Rigid foam polyurethane thermal insulation material

A technology of rigid polyurethane foam and thermal insulation materials, applied in the field of rigid polyurethane thermal insulation materials, which can solve problems such as lack of active hydrogen, foam and shell shedding, shell deformation, etc., achieve excellent compressive strength and avoid deformation of the water tank

Inactive Publication Date: 2016-05-25
GUANGXI JISHUN ENERGY TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Vegetable oil is mostly obtained from stable raw materials, so it is a cost-effective polyurethane raw material. The disadvantage is that it lacks the active hydrogen necessary for the reaction with isocyanate, so it needs to be modified.
[0006] During the production process of rigid polyurethane foam, due to various reasons such as its own characteristics, production process and production wor

Method used

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  • Rigid foam polyurethane thermal insulation material

Examples

Experimental program
Comparison scheme
Effect test

Example Embodiment

[0032] Example 1

[0033] First prepare polyether polyol I, the process is as follows:

[0034] (1) Weigh 80g of lignin, 40g of water, 5g of lignin peroxidase, 1g of catalase, 1g of furan acetaldehyde and 5g of furfuryl alcohol in a reactor at a reaction temperature of 80°C, stir and react for 5 hours to obtain Enzymatic hydrolysis of modified lignin;

[0035] (2) Mix 100g of enzymatically hydrolyzed modified lignin, 300g of glycerol, 200g of diethylene glycol and 0.03g of Pd-Fe catalyst in the reactor, control the reaction temperature to 120°C, and bubbling with nitrogen from the bottom of the reactor. , Then vacuumize, add 8 g of propylene oxide, and conduct a sealed reaction at normal pressure for 2 hours to obtain the polyether polyol I with a functionality of 4.6 and a hydroxyl value of 400 mgKOH / g.

[0036] Then prepare polyether polyol II, the process is as follows:

[0037] (1) Weigh 40 g of ethylene glycol and 3 g of magnesium chloride to 200 g of peanut oil, control the reac...

Example Embodiment

[0040] Example 2

[0041] First prepare polyether polyol I, the process is as follows:

[0042] (1) Weigh 50g of lignin, 30g of water, 3g of lignin peroxidase, 2g of catalase, 3g of furan acetaldehyde and 10g of furfuryl alcohol in a reactor at a reaction temperature of 80°C, stir and react for 5 hours to obtain Enzymatic hydrolysis of modified lignin;

[0043] (2) Mix 100g of enzymatically hydrolyzed modified lignin, 250g of glycerol, 100g of diethylene glycol and 0.01g of Pd-Fe catalyst in the reactor, control the reaction temperature at 120℃, and bubbling with nitrogen from the bottom of the reactor for reaction , Then evacuated, added 4 g of propylene oxide, and reacted under normal pressure for 2 hours to obtain the polyether polyol I with a functionality of 5.0 and a hydroxyl value of 400 mgKOH / g.

[0044] Then prepare polyether polyol II, the process is as follows:

[0045] (1) Weigh 20 g of ethylene glycol and 1 g to 100 g of magnesium chloride in peanut oil, control the react...

Example Embodiment

[0048] Example 3

[0049] First prepare polyether polyol I, the process is as follows:

[0050] (1) Weigh 100g of lignin, 50g of water, 2g of lignin peroxidase, 3g of catalase, 8g of furan acetaldehyde and 6g of furfuryl alcohol in a reactor at a reaction temperature of 80°C, stir and react for 5 hours to obtain Enzymatic hydrolysis of modified lignin;

[0051] (2) Mix 100g of enzymatically hydrolyzed modified lignin, 350g of glycerol, 250g of diethylene glycol and 0.05g of Pd-Fe catalyst in the reactor, control the reaction temperature to 120℃, and bubbling with nitrogen from the bottom of the reactor for reaction , And then evacuated, add 10 g of propylene oxide, and react under normal pressure for 2 hours to obtain the polyether polyol I with a functionality of 4.7 and a hydroxyl value of 410 mgKOH / g.

[0052] Then prepare polyether polyol II, the process is as follows:

[0053] (1) Weigh 50 g of ethylene glycol and 5 g of magnesium chloride to 300 g of peanut oil, control the reac...

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Abstract

The invention relates to a thermal insulation material and discloses a rigid foam polyurethane thermal insulation material. The thermal insulation material is prepared by mixing and foaming the following raw materials in parts by weight: 70-100 parts of isocyanate, 40-80 parts of polyether polyol I, 10-30 parts of polyether polyol II, 3-6 parts of expanded vermiculite, 5-8 parts of nano silicon dioxide, 10-20 parts of foaming agent, 1-5 parts of catalyst and 1-5 parts of 3-[polyethylene glycol methyl ether]propyl trialkoxy silane, wherein the polyether polyol I is lignin polyether polyol; and the polyether polyol II is polyether polyol polymerized by taking modified peanut oil as an initiator and epoxy propane as a polymerization monomer. The thermal insulation material has high compressive strength, tensile strength and impact strength and avoids the phenomena of deformation, bulging, barring and even cracking of a water tank.

Description

technical field [0001] The invention relates to thermal insulation materials, in particular to a rigid foam polyurethane thermal insulation material. Background technique [0002] With the increasing shortage of energy and the increasing pressure on environmental protection, countries around the world have begun to promote the development of renewable energy, among which solar energy is the most widely used and developed renewable energy with the best development prospects, and has been widely used in various industries , the solar water heater industry is one of them. Our country is rich in solar energy resources and has broad prospects for solar energy utilization. At present, it is the first user and producer of solar water heaters in the world. [0003] As we all know, for solar water heaters, the selection of water tank insulation materials is very important. At present, the insulation materials that can be used as water tanks mainly include polyurethane foam, phenolic...

Claims

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Application Information

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IPC IPC(8): C08G18/48C08K3/34C08K7/10C08K7/26C08G65/26C08G65/28C08J9/14C08J9/04
CPCC08G18/4816C08G65/2603C08G65/2609C08G65/2615C08J9/04C08J9/144C08J9/147C08J2375/08C08K3/34C08K7/10C08K7/26C08K2201/011
Inventor 马云李正良陈明贤周腾飞
Owner GUANGXI JISHUN ENERGY TECH
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