Rare-earth uniformly-doped fiber perform core rod and preparation method thereof
An optical fiber preform and uniform doping technology, which is applied in the field of optical fiber manufacturing, can solve the problem of uneven doping of preforms, fluorine-doped cladding outer cladding technology and rare earth-doped optical fiber technology, which cannot meet the requirements of one-rod multi-fiber design and Optical fiber implementation technology requirements and other issues, to achieve the effect of flexible selection, easy control of concentration adjustment, and low background absorption loss
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Embodiment 1
[0026] Mandrel Example 1: The nanoporous SiO2 powder with a particle size of 10-200 nm is added to the chloride aqueous solution of rare earth and co-doped ions, and the ratio of the molar concentration of dopant ion Al3+ in the solution to the molar concentration of rare earth ion Yb3+ 5 to 6, then adjust the pH value of the solution to 10 to 11 with ammonia water, and stir continuously to form a suspension; then perform high-speed centrifugation to separate solid particles and liquid, then dry, dehydrate, and granulate to form ion-adsorbed SiO2 particles; The adsorbed SiO2 particles are formed by isostatic pressing, and then dehydrated and purified by Cl2; then in the atmosphere furnace, they are sintered and dense at high temperature, the sintering temperature is 1500-1600 °C, and the sintering time is 5-20 hours; processing and chemical cleaning to obtain a cylindrical rare earth doped silicon oxide core rod; finally, a thin layer of SiO2 without rare earth ion doping is sp...
Embodiment 2
[0027] Mandrel Example 2: The nanoporous SiO2 powder with a particle size of 10-200 nm is added to the chloride ethanol solution of rare earth and co-doped ions, and the solution contains the molar concentration of dopant ions Al3+ and the molar concentration of rare earth ions Yb3+ and Er3+ The ratio of the sum of the concentrations is 9-12, and then adjust the pH value of the solution to 7-9 with ammonia water, and stir continuously to form a suspension; then perform high-speed centrifugation to separate solid particles and liquid, and then dry, dehydrate, and granulate to form ion adsorption SiO2 particles of SiO2 particles; ion-adsorbed SiO2 particles are formed by isostatic pressing, followed by Cl2 dehydration and purification; then in the atmosphere furnace, high-temperature sintering is dense, the sintering temperature is 1200-1600 ° C, and the sintering time is 2-10 hours; Then, surface processing and chemical cleaning are carried out to obtain a cylindrical rare earth...
Embodiment 3
[0028] Mandrel Example 3: The nanoporous SiO2 powder with a particle size of 10 to 200 nm is added to the hydrogen phosphate aqueous solution of rare earth and co-doped ions, and the solution contains the sum of the molar concentrations of the dopant ions Al3+ and PO33- and the rare earth The ratio of the molar concentration of ions Er3+ is 25-30, adjust the pH value of the solution to 7-8, and stir continuously to form a suspension; then perform high-speed centrifugation to separate solid particles and liquid, then dry, dehydrate, and granulate to form ion-adsorbed SiO2 particles ; The ion-adsorbed SiO2 particles are formed by isostatic pressing, followed by Cl2 dehydration and purification; then in the atmosphere furnace, high-temperature sintering is dense, the sintering temperature is 1000-1400 ° C, and the sintering time is 1-8 hours; and then, Surface processing and chemical cleaning are carried out to obtain a cylindrical rare earth doped silicon oxide core rod; finally,...
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