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Hybrid coating equipment and manufacturing method for NdFeB rare earth permanent magnet device

A rare earth permanent magnet and mixed coating technology, which is applied in the manufacture of inductors/transformers/magnets, magnetic materials, electrical components, etc., can solve the problem of poor bonding between the film layer and the substrate, high energy consumption and pollution, and low efficiency of magnetron sputtering and other problems, to achieve the effect of improving magnetic energy product and coercive force, improving corrosion resistance, and reducing the amount of rare earth

Active Publication Date: 2016-10-05
SHENYANG CHINANORTH VACUUM TECH CO LTD
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  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] The existing technology uses evaporation coating, the bonding force between the film layer and the substrate is poor, and there are deficiencies in improving the corrosion resistance of rare earth permanent magnet devices; there are also existing technologies that use magnetron sputtering coating, due to the low efficiency of magnetron sputtering, It is not suitable for low-cost mass production, and some have not solved the card installation technology, which is not easy to install, and the production is troublesome; some existing technologies use multi-arc ion coating, because there are large particles in the multi-arc ion coating, it cannot reach rare earth permanent magnet devices Corrosion resistance requirements; In order to solve the shortcomings of multi-arc ion plating, some people in the prior art thought of using multi-arc ion plating and magnetron sputtering mixed coating, but none of them solved the problem of high efficiency, low cost, mass production technology , there are deficiencies in the equipment structure; especially the electroplating chemical treatment process of the rare earth permanent magnet device in the prior art, the energy consumption is high and there is pollution, requiring expensive water treatment equipment, improper treatment has a serious impact on the ecological environment, because the production process of the present invention The process is carried out in a vacuum, without using environmental pollutants, and will not pollute the ecological environment. At the same time, it also eliminates the influence of the "battery" effect on the reduction of magnetic properties in the electroplating process.

Method used

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  • Hybrid coating equipment and manufacturing method for NdFeB rare earth permanent magnet device
  • Hybrid coating equipment and manufacturing method for NdFeB rare earth permanent magnet device
  • Hybrid coating equipment and manufacturing method for NdFeB rare earth permanent magnet device

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Experimental program
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Effect test

Embodiment 1

[0047] Manufactured according to the following process:

[0048] 1. According to the components of A1, A2, A3, and A4 in Table 1, select 600Kg alloy for smelting. In the molten state, the alloy is cast on a rotating copper roll with water cooling to form alloy flakes, and then hydrogen crushed, and mixed after hydrogen crushing. After mixing, airflow milling is carried out, and then mixed with a mixer under the protection of nitrogen, and then sent to a nitrogen-protected magnetic field orientation press for molding. The oxygen content in the protective box is 150ppm, the orientation magnetic field intensity is 1.8T, and the mold cavity temperature is 2 ℃, the size of the magnetic block is 62×52×42mm, and the orientation direction is 42 size direction. After forming, it is packaged in a protective box, and then taken out for isostatic pressing with an isostatic pressure of 200MPa, and then sent to the sintering equipment for sintering and aging.

[0049] 2. After aging, perform mec...

Embodiment 2

[0059] Select the composition in Example 1 to make a neodymium iron boron rare earth permanent magnet device, and select the first layer of Dy-Al alloy, the second layer of Al+Al, and the third layer of Al for the temperature experiment. The results are listed in Table 4 , No. 1 is a comparative example without heating and no heat treatment during coating. Table 4 shows that the coating temperature and the heat treatment temperature after coating have an impact on the magnetic properties of the material, which significantly improves the coercivity of the magnet, that is The use temperature of the magnet is increased, and under the same use temperature, the amount of heavy rare earth can be reduced, and scarce resources are saved.

[0060] Table 4. The influence of coating temperature and heat treatment temperature on magnetic properties and corrosion resistance

[0061]

[0062] Note: 1. Corrosion resistance (PCT test)

[0063] Experimental conditions: sample 10X10X10mm, 2 standard ...

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Abstract

The invention discloses mixed film coating equipment for neodymium iron boron rare-earth permanent magnet components and a manufacturing method of the mixed film coating equipment. The film coating equipment comprises a vacuum chamber, cylinder rotating cathode magnetic control targets, plane cathode magnetic control targets, multi-arc ion targets, rotating stands and material baskets. In the working process, the rotating stands perform revolution in the vacuum chamber, and the two ends of each net-shaped material basket are installed on the corresponding rotating stand through rotary shafts and not only perform revolution along with the rotating stand, but also perform rotation. The cylinder rotating cathode magnetic control targets are installed in the rotating stands in the vacuum chamber, the plane magnetic control targets, the multi-arc ion targets, anode layer linear ion sources and a heating device are installed around the rotating stands in the vacuum chamber, and vacuum film coating is performed in a three-layer mode. The first layer is a magnetron sputtering coating layer, the thickness of the coating layer is 0.1 micrometer-5 micrometers, the second layer is a mixed coating layer of magnetron sputtering and multiple arcs, the thickness of the mixed coating layer is 1 micrometer-15 micrometers, the third layer is a magnetron sputtering coating layer, and the thickness of the coating layer is 0.1 micrometer-5 micrometers. Mixed film coating is adopted as the surface treatment process of the rare-earth permanent magnet components, so that the anti-corrosion capacity of the rare-earth permanent magnet components is improved, and meanwhile the magnetic performance of the rare-earth permanent magnet components is improved.

Description

Technical field [0001] The invention belongs to the field of permanent magnetic devices, and particularly relates to a hybrid coating equipment and a manufacturing method of a neodymium iron boron rare earth permanent magnetic device. Background technique [0002] NdFeB rare earth permanent magnet materials are more and more used for their excellent magnetic properties, and are widely used in medical MRI, computer hard disk drives, audio, mobile phones, etc.; with the requirements of energy saving and low carbon economy , Neodymium-iron-boron rare-earth permanent magnet materials have begun to be applied in automotive parts, household appliances, energy-saving and control motors, hybrid vehicles, wind power and other fields. [0003] The surface treatment processes of rare earth permanent magnet devices in the prior art mainly include electroplating Ni-Cu-Ni, electroplating Zn, electrophoresis, spraying, etc., and also use vacuum aluminum plating methods, such as Chinese patent ZL9...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): H01F1/057H01F41/02C22C33/02C22C38/00B22F9/08B22F3/16C23C14/22
Inventor 陈晓东孙宝玉
Owner SHENYANG CHINANORTH VACUUM TECH CO LTD
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