Expanded flexible well cementing grout and preparation method thereof

A technology of cementing slurry and toughness, applied in the direction of chemical instruments and methods, drilling compositions, etc., can solve the problems of difficult mixing, high price, poor cementing ability, etc., to improve the packing density and reduce transmission coefficient, the effect of prolonging the service life

Active Publication Date: 2015-02-25
BC P INC CHINA NAT PETROLEUM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] (1) The disadvantage of latex is that the environment is seriously polluted, the amount added is large, and the price is expensive. After adding latex, the degree of reduction of the elastic modulus of cement stone is difficult to meet the requirements of on-site application;
[0005] (2) Rubber powder with poor surface hydrophilicity such as waste tire rubber powder and silicone rubber powder has poor bonding ability to cement stone matrix, which affects the integrity of cement stone. Although some studies have proved that modification can be carried out to improve the bonding strength, the increase Reduced industrial production costs;
[0006] (3) The disadvantages of fiber are poor dispersion, difficult mixing, high price, poor bonding with cement stone matrix, and the elastic modulus of fiber cement stone alone is difficult to meet the requirements of on-site application

Method used

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  • Expanded flexible well cementing grout and preparation method thereof
  • Expanded flexible well cementing grout and preparation method thereof
  • Expanded flexible well cementing grout and preparation method thereof

Examples

Experimental program
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Effect test

Embodiment 1

[0031] This embodiment provides an expansive toughness cementing cement slurry, which comprises the following components in parts by weight: 100 parts by weight of cement, 6 parts by weight of a graded mixture of modified nitrile rubber powder, 20 parts by weight of slag powder, powder A graded mixture of coal ash, superfine cement, metakaolin, 39 parts by weight of glass microspheres, 0.8 parts by weight of bentonite, 95 parts by weight of distilled water, 1 part by weight of aldehyde and ketone condensate dispersant, 3.2 parts by weight of PVA fluid loss reducer, 1.2 parts by weight of AMPS polymer retarder, 0.5 parts by weight of silicone foam suppressor, and 0.5 parts by weight of tributyl phosphate.

[0032] The preparation method of the above-mentioned expansive toughness cementing slurry, it comprises the following steps:

[0033] The graded mixture of 6 parts by weight of modified nitrile rubber powder, 20 parts by weight of slag powder, fly ash, superfine cement, the ...

Embodiment 2

[0037] This embodiment provides an expansive toughness cementing cement slurry, which comprises the following components in parts by weight: 100 parts by weight of cement, 8 parts by weight of a graded mixture of modified nitrile rubber powder, 28 parts by weight of slag powder, powder A graded mixture of coal ash, superfine cement, metakaolin, 12 parts by weight of glass microspheres, 0.5 parts by weight of bentonite, 72 parts by weight of distilled water, 1 part by weight of aldehyde and ketone condensate dispersant, 3 parts by weight of PVA fluid loss reducer, 1.5 parts by weight of AMPS polymer retarder, 0.5 parts by weight of silicone foam suppressor, and 0.5 parts by weight of tributyl phosphate.

[0038] The preparation method of the above-mentioned expansive toughness cementing slurry, it comprises the following steps:

[0039] The graded mixture of 8 parts by weight of modified nitrile rubber powder, 28 parts by weight of slag powder, fly ash, superfine cement, the gr...

Embodiment 3

[0043] This embodiment provides an expansive toughness cementing cement slurry, which comprises the following components in parts by weight: 100 parts by weight of cement, 11 parts by weight of a graded mixture of modified nitrile rubber powder, 4 parts by weight of slag powder, powder Coal ash, superfine cement, graded mixture of metakaolin, 35 parts by weight of quartz sand, 55 parts by weight of distilled water, 1 part by weight of aldehyde and ketone condensate dispersant, 2.5 parts by weight of PVA fluid loss reducer, 2.5 parts by weight of AMPS polymer Retarder, 0.5 parts by weight organosilicon foam suppressor, 0.5 parts by weight tributyl phosphate.

[0044] The preparation method of the above-mentioned expansive toughness cementing slurry, it comprises the following steps:

[0045] A gradation mixture of 11 parts by weight of modified nitrile rubber powder, 4 parts by weight of slag powder, fly ash, superfine cement, a gradation mixture of metakaolin, 35 parts by weig...

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Abstract

The invention provides an expanded flexible well cementing grout and a preparation method thereof. The grout comprises the following components in parts by weight: 100 parts of cement, 6-14 parts of toughening material, 3-80 parts of reinforcing material, 8-120 parts of density modifier, 0.5-2.5 parts of suspension stabilizer, 20-40 parts of high-temperature stabilizer, 35-100 parts of distilled water, 0.5-2 parts of dispersant, 0.5-4 parts of fluid loss agent, 0.3-4 parts of retarder, 0.1-2 parts of foam inhibitor and 0.1-2 parts of defoamer. The invention further provides a preparation method of the expanded flexible well cementing grout. The grout has good sedimentation stability; and the set cement has the characteristics of micro expansion, high strength and low elasticity modulus, and can avoid the phenomena of micro cracks, micro annuluses, even fracture and the like caused by cement sheaths in subsequent operation of gas storage wells, shale gas wells, dense oil-gas horizontal wells and the like, thus realizing good zonal isolation and providing a technical support for long-term, safe and effective operation of oil-gas wells.

Description

technical field [0001] The invention provides an expansion toughness cementing cement slurry and a preparation method thereof, belonging to the field of oil and gas well cementing engineering. Background technique [0002] Ordinary Portland cement is a brittle, porous, and shrinkable material with congenital defects. Due to the alternating stress and temperature changes in the process of gas injection and production in gas storage wells, large-scale shale gas wells and tight oil and gas horizontal wells Volume fracturing can easily lead to microcracks or even breakage of brittle ordinary cement stones; and cement hydration shrinkage is an inherent characteristic of Portland cement, which can easily lead to cement sheaths in the well and micro-gap in the annulus; the above two Both of these situations will cause the cement sheath to lose its interlayer isolation, resulting in formation fluid channeling, annular pressure and other phenomena. Therefore, it is necessary to modif...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09K8/467C09K8/48
CPCC09K8/467C09K8/48
Inventor 靳建洲徐明刘硕琼张华袁进平于永金齐奉忠李勇刘子帅
Owner BC P INC CHINA NAT PETROLEUM CORP
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