050] a. Take the pretreated Microcystis powder and dry it at 50°C for 6 hours;

[0051] b. Dissolve 1 part of tebuconazole, 0.6 part of naphthalene acetic acid, and 0.16 part of indole butyric acid in a reactor containing 14 parts of propanol, and add 6 parts of dried algae powder, and place in a constant temperature air bath shaker for 25 Shaking and soaking at ℃ for 24 hours;

[0052] c, 0.6 part of polyvinyl alcohol is added in the material gained in step b;

[0053] d, 0.8 parts of hydroxymethylcellulose and 1.6 parts of polypropylene glycol ethylene oxide ether are dissolved in 40 parts of double distilled water;

[0054] e. After mixing the substance of step c with the substance of step d, first stir it with a high-shear emulsifier at a speed of 10000rpm for 15 minutes, evaporate the propanol at 55°C, solidify into a capsule, filter to remove water, and mix with 1.2 parts of sulfuric acid Mix the ferrous iron evenly to obtain the tebuconazole-algae sustained-release ...

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Abstract

The invention discloses a tebuconazole-algae slow-release microcapsule fungicide and a preparation method thereof. The algae is used as a carrier, and the original drug tebuconazole and a plant growth regulator are adsorbed by its physical adsorption, and a degradable polymer is added. Surfactants and stabilizers are mixed with micro-fertilizers after being solidified into capsules to obtain the tebuconazole-algae sustained-release microcapsule bactericide of the present invention, the weight ratio of each component of the bactericide is: 1 part of tebuconazole; 5-50 parts of algal powder; 0.6-1 part of surfactant; 0.5-1 part of degradable polymer compound; 1-3 parts of stabilizer; 1-2 parts of micro-fertilizer; 0.5-1 part of plant growth regulator. The fungicide of the present invention can effectively control the release, prolong the effective period and reduce the dosage, so as to be less toxic; it adopts the combination of pesticide and micro-fertilizer, and exerts the dual effects of fertilizing the field and plant protection; moreover, the raw materials of the present invention are easy to obtain and low in cost , the process is simple, the environment is friendly, and is suitable for industrial scale production.

Description

technical field [0001] The invention belongs to the field of pesticide preparations, in particular to a tebuconazole-algae slow-release microcapsule fungicide and a preparation method thereof. Background technique [0002] Tebuconazole, English name Tebuconazole, structural formula is as follows: [0003] [0004] Its molecular formula is C 16 h 22 ClN 3 O, the molecular weight is 307.8. The pure product of tebuconazole is a colorless crystal with a melting point of 102.4°C to 104.7°C, a vapor pressure of 0.013mPa at 20°C, and a solubility of 20°C: water 3.2×10 -5 kg / L, dichloromethane>0.2kg / L, hexane<0.0001kg / L, isopropanol, toluene 0.05~0.1kg / L. Stability: Hydrolyzed DT at pH 4, 7 or 9 at 22°C 50 > 1 year. [0005] Tebuconazole is a triazole high-efficiency broad-spectrum systemic fungicide. It is an alcohol demethylation inhibitor, which can penetrate into plants and conduct in vivo. It has a wide antibacterial spectrum and low dosage. Tebuconazole inh...

Claims

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Application Information

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IPC IPC(8): C05G3/00A01N43/653A01N43/38A01N37/10A01N25/28A01P3/00A01P21/00
Inventor 任天瑞艾丽娟王全喜韩睿张晓敏温夏夏
Owner SHANGHAI NORMAL UNIVERSITY
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