Preparation method of flame-retardant composite over-rust antirust paint

A rust-proof, flame-retardant composite technology, used in anti-corrosion coatings, fire-retardant coatings, coatings, etc., can solve the problems of poor uniform compactness and fluidity, weak hydrolysis resistance, and poor adhesion of anti-rust paints. Simple preparation steps, good uniformity and compactness, and strong hydrolysis resistance

Inactive Publication Date: 2016-09-21
张静
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] The technical problem to be solved by the present invention: the current anti-rust paint has poor adhesion, severe paint film shedding, weak hydrolysis resistance, easy fading and bubble generation, poor uniformity and density, and poor fluidity, resulting in its water resistance, alkali resistance and corrosion resistance. The drawback of the reduced anti-rust and flame-retardant ability provides a method of drying and crushing tung seeds and Maofeng, mixing them with lime water, adjusting the pH, standing and filtering to get the filter residue to be air-dried, adding distilled water for grinding, and heating and heat preservation under ultrasonic waves. The filtrate is obtained by mixing n-hexane with heat preservation and filtering, stirring and mixing with hectorite and talcum powder, adding zinc oxide for heat preservation, adding polyurethane, iron oxide and barium sulfate, stirring and maintaining pressure to obtain a flame-retardant composite anti-rust paint with rust
The preparation steps of the invention are simple, and the obtained product has good adhesion, uniform density and fluidity, effectively solves the problem of serious shedding of the anti-rust paint film, weak hydrolysis resistance, easy fading and generation of bubbles, water resistance, alkali resistance and rust prevention The problem of reduced flame retardancy

Method used

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Examples

Experimental program
Comparison scheme
Effect test

example 1

[0015] First, according to the mass ratio of 1:2, take tung seeds and Maofeng and put them in a 50°C oven to dry for 6 hours, then crush them, pass through a 100-mesh sieve, and then put the sieved particles and lime water into In the container, use a phosphoric acid solution with a mass fraction of 20% to adjust the pH to 7.2, let it stand at 60°C for 10 minutes, then filter and collect the filter residue, put the filter residue in an air dryer to dry; then mix the air-dried filter residue and distilled water according to the mass ratio 1:3, put it into a refiner for refining, place the obtained slurry in an ultrasonic heater, heat it to 70°C in an ultrasonic environment, keep the temperature for 5h, cool it down to 35°C, add distilled water volume 60% n-hexane alkane, keep the temperature for 2h, then filter while it is hot, and collect the filtrate; then in parts by weight, get 30 parts of the above-mentioned filtrate, 10 parts of hectorite, 8 parts of mass fractions of 4.6m...

example 2

[0018] First, according to the mass ratio of 1:2, take tung seeds and Maofeng and put them in a 50°C oven to dry for 7 hours, then crush them, pass through a 100-mesh sieve, and then put the sieved particles and lime water into In the container, adjust the pH to 7.5 with a mass fraction of 20% phosphoric acid solution, let it stand at 65°C for 15 minutes, then filter and collect the filter residue, put the filter residue into an air dryer to dry; then mix the air-dried filter residue and distilled water according to the mass ratio 1:2, put it into a refiner for refining, put the obtained slurry in an ultrasonic heater, heat it to 75°C in an ultrasonic environment, keep the temperature for 6h, cool it down to 38°C, add distilled water volume 63% n-hexane alkane, keep the temperature for 3h, then filter while it is hot, and collect the filtrate; then in parts by weight, get 33 parts of the above-mentioned filtrate, 13 parts of hectorite, 10 parts of mass fraction of 4.6mol / L phos...

example 3

[0021]First, according to the mass ratio of 1:2, take tung seeds and Maofeng and put them in a 50°C oven to dry for 8 hours, then crush them, pass through a 100-mesh sieve, and then put the sieved particles and lime water into In the container, adjust the pH to 7.8 with a phosphoric acid solution with a mass fraction of 20%, let it stand at 70°C for 20 minutes, then filter and collect the filter residue, put the filter residue into an air dryer to dry; then mix the air-dried filter residue and distilled water according to the mass ratio 1:2, put it into a refiner for refining, place the obtained slurry in an ultrasonic heater, heat it to 80°C in an ultrasonic environment, keep the temperature for 8 hours, cool down to 40°C, add distilled water volume 65% n-hexane alkane, keep the temperature for 3h, then filter while it is hot, and collect the filtrate; then in parts by weight, get 35 parts of the above-mentioned filtrate, 15 parts of hectorite, 11 parts of mass fraction of 4.6...

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Abstract

The invention discloses a preparation method of a flame-retardant composite over-rust antirust paint, belonging to the technical field of antirust paint preparation. The preparation method comprises the following steps: drying and pulverizing tung seeds and Maofeng, mixing with lime water to regulate the pH value, standing, filtering, airing the filter residue, adding distilled water, grinding into slurry, heating to keep the temperature under ultrasonic actions, mixing with n-hexane, filtering to obtain the filtrate while keeping the temperature, stirring and mixing with hectorite, talcum powder and the like, adding zinc oxide, keeping the temperature, respectively adding polyurethane, iron oxide and barium sulfate, stirring and mixing, and keeping the pressure, thereby obtaining the flame-retardant composite over-rust antirust paint. The method has the advantage of simple preparation steps. The obtained product has the advantages of favorable adhesive force, favorable uniformity and compactness, favorable flowability, high shock strength (greater than 50kg.cm) and high hydrolysis resistance. After being immersed in water for 140-145 hours, the paint film does not shed or discolor, and does not generate the bubble phenomenon; the water resistance, alkali resistance, rust resistance and flame retardancy are effectively enhanced; and the paint film can resist the high temperature of 130 DEG C for 6080-7100 hours.

Description

technical field [0001] The invention relates to a preparation method of a flame-retardant composite anti-rust paint with rust, belonging to the technical field of anti-rust paint preparation. Background technique [0002] Antirust paint is a coating that protects metal surfaces from chemical or electrochemical corrosion from the atmosphere, sea water, etc. Mainly divided into two categories of physical and chemical antirust paint. The former relies on the proper coordination of pigments and paints to form a dense paint film to prevent the intrusion of corrosive substances, such as iron red, aluminum powder, graphite antirust paint, etc.; the latter relies on the chemical antirust effect of antirust pigments, such as red Dan, zinc yellow antirust paint, etc. Used for rust prevention of bridges, ships, pipelines and other metals. Corrosion of metals is very common. The loss caused by metal corrosion not only damages the metal material itself in terms of its shape, color an...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09D175/04C09D5/08C09D5/18C09D7/12
CPCC09D175/04C08K3/22C08K3/32C08K3/34C08K5/1539C08K13/02C08K2003/2296C08K2003/329C08K2201/014C09D5/08C09D5/18C09D7/61C09D7/63
Inventor 张静盛海丰宋奇
Owner 张静
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