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Glass bead modified PBT (polybutylene terephthalate) material with epoxy resin bonding performance and preparation method for glass bead modified PBT material

A technology of glass microbeads and epoxy resin, which is applied in the field of glass microbead modified PBT materials and its preparation, can solve the problems of reduced packaging efficiency, difficulty in controlling the curing process of epoxy resin viscosity changes, etc., to reduce density and improve viscosity conjunctive effect

Inactive Publication Date: 2016-08-24
ANHUI KING AUTO ELECTRONICS TECH CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] Chinese patent CN 104610711 B discloses a PBT material with good epoxy resin adhesion and its preparation method. The invention uses antioxidant 24-44, antioxidant 168, antioxidant 1010 and carbon free scavenger HP136 The compounding, through the synergistic effect of each component, makes the material have excellent anti-aging performance, introduces reactive functional groups that have the ability to react with epoxy resin, and improves the interfacial adhesion with epoxy resin, but when using epoxy resin Rapid viscosity changes make it difficult to control the curing process, and rapid curing results in reduced encapsulation efficiency

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0028] Weighing: 70 kg of PBT, 18 kg of cardanolamine, 18 kg of polyvinyl alcohol microspheres, 6 kg of sodium dodecyl sulfonate, 6 kg of gelatin, 10 kg of glass microbeads, 2 kg of erucamide, Oxygen agent 245 2 kg;

[0029] The glass microbead masterbatch includes the following composition in parts by weight: 10 parts of PBT, 5 parts of hollow glass microspheres, and 2 parts of PP-g-MAH grafted compatibilizer.

[0030] Specific steps are as follows:

[0031] (1) Preparation of glass microbead masterbatch:

[0032] Mix PBT and PP-g-MAH grafted compatibilizer evenly, and pour them into the main feeding port of the twin-screw extruder; put the hollow glass microspheres into the side feeding port at the rear end of the extruder; The screw extruder extrudes the strands and cuts them into pellets to obtain the glass microbead masterbatch, which is ready for use;

[0033] (2), preparation of microcapsule curing agent:

[0034] ①. Under stirring conditions, add 0.5wt% gelatin aqu...

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Abstract

The invention discloses a glass bead modified PBT (polybutylene terephthalate) material with epoxy resin bonding performance. The glass bead modified PBT material consists of the following raw materials in parts by weight: 60 to 80 parts of PBT, 15 to 20 parts of cardanol amine, 15 to 20 parts of polyvinyl alcohol microspheres, 5 to 8 parts of sodium dodecyl sulfate, 5 to 10 parts of gelatin, 6 to 12 parts of glass bead master batches, 1 to 3 parts of erucamide and 1 to 3 parts of an antioxidant 245. According to the glass bead modified PBT material, a coated curing agent is introduced to increase the content of functional groups capable of being reacted with epoxy resin in the material, and meanwhile, a microcapsule of the microcapsule curing agent can be broken to be slowly released under a certain condition to implement curing, so that the aim of controlling a material and epoxy resin pouring sealant curing process is fulfilled, and the interface bonding performance between the material and the epoxy resin is improved; in addition, the advantages of vacuum structures of hollow glass beads are fully utilized, so that the density, dielectric constant and electric conductivity of the PBT material are improved.

Description

technical field [0001] The invention relates to the technical field of polymer materials, in particular to a glass microsphere modified PBT material with epoxy resin bonding properties and a preparation method thereof. Background technique [0002] Polybutylene terephthalate (English name Polybutylene Terephthalate, referred to as PBT) is milky white [0003] Color Translucent to opaque, crystalline thermoplastic polyester. It has excellent electrical properties, high heat resistance, toughness, fatigue resistance, self-lubrication, low coefficient of friction, weather resistance, low water absorption, and maintains various physical properties (including electrical properties) in a humid environment. Good, so it is widely used as engineering plastics in automobiles, electronic and electrical components. [0004] The engine ignition coil is the main component of the engine ignition system. Its function is to increase the low voltage of the car battery to a high voltage of 2...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L67/02C08L51/06C08L29/04C08L89/00C08K7/28C08K5/20C08K5/134C08J3/22C08G59/62
CPCC08L67/02C08G59/62C08G59/623C08J3/226C08J2367/02C08J2467/02C08L2205/025C08L2205/035C08L2205/08C08L51/06C08L29/04C08L89/00C08K7/28C08K5/20C08K5/1345
Inventor 王进
Owner ANHUI KING AUTO ELECTRONICS TECH CO LTD
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