Modified bamboo fiber/polymer composite high-toughness concrete and preparation method thereof
A technology of bamboo fiber and high toughness, which is applied in the field of modified bamboo fiber/polymer composite high toughness concrete and its preparation, which can solve the problems affecting the overall safety and service life of the building, the concrete is prone to cracks, and the concrete is brittle. Microscopic stress-strain performance, low cost, and excellent mechanical properties
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[0072] The preparation method of polyurethane toughening emulsion comprises the following steps:
[0073] 1) Stir 30kg of polyether diol and 22.5kg of polypropylene glycol at 110°C for 1 h under vacuum conditions, then cool to room temperature;
[0074] 2) Add 17kg of toluene-2,4-diisocyanate, 21.5kg of 3-isocyanatomethylene-3,5,5-trimethylcyclohexylisocyanate and 0.25kg of dibutyltin dilaurate to the emulsion of step 1) During 1 hour, the temperature was slowly raised to 82°C while stirring, and then continued to stir at 82°C for 2 hours and then cooled to room temperature;
[0075] 3) Add 20kg of N,N-dimethylacetamide solution dissolved with 10.5kg of dimethylolbutyric acid into the emulsion in step 2) within 0.5 h, and stir within 1.5 h after the addition is complete Slowly raise the temperature to 85°C, and continue to stir at 85°C for 2.5 h, then cool to room temperature;
[0076] 4) Add 1.4kg of ethylene glycol to the emulsion in step 3), slowly raise the temperature t...
Embodiment 1
[0081] 1. The modification method of activated bamboo fiber comprises the following steps: at 23°C, 0.7kg of coupling agent is added to 90kg of water, stirred until it dissolves completely; at 20°C, 9kg of activated bamboo powder is added to In the aqueous solution containing the coupling agent, stir for 0.5 h, heat up to 50°C, stir for 8.5 h, filter and put the bamboo powder in an industrial centrifuge, centrifuge at 500 r / min for 10 min, then put the bamboo powder at 53°C Under vacuum drying 24 hours; Gained bamboo powder and 3.5kg maleic anhydride graft copolymer are packed in the high-speed mixer at 27 ℃, be warming up to 108 ℃ after 280 r / min mixes 2.5 h, again at 430 r / min After mixing at low speed for 7 minutes, put it into the cold mixing pot to cool, and discharge the material when the temperature drops to 45°C to obtain the primary mixture; put the primary mixture in a twin-screw extruder with a temperature of 165°C and a rotational speed of 55 r / min. Extrude after k...
Embodiment 2
[0119] 1. The modification method of activated bamboo fiber comprises the following steps: at 25°C, 1.0kg of coupling agent is added to 100kg of water, stirred until it dissolves completely; at 23°C, 10kg of activated bamboo powder is added to In the above-mentioned aqueous solution containing coupling agent, stir for 0.5 h, heat up to 51°C, stir for another 10 h, put the bamboo powder in an industrial centrifuge after filtration, centrifuge at 500 r / min for 10 min, then put the bamboo powder at 55°C Under vacuum drying 24 hours; Gained bamboo powder and 3.5kg maleic anhydride graft copolymer are packed in the high-speed mixer at 30 ℃, be warming up to 109 ℃ after mixing 3 h at 300 r / min, then at 450 r / min After mixing at low speed for 8 minutes, put it into the cold mixing pot to cool, and discharge the material when the temperature drops to 45°C to obtain the primary mixture; put the primary mixture in a twin-screw extrusion machine with a temperature of 170°C and a rotationa...
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