Silver-loaded antibacterial paper and preparing method thereof
An antibacterial paper and silver-carrying technology, applied in the field of papermaking, can solve the problem of not being able to provide the effect of sterilization and disinfection, and achieve the effects of inhibiting the growth and growth of microorganisms, avoiding damage, and fast and good sterilization.
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[0019] A silver-loaded antibacterial paper, which is prepared from the following raw materials: silver-loaded antibacterial agent, softener, dry strength agent, wet strength agent, desiccant, retention aid, sizing agent, antibacterial agent, dispersant and bleaching agent agent. The softening agent is one or more combinations of quaternary ammonium salt resins, imidazolines, amino silicone oils, and betaine; the dry strength agent is cationic starch, anionic starch, modified starch, polyacrylamide, chitosan One or more combinations of , guar gum, hydroxymethyl cellulose, polyethylene glycol; wet strength agent is one or more of polyamide polyepichlorohydrin resin, melamine formaldehyde resin, urea-formaldehyde resin combination; the desiccant is one or more combinations of silica gel desiccant, molecular sieve, and cellulose desiccant; the retention and drainage aid is one or more of cationic starch, polyacrylamide, polyethyleneimine, and anionic starch The sizing agent is on...
Embodiment 1
[0024] Preparation of silver-loaded zeolite
[0025] Use 4A artificial zeolite, add dilute nitric acid dropwise at 25°C, adjust the pH value to 5.5-6.5, heat in a water bath, stir and add the AgNO3 solution prepared according to the solid-liquid ratio of 1:1.5 (0.2-0.5mol / L, zeolite A better silver-loaded amount can be obtained), carry out the exchange reaction at 50°C in the dark for 2 hours, suction filter after standing, and dry to prepare the silver-loaded antibacterial agent, the grinding particle size is 10-20μm silver-loaded antibacterial agent, silver-loaded antibacterial The agent is introduced into the paper sheet according to two addition methods in scheme 1, one is directly added to the paper pulp at the pulpmaking stage, and the silver ion concentration per ton of dry paper is calculated according to the following formula: CAg + =K*W 1 (K is silver-loaded zeolite mass percentage of silver-loaded, W 1 is the mass fraction of silver-loaded zeolite added to each to...
Embodiment 2
[0027] Preparation of silver-loaded zeolite
[0028] A certain amount of silver-loaded sodium zirconium phosphate is added to seaweed fiber for blend spinning, in which silver ions are calculated according to the formula: CAg + =K 2 *W 2 , where K is the mass percentage of silver in silver-loaded sodium zirconium phosphate, and W is the weight percentage of alginate fiber added per ton of pulp fiber.
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