Preparation method of fatty ester sulphonate
A technology of ester sulfonate and fatty acid, which is applied in the field of preparation of fatty acid ester sulfonate, can solve problems such as ignoring research, and achieve the effects of broad application prospects, low production cost, and high active substance content
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Embodiment 1
[0027] Embodiment 1: a kind of preparation method of fatty acid ester sulfonate
[0028] First carry out the transesterification reaction: first take 10g of microbial oil (iodine value 60), 10g of n-hexane, 2.5g of methanol, and 0.01g of catalyst sodium hydroxide, add it to the reactor and heat it in a water bath, raise the temperature to 50°C, react for 1 hour, and the reaction ends Finally, the obtained crude product is washed with hot water to make the solution neutral, the product after the water washing is distilled and dehydrated under reduced pressure to obtain the target crude product, and the obtained crude product is purified and refined using a vacuum distillation range meter to obtain microbial oil methyl ester; Carry out epoxidation reaction then: get microbial grease methyl ester 10g, formic acid 0.5g, catalyzer concentrated sulfuric acid 0.1g, stir, slowly add dropwise 8g sodium peroxide, after dropwise finishes, 60 ℃ of reaction 4 hours, after reaction finishes,...
Embodiment 2
[0029] Embodiment 2: a kind of preparation method of fatty acid ester sulfonate
[0030]Referring to Example 1, the difference is that in the transesterification reaction, ethanol is 4g, the catalyst is 0.04g potassium hydroxide, and reacted at 60°C for 2 hours; in the epoxidation reaction, 10g of microbial oil ethyl ester, 1.3g of acetic acid, and catalyst concentrated hydrochloric acid 0.2g, stir, slowly add 10g potassium peroxide dropwise, react at 65°C for 6 hours; in the ring-opening reaction, take 10g of epoxidized microbial ethyl ester, 10g of ring-opening agent ethanol, 0.05g of catalyst fluoboric acid, and react at 75°C for 2 hours ; In the sulfonation reaction, 20g of sulfonating agent was sulfonated at 80°C for 1 hour, and aged for 0.7 hours.
Embodiment 3
[0031] Embodiment 3: a kind of preparation method of fatty acid ester sulfonate
[0032] Referring to Example 1, the difference is: 5 g of butanol in the transesterification reaction, 0.1 g of potassium bicarbonate as a catalyst, and 2 hours of reaction at 80° C.; 0.4g hydrochloric acid, stir, slowly drop 15g potassium peroxide, react at 90°C for 8 hours; in the ring-opening reaction, take 10g epoxidized microbial oil butyl ester, ring-opening agent butanol 12g, catalyst concentrated hydrochloric acid 0.1g, react at 105°C 4 hours, 30g of sulfonating agent in the sulfonation reaction, sulfonated at 90°C for 2 hours, then aged for 1 hour.
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