Preparation method of fatty ester sulphonate

A technology of ester sulfonate and fatty acid, which is applied in the field of preparation of fatty acid ester sulfonate, can solve problems such as ignoring research, and achieve the effects of broad application prospects, low production cost, and high active substance content

Active Publication Date: 2015-06-03
GUANGZHOU INST OF ENERGY CONVERSION - CHINESE ACAD OF SCI
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] Chinese patents 102618398 A and 103320236 A propose a method for preparing detergents containing sodium fatty acid methyl ester sulfonate, and Chinese patent 101921678 A proposes a method for preparing soap containing fatty acid ethyl ester sulfonate. The above patents only focus on The focus is on the performance of washing products, but the research on the intermediate raw material fatty acid methyl ester sulfonate is neglected
Researchers from all walks of life pay more attention to the extraction of oil-producing microorganisms and microbial oils. The application of microbial oils is limited to biodiesel. There are few reports on the application of chemical products, especially MES.

Method used

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  • Preparation method of fatty ester sulphonate

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Effect test

Embodiment 1

[0027] Embodiment 1: a kind of preparation method of fatty acid ester sulfonate

[0028] First carry out the transesterification reaction: first take 10g of microbial oil (iodine value 60), 10g of n-hexane, 2.5g of methanol, and 0.01g of catalyst sodium hydroxide, add it to the reactor and heat it in a water bath, raise the temperature to 50°C, react for 1 hour, and the reaction ends Finally, the obtained crude product is washed with hot water to make the solution neutral, the product after the water washing is distilled and dehydrated under reduced pressure to obtain the target crude product, and the obtained crude product is purified and refined using a vacuum distillation range meter to obtain microbial oil methyl ester; Carry out epoxidation reaction then: get microbial grease methyl ester 10g, formic acid 0.5g, catalyzer concentrated sulfuric acid 0.1g, stir, slowly add dropwise 8g sodium peroxide, after dropwise finishes, 60 ℃ of reaction 4 hours, after reaction finishes,...

Embodiment 2

[0029] Embodiment 2: a kind of preparation method of fatty acid ester sulfonate

[0030]Referring to Example 1, the difference is that in the transesterification reaction, ethanol is 4g, the catalyst is 0.04g potassium hydroxide, and reacted at 60°C for 2 hours; in the epoxidation reaction, 10g of microbial oil ethyl ester, 1.3g of acetic acid, and catalyst concentrated hydrochloric acid 0.2g, stir, slowly add 10g potassium peroxide dropwise, react at 65°C for 6 hours; in the ring-opening reaction, take 10g of epoxidized microbial ethyl ester, 10g of ring-opening agent ethanol, 0.05g of catalyst fluoboric acid, and react at 75°C for 2 hours ; In the sulfonation reaction, 20g of sulfonating agent was sulfonated at 80°C for 1 hour, and aged for 0.7 hours.

Embodiment 3

[0031] Embodiment 3: a kind of preparation method of fatty acid ester sulfonate

[0032] Referring to Example 1, the difference is: 5 g of butanol in the transesterification reaction, 0.1 g of potassium bicarbonate as a catalyst, and 2 hours of reaction at 80° C.; 0.4g hydrochloric acid, stir, slowly drop 15g potassium peroxide, react at 90°C for 8 hours; in the ring-opening reaction, take 10g epoxidized microbial oil butyl ester, ring-opening agent butanol 12g, catalyst concentrated hydrochloric acid 0.1g, react at 105°C 4 hours, 30g of sulfonating agent in the sulfonation reaction, sulfonated at 90°C for 2 hours, then aged for 1 hour.

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Abstract

The invention discloses a preparation method of fatty ester sulphonate which takes microbial oil as a raw material to obtain an anionic surfactant, namely fatty ester sulphonate, via a series of reactions such as ester exchange, epoxidation, ring opening and sulfonation. The microbial oil adopted by the method is prepared by fermentation of yeast and algae by taking a straw as a raw material; the oil is low in production cost; large scale industrial production of a product of the oil is easy to realize; and the method achieves conversion of the straw into soap and a detergent. The anionic surfactant, namely fatty ester sulphonate, prepared by the method has a higher active substance content; the preparation method of the anionic surfactant has no problem of 'fighting for grains with people', and solves the problems that animal and vegetable oil are long in production cycle and are limited by seasons and climates, raw materials are narrow in source and additional cultivated land resources are occupied at present, and particularly the problem that the yield of the animal and vegetable oil is far from meeting MES (fatty acid methyl ester sulfonate) industrial production requirements; and the method has good economic benefits and wide application prospects.

Description

Technical field: [0001] The invention relates to the technical field of biochemical industry, in particular to a preparation method of fatty acid ester sulfonate. Background technique: [0002] Surfactants can greatly reduce the surface tension of the solvent and change the interface state of the system when added in a small amount, thereby producing a series of properties such as wetting, emulsification or demulsification, foaming or defoaming. Surfactants, as industrial additives, "industrial monosodium glutamate", and functional additional materials, play an increasingly important role in various fields of our national economy, national defense and military industries, and people's lives. Through continuous and in-depth research on surfactants, it is bound to have important significance for economic development and social progress. [0003] At present, the main effective components in detergents are mostly surfactants such as alkylbenzene sulfonate (LAS), dodecyl sulfate...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C07C309/62C07C303/32B01F17/06C09K23/06
Inventor 陈新德杨丹张海荣黄超熊莲施丝兰
Owner GUANGZHOU INST OF ENERGY CONVERSION - CHINESE ACAD OF SCI
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